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A voltaic cell is constructed from a standard Cr3Cr half cell (Ered=-0.740V) and a standard Fe3+|Fe2+ half cell (Ered=0.771V)

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Answer #1

1)

a)

Oxidation takes place on Anode.

The one with smaller Eo value will be oxidised.

So, the anode reaction is:

Cr(s) —> Cr3+(aq) + 3 e-

b)

Reduction takes place on Cathode.

The one with greater Eo value will be reduced.

So, the Cathode reaction is:

Fe3+(aq) + e- —> Fe2+(aq)

C)

Overall reaction is:

3 Fe3+(aq) + Cr(s) -> 3 Fe2+(aq) + Cr3+(aq)

d)

Eo cell = Eo cathode - Eo anode

= 0.771 V - (-0.740 V)

= 1.51 V

Answer: 1.51 V

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