Question
need help with 42 & 44

42. What volumes of 0.50 M HNO2 and 0.50 M NaNO2 must be mixed to prepare 1.00 L of a solution buffered at pH = 3.55? 43. Con

I am trying to figure out how to make a desired buffer


APPENDIX 5 Equilibrium Constants and Reduction Potentials A5.1 | Values of Ka for Some Common | Monoprotic Acids Name Formula
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Answer #1

According to HOMEWORKLIB RULES we have to answer only first one problem

pH = pKa + log(NaNO2/HNO2)

Ka for HNO2 = 4x10^-4

pKa = 3.4 (-logKa = pKa)

3.55 = 3.4 + log(A-/HA)

log(A-/HA)= 0.15

A-/HA = (10^0.15 = 1.41)

A-/HA = 1.41

A- = 1.41 HA

A- + HA = 1

1.41 HA + HA = 1

2.41 HA = 1

HA= 0.414

HNO2 = HA = 0.415 L

NaNO2 = A- = 0.585 L

CROSS CHECK

pH = pKa + log(NaNO2/HNO2)

= 3.4 + log 0.585/0.415

= 3.4 +0.149

= 3.549

=3.55

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