H2CO3 is diprotic acid but the second dissociation constant is very small, we can consider that H+ ions are mainly coming from the first dissociation of acid .
H2CO3 H+ + HCO3-
[H+] = √(c.Ka1) = √(0.10×4.3×10-7) = 2.0736×10-4 M
pH = -log[H+] = -log(2.0736×10-4) = 3.6833
pH = 3.68
Answer : (d) 3.68
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