The 2nd product is the benzoic
acid.
17. Give the reagents for the following reaction. Write the product for each step. HCECH CH, CH2CH2CH CH, CH.CHOH 18. Give the reagents for the following reaction. Write the mechanism for each step. Br Br HCECH CH.CH -CH2CH3 1 Br Br
6. (20) Fill in the missing reagents to accomplish these conversions (>1 step may be needed): 7, (10) Give the alkyl halide which would give only the alkene shown by way of an E2 elimination (one alkyl halide for each alkene): 8. (10 - extra credit) (a) (6) Propose a 2-4 step mechanism to explain this conversion. (b) (4) Draw a reasonable reaction coordinate diagram for this process.
16. Give the reagents for the following reaction. Write the product for each step. CH, CH2CH2CECH CH3CH2CH2CHCH2Br :CH, HCH. BY Br
3) Draw the mechanism for the following reaction. (6 pes) N-N OMSO The following total synthesis involves multiple steps. Give all necessary reagents and intermediate structures 4) that are formed. (8 points) s) Which one of the following pairs of compounds wilield the following product in presence of suifuric acid? 16 pts) What are three different sets of reagents that wil directly produce the product shown? (6 pt)
7. MECHANISM: Give the complete stepwise mechanism to account for the following observation. Use curved arrows to show FLOW OF ELECTRONS. [9 points H-CI 8.RETROSYNTHETIC ANALYSIS Give a reasonable synthesis for the following compound from the indicated starting materials. You may use any other organic reagents or inorganic reagents you wish. The desired product for each reaction must be the MAJOR PRODUCT. Give the reactants, conditions (where appropriate), and products of each synthetic step but NO MECHANISMS. [6 points] OH...
Section: 7-11 8. Give the reagents for the following reaction. Write the product for each step. HCECH CH:CHCH2CH3
Organic ChemistryPlease show all reagents used,
the mechanism, and the product of each reactant.
27) Devise a multistep synthesis for the following transformation. You may use any organic or inorganic reagents of your choice. Include the reagents necessary for each step and the product of each step. -
Problem B. For the mechanism Step 1 2NO:N20s+ 0 Step 2 CO+O→CO2 Step 3 N:0> NO+NO ki fast equilibrium s slow ks fast Draw a reaction coordinate for the mechanism below, keeping in mind that the following must be included Reagents, intermediates (if present) and products a. b. Relative magnitude of activation energy c. Endo/exothermicity of each step and of the overall reaction (Hint: Think about bond enthalpies)
Draw the two step mechanism for the nitration of bromobenze to give the para product. Draw the four major resonance contributers for the intermediate cation. Circle the resonance structure that is particularlt stable, and explain the reasoning.
to a. Provide the mechanism for its reaction with HCl and give the major product(s), including stereochemistry. Give a BRIEF explanation for why this mechanism follows Markovnikov or anti-Markovnikov addition. b. Provide the mechanism for its reaction with Br2 in water solvent. Give the structure of the major product(s), including stereochemistry. For each step of your mechanism, identify the Nu- and the E+.