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6. The 1H NMR spectrum for a compound with molecular formula C7H1402 is given below. Propose a structure for this compound an

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Answer #1

To calculate the number of protons, divide all integrals by smallest value i.e. 0.55.

Proton marked Integral value protons responsible multiplicity
a 1.12 1.12/0.55 = 2 triplet
b 0.55 0.55/0.55 = 1 septet
c 1.08 1.08/0.55 = 2 sextet
d 3.2 3.2/0.55 = 6 doublet
e 1.6 1.6/0.55 = 3 triplet

As per the NMR signals below 4.5, the given compound is neither carboxylic ester, aldehyde or alcohol. So, it is an ester.

The most suitable compound is propyl-2-methyl propanoate.

СИ, - Си Си -0 C - C6) m,

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