E4B.4(a) Pressure was exerted with a piston on water at 20°C. The vapour pressure of water...
E4B.13(a) Naphthalene, C, H, melts at 80.2°C. If the vapour pressure of liquid is 1.3 kPa at 85.8 °C and 5.3 kPa at 119.3°C, use the Clausius-Ch equation to calculate (i) the enthalpy of vaporization, (ii) the normal point, and (iii) the entropy of vaporization at the boiling point. lausius-Clapeyror (11) the normal boiling
(E4B.3(a) By how much does the chemical potential of copper change when the pressure exerted on a sample is increased from 100 kPa to 10 MPa? Take the mass density of copper to be 8960 kg m ?
E4B.12(a) An open vessel containing water stands in a laboratory measuring 5.0 m x 5,0 m x 3.0 m at 25°C; the vapour pressure of water at this tempera ture is 3.2 kPa. When the system has come to equilibrium, what mass on will be found in the air if there is no ventilation? Repeat the calculation to open vessels containing benzene (vapour pressure 13.1 kPa) and mercury (vapour pressure 0.23 Pa).
1.Water vapor contained in a piston–cylinder assembly undergoes an isothermal expansion at 277°C from a pressure of 5.1 bar to a pressure of 2.7 bar. Evaluate the work, in kJ/kg. 2.Nitrogen (N2) contained in a piston–cylinder arrangement, initially at 9.3 bar and 437 K, undergoes an expansion to a final temperature of 300 K, during which the pressure–volume relationship is pV1.1 = constant. Assuming the ideal gas model for the N2, determine the heat transfer in kJ/kg. 3.Argon contained in...
E4B.2(a) Water is heated from 25 °C to 35°C. By how much does its chemi- cal potential change? The standard molar entropy of liquid water at 298 K is 69.9JK'mol"!.
A piston-cylinder device contains water which is initially at 100 C and 20 bar. It undergoes two processes. The first process is isothermal and the second process is constant volume. The final condition is a saturated vapour at 2 bar. Calculate heat transfer and work (both in kJ/kg) for each process.
5. (25 Pts) Water in a piston-cylinder device exists as a saturated liquid at a pressure of 2.0 MPa (2000 kPa). Heat is then added to complete this process such that the final temperature of the water is 500 °C. Determine the following: a. What phase is the water in at State 2? b. If V1 = 2 m3, what is the mass of water [kg] in the piston-cylinder device? c. Show the process on a T-v diagram. Clearly label...
05/03/2019 Problem 5 (20 pts) 4-kg of water vapor contained within a piston-cylinder assembly, initialy at 5 bar, s00°C, undergoes an adiabatic expansion to a state where pressure is 1 bar and the temperature is (a) 360°C, (b) 200°C. Using the entropy balance equation below, explain the nature of the process in each case. +σ ,-1.0 har-a10 MPa 004034 2712 30229 1.5 200 2172 1 2875.3 .4 120 05416 237 3105.6 .50 240 2359 27185 29545 7,9949 2.546 | 277401...
1. When ammonium chloride is heated the vapour pressure at 427°C is 6.0 bar. At 459°C the vapour pressure has risen to 11.0 bar. The dissociation equilibrium is: NHACI(S) NH3(g) + HCl(g) What is (i) the equilibrium constant at both temperatures; (ii) the standard Gibbs energy of the dissociation reaction at 427°C; (iii) the molar dissociation enthalpy at 427°C; (iv) the molar dissociation entropy at 427°C? din K - 4H a(1/) R
Toluene vapour at 1.013 bar (1.0 atm) and 150°C is to be cooled under constant pressure to a final temperature of 22°C. a) Determine the change of entropy of the system in J/mol·K. b) What is the change of entropy of the system J/mol·K if the final state is a vapour-liquid mixture that is 47 mol% vapour? Data: Use the heat capacity data in Table C1 for toluene as a gas and the data in Table C3 for toluene as...