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200 ml of buffer needed using stock solutions of .196M HCHOO and .271M NaCHOO. compute volume...

200 ml of buffer needed using stock solutions of .196M HCHOO and .271M NaCHOO. compute volume of each needed to reach PH of 4.4
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Answer #1

Henderson - Hasselbalch equation is

pH = pKa + log([A-]/[HA])

4.4 = 3.75 + log( [ HCOO-]/[HCOOH])

log([HCOO-]/[HCOOH]) = 0.65

[HCOO-]/[HCOOH] = 4.467

moles of HCOO-/moles of HCOOH = 4.467

( 0.271mol/1000ml) × X / (0.196mol/ 1000ml) × ( 200ml - X) = 4.467

X 0.000271mol/ml / ( 0.0392mol - X 0.000196mol/ml) = 4.467

X0.000271mol/ml = 0.1751mol - X0.0008756mol/ml

X0.001147mol/ml = 0.1751mol

X = 152.7ml

200ml - 152.66ml = 200ml - 152.66ml = 47.3ml

Therefore,

Volume of 0.196M HCOOH required = 47.3ml

Volume of 0.271M NaHCOO required = 152.7ml

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