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HH on. Draw the mechanism, including curly arrows, 11. Consider the following reaction. Draw the mechanism,...
Question 1: Draw the expected major product for the following reactions: НІ HC CH CH₂ HBO...
Question 1: Draw the expected major product for the following reactions: НІ HC CH CH₂ HBO ROOR Question 2: Draw a mechanism for the following transformations: a) H₃C CH3 HCI H₂C T CH3 HAC CH3 нс с Question 3: Draw the mechanism for the following transformations: нс сH3 CH3 о (H,SO4), он H₂C7 Question 4 HĄCE 1) Hg(OAC), H, 2) NaBH, HEC CH, Question : Predict the product(s) of the following reaction: 1) BHZ. THE Н4С SCH, 2) H2O, NaOH...
1. Draw structures for the following compounds: a) l-ethyl-2-methylcyclohexane b) 4-methyl hexanal c) N-N-dimethylpentanamide 2. What...
1. Draw structures for the following compounds: a) l-ethyl-2-methylcyclohexane b) 4-methyl hexanal c) N-N-dimethylpentanamide 2. What is the product of this bromination reaction? H2C-CH=CH-CH2-CH2-CH3 + Br2 3. What is the product of this oxidation reaction? OH H3C-CH-CH-CHg 10 Сн, 4. Consider the esterification reaction reaction below: H, SO H3C-CH2-CH2-CH2-C-OH + H2C-CH2-OH What organic compound is the reactant on the left? What organic compound is the reactant on the right? Draw the product of the reaction. What type of organic compound...
30. Late papers not accepted. Work Independently. 1. Predict the most likely reaction mechanism (SN1, SN2,...
30. Late papers not accepted. Work Independently. 1. Predict the most likely reaction mechanism (SN1, SN2, E1, E2) and draw all products. CH₂ Na O=CH₂ Hic Br 2 Draw complete mechanism with arrows for the SNI/E1 mechanism. Check for carbocation rearrangements CH3 + H2O 3. Which is the major product for the following reaction? Y CH + NaOH CH HO HO H₃ CH₂ H₃ HOCH CH₂ H₃ CHE CH₂ CH₂ CH3 CH 4. Name the following including the R/S, E/Z...
Predict products and for the type of reaction one the last option is rearrangement CA2. Predict...
Predict products and for the type of reaction one the last
option is rearrangement
CA2. Predict the product(s) in the reaction below. H2SO4 minor major minor major 43. Predict the product in the reaction below PBr, CH3CH2OH A. H2C CH2 B. D. H C-CH. H,C-CH, H2C-CH. 44. Which of the following alcohols undergoes dehydration most readily? OH OH OH OH
7. Consider the reaction below to answer the following question(s). CH H3C-c-c13;0 CH7 HC H3C-C-OH +...
7. Consider the reaction below to answer the following question(s). CH H3C-c-c13;0 CH7 HC H3C-C-OH + C=CH, H2C ethanol CH CH3 The substrate in the reaction is: (1 pt) Compound B is the product of mechanism (1 pt) Compound C is the product of mechanism (1 pt) Write the complete reaction mechanism for the formation of Compound C in this reaction. (2 pts) Final Exam- Part 11 (40 pts) Dr. Indika Galpothdeniya 8. Consider the reaction below to answer the...
CH3 7) Draw in the appropriate curly arrows for the following El mechanism. Note! The below...
CH3 7) Draw in the appropriate curly arrows for the following El mechanism. Note! The below steps are the steps in a single mechanism for a single reaction! Pay attention to lone pairs (i.e. draw them in if appropriate.) Also write in hidden hydrogens that are in the vicinity of the reaction site. HO Start by rewriting each of the reactants. Then use "arrow pushing" to show how the reactants are converted to products, assuming an El mechanism. Be sure...
37. H0+ (CH3), C CH OH alkene + H2O Draw the structure of the major alkene...
37. H0+ (CH3), C CH OH alkene + H2O Draw the structure of the major alkene product of this acid-catalyzed dehydration. (Hint: rearrangement.) 38. alkenes Three alkenes produce butane when treated with hydrogen and platinum. Draw their structures. + H-Br - 39. CH2=CH CH3 CH2-CH-CH, H Br The first step of the mechanism of this reaction produces two carbocations. Draw both and circle the one that is more stable. ODHO Br 11 =C + Br - Br - - Br...
Problem of the Day 18 1. (10 pts) Consider the following reaction: TO + HBr a....
Problem of the Day 18 1. (10 pts) Consider the following reaction: TO + HBr a. Estimate AH for this reaction (use table 6.1 in your textbook) b. Is AS for this reaction positive or negative? Explain. C. Determine if AG is positive or negative. d. Is the sign of AG (positive or negative) dependent on temperature? Why? TABLE 6.1 BOND DISSOCIATION ENERGIES (AH) OF COMMON BONDS KJ/MOL KCAL/MOL KI/MOL KCAUMO Bonds to H H2C=CH-CH3 HCC-CH3 KJ/MOL KCAL/MOL 385 92...
1- Draw all of the expexted products from the reaction and explain. Draw the products of...
1-
Draw all of the expexted products from the reaction and
explain.
Draw the products of the reaction.
(2 equiv.) NH Select Draw / H2C--0-0- HC=CH CH + OH- - CH3 HC-CH cs H3C-CH2-C-N-CH3 + HCI heat
please show all steps including each mechanism (arrows) and also if SN1 has any rearrangements of...
please show all steps including each mechanism (arrows) and
also if SN1 has any rearrangements of carbocation intermediate
through a hydride shift and/or methyl shift. DO NOT NEED
ELIMINATION. ONLY SUBSTITUTION.
Sy1/E1 versus S2/E2 Learning Checks Draw the major organic substitution and/or elimination products in the following reactions. If no reaction is possible, write “No Reaction". Substitution Product(s) Elimination Product(s) 2) 2) OH BrCH K* -Ot-Bu NaOCH н"Сн, сн,он нсн, Ph NaOCH Br H CH3OH CH NaOCH NaOH T.CH, I...
Question 1: Draw the expected major product for the following reactions: НІ HC CH CH₂ HBO ROOR Question 2: Draw a mechanism for the following transformations: a) H₃C CH3 HCI H₂C T CH3 HAC CH3 нс с Question 3: Draw the mechanism for the following transformations: нс сH3 CH3 о (H,SO4), он H₂C7 Question 4 HĄCE 1) Hg(OAC), H, 2) NaBH, HEC CH, Question : Predict the product(s) of the following reaction: 1) BHZ. THE Н4С SCH, 2) H2O, NaOH...
1. Draw structures for the following compounds: a) l-ethyl-2-methylcyclohexane b) 4-methyl hexanal c) N-N-dimethylpentanamide 2. What is the product of this bromination reaction? H2C-CH=CH-CH2-CH2-CH3 + Br2 3. What is the product of this oxidation reaction? OH H3C-CH-CH-CHg 10 Сн, 4. Consider the esterification reaction reaction below: H, SO H3C-CH2-CH2-CH2-C-OH + H2C-CH2-OH What organic compound is the reactant on the left? What organic compound is the reactant on the right? Draw the product of the reaction. What type of organic compound...
30. Late papers not accepted. Work Independently. 1. Predict the most likely reaction mechanism (SN1, SN2, E1, E2) and draw all products. CH₂ Na O=CH₂ Hic Br 2 Draw complete mechanism with arrows for the SNI/E1 mechanism. Check for carbocation rearrangements CH3 + H2O 3. Which is the major product for the following reaction? Y CH + NaOH CH HO HO H₃ CH₂ H₃ HOCH CH₂ H₃ CHE CH₂ CH₂ CH3 CH 4. Name the following including the R/S, E/Z...
Predict products and for the type of reaction one the last
option is rearrangement
CA2. Predict the product(s) in the reaction below. H2SO4 minor major minor major 43. Predict the product in the reaction below PBr, CH3CH2OH A. H2C CH2 B. D. H C-CH. H,C-CH, H2C-CH. 44. Which of the following alcohols undergoes dehydration most readily? OH OH OH OH
7. Consider the reaction below to answer the following question(s). CH H3C-c-c13;0 CH7 HC H3C-C-OH + C=CH, H2C ethanol CH CH3 The substrate in the reaction is: (1 pt) Compound B is the product of mechanism (1 pt) Compound C is the product of mechanism (1 pt) Write the complete reaction mechanism for the formation of Compound C in this reaction. (2 pts) Final Exam- Part 11 (40 pts) Dr. Indika Galpothdeniya 8. Consider the reaction below to answer the...
CH3 7) Draw in the appropriate curly arrows for the following El mechanism. Note! The below steps are the steps in a single mechanism for a single reaction! Pay attention to lone pairs (i.e. draw them in if appropriate.) Also write in hidden hydrogens that are in the vicinity of the reaction site. HO Start by rewriting each of the reactants. Then use "arrow pushing" to show how the reactants are converted to products, assuming an El mechanism. Be sure...
37. H0+ (CH3), C CH OH alkene + H2O Draw the structure of the major alkene product of this acid-catalyzed dehydration. (Hint: rearrangement.) 38. alkenes Three alkenes produce butane when treated with hydrogen and platinum. Draw their structures. + H-Br - 39. CH2=CH CH3 CH2-CH-CH, H Br The first step of the mechanism of this reaction produces two carbocations. Draw both and circle the one that is more stable. ODHO Br 11 =C + Br - Br - - Br...
Problem of the Day 18 1. (10 pts) Consider the following reaction: TO + HBr a. Estimate AH for this reaction (use table 6.1 in your textbook) b. Is AS for this reaction positive or negative? Explain. C. Determine if AG is positive or negative. d. Is the sign of AG (positive or negative) dependent on temperature? Why? TABLE 6.1 BOND DISSOCIATION ENERGIES (AH) OF COMMON BONDS KJ/MOL KCAL/MOL KI/MOL KCAUMO Bonds to H H2C=CH-CH3 HCC-CH3 KJ/MOL KCAL/MOL 385 92...
1-
Draw all of the expexted products from the reaction and
explain.
Draw the products of the reaction.
(2 equiv.) NH Select Draw / H2C--0-0- HC=CH CH + OH- - CH3 HC-CH cs H3C-CH2-C-N-CH3 + HCI heat
please show all steps including each mechanism (arrows) and
also if SN1 has any rearrangements of carbocation intermediate
through a hydride shift and/or methyl shift. DO NOT NEED
ELIMINATION. ONLY SUBSTITUTION.
Sy1/E1 versus S2/E2 Learning Checks Draw the major organic substitution and/or elimination products in the following reactions. If no reaction is possible, write “No Reaction". Substitution Product(s) Elimination Product(s) 2) 2) OH BrCH K* -Ot-Bu NaOCH н"Сн, сн,он нсн, Ph NaOCH Br H CH3OH CH NaOCH NaOH T.CH, I...
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