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Which would you expect to be the stronger nucleophile: a) The amid ion (NH) or ammonia? b) RS or RSH ?
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Answer #1

Amide ion is a stronger nucleophile than ammonia because of the negative charge on nitrogen in the ion. This makes it a good nucleophile

RS- is a stronger nucleophile than RSH because of the negative charge on the sulphur in the ion. This makes it a better nucleophile.

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