2. (a) Draw the products for the following Snl reactions. (0.5 pt ea) (b) Designate all...
1. (a) Draw the products for the following Sy2 reactions (0.5 pt ea) (b) Designate all asymmetric carbons as R or S (0.5 pt ea) CH3 OSOH + Bracetone P:EN: + , scelone, :OCH + Door NCCHE 2. (a) Draw the products for the following Syl reactions. (0.5 pt ea) (b) Designate all asymmetric carbons as R or Sor racemic. (0.5 pt ea) CH,OH - - - #20+ ytor - 3. (a) For the reactions below, predict the mechanism (Snl...
1. (a) Draw the products for the following SN2 reactions (0.5 pt ea) (b) Designate all asymmetric carbons as R or S (0.5 pt ea) CH3 :Bracetone OsSo3H cEN: acetone NCCH3 Br :OCH
1. We will be doing the following reactions. Draw the reactions as Snl or Sn2 reactions including reaction arrows. RFR + Nal → R R + NaBr(s) acetone R PT R EtOH AgNOR OEt R + AgBr(s) + HNO3 2. We will be using Nal (in acetone) and ethanol as nucleophiles. Nat is a spectator ion. Classify I and ethanol as good nucleophiles or poor nucleophiles. Explain why. 3. In your lab notebook draw the following table a. Rank cach...
5. Predict the major organic products of the following reactions. Show all asymmetric carbons with wedgeldash notation (i.e., as shown in the starting material). If a reaction produces a racemic mixture, show only one of the enantiomers produced. Carefully note the requested reaction mechanism for each reaction. (20 pts) NaOCH3 CH3OH SN2 Br CH3OH SN1 Br NaOCH3 CH3OH E2 Show Zaitsev product Br CH3OH Br E1
2. Consider the following SNl reaction: H3 CHs CH3 CH3 i. Draw a mechanism using curved arrows. Show all step(s) involved in bond breaking& forming. ii. Draw an energy diagram. Label the axes, the reactants, products, Ea, and AH. Assume that the reaction is exothermic. ili Draw the structure of the intermediate product at the correct position in the energy diagram.
Question 4 Using R-2-chlorobutane as an example, compare and contrast SNl and SN2 reactions (a) Things you may wish to consider are: i. stereochemistry solvent leaving group iv strength of nucleophile [Marks: 5] Give one method for separating racemic mixtures (b)
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1. 1. Provide the full name for the following molecule. (0.5 pt) 1. Draw the product for the following reactions. Indicate if the product is racemic. (3.5 pts) 1. HBr 2. HCI 1. NaH
Draw the structure of the final product(s) of this series of reactions 1pt ernces 1 pt 1. Br 1 pt 2.3 equivalents of NaNH 3. mild acid 1 pt 4. BH 5. H202/ NaOH 1 pt 1 pt 1 pt Use the wedge/hash bond tools to indicate stereochemistry where it exists Include H atoms at chiral centers only If a group is achiral, do not use wedged or hashed bonds on it Draw organic species only. Do not include lone...
Additional Questions: 16. For the following reactions, identify all the B-hydrogens, draw all possible elimination products, and circle the major elimination product formed. (a) acetone CHоо + Br (b) -CI +NaOCH3 (c) CI NaOH Elimir (dpm6 mot r atnemepnsise1 p n6 26 0s 2 121t d 0ms2 erit 26d meinsrbom 13 na -BreNaOEt buborn tootSTI691 prilloert lo noitsof e
Q1- Fill in the boxes with the product of the following reactions. Draw only the PREDOMİNANT REGIOISOMER. When a racemic mixture is formed mark the chiral center with an ASTERICK () and write RACEMİC in the box. 1 Eq LDA 0 1 Eq NaOH 1) 0.5 Eq LDA1) Cat NaOH 2) H30 јнзо-, Heat , NaOEt, EtOH 1. NaOEt EtOH Br 1) NaOH, H2O 2) H3O 3) Heat 1) (CH3)zMgBr 2) H30 2 a2- Fill in the boxes with the...