Homework Answers
Solution:
The four step product is given below with explanation of each steps.
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Synthesis #3 Deter mine the final product in the synthesis outlined below. To ensure full credin,...
Draw the two major allylic alcohol intermediates and the two final products in the following two-step...
Draw the two major allylic alcohol intermediates and the two
final products in the following two-step synthesis. Show the
correct stereochemistry of each compound; if applicable, use
wedge/dash bonds to indicate chirality centers, and you must show
hydrogens on these centers.
Map Draw the two major allylic alcohol intermediates and the two final products in the following two-step synth Show the correct stereochemistry of each compound; if applicable, use wedge/dash bonds to indicate chirality centers, and you must show hydrogens...
C. REACTIONS: (8 points each; 40 points total) For each of the following reactions or series...
C. REACTIONS: (8 points each; 40 points total) For each of the following reactions or series of reactions, draw the final major organic product, reactant, or reagents in the box. Be sure to indicate STEREOCHEMISTRY where pertinent. In multiple step reactions, you may place intermediate products below the reaction for partial credit. 1. NH2 2. 1) NBS, hv 2) NaCN 0.5 eq 3) NaOH, H20 4) HCI 3. 1) NaBH4 2) MCPBA 3) NaOH 4) excess acetic acid, H+
5. Draw the intermediates and final product for the following synthesis (Full: all products correct with...
5. Draw the intermediates and final product for the following synthesis (Full: all products correct with no more than 1 minor error, partial: 3 out of 4 correct with no more than 1 minor error) Mg, Et,0 Br 1, CO, 2. H, H20 SOCI NH2
please help 3. Draw the major product of the final step of the following scheme in...
please help
3. Draw the major product of the final step of the following scheme in the box provided. 1. NBS, ROOR or NBS, cat AIBN, CCls, heat 2. DBN 3. Hydroboration-oxidation 4. PBr3 5. Mg, Et2o 6. PhCHO, then workup 7. Jones reagent 8. PhLi, Et O, then H30 9. TsOH, heat 10. NBS, HOH 11. NaOH (intramolecular SN2) 12. MeMgBr (excess), then workup 13. E2 14. HBr 15. Mg, ether 16. dry ice, then workup 17. LiAlH4, ether,...
The scheme below shows the synthesis of an antihypertensitive agent (drug used to treat high blood...
The scheme below shows the synthesis of an antihypertensitive agent (drug used to treat high blood pressure). Answer the questions that follows. a Br 1 Br CI с CO Me + Meo H2NCO Me (Question 3) B OME CN CN CN CN 6 2 3 4 5 CO Me CO Me Buz SnNz d Final product (9) (1) KOH, heat (2) H+ work up partial hydrolysis (Question 4) CAH, CAH, CN 7 NH NEN 8 Question 1 Select the best...
This is for Organic II. Thank you! Give the primary product that would result from the...
This is for Organic II. Thank you!
Give the primary product that would result from the following reactions: NOTE: If the problem involves multiple reactions, and you cannot determine the final product, draw the structure of any of the intermediate products (and indicate which reaction the product is for, i.e. Step # 1 , Step # 2 , etc.) 1) BHs, THF 2) н.о,. он-) 3) (CH3)2NH 4) H2, Pt/C Cat. н. он N-CH3 b) 1) н,о'*) 2) Na2Cr o,,...
Propose an efficient synthesis for the transformation below. Enter the appropriate number of letter from the...
Propose an efficient synthesis for the transformation below. Enter the appropriate number of letter from the reagent list handout Step 1 Step 2 Step 3 OH Alkyl Halides (X = CI, Br or 1) and Acyl chlorides: Assume Allig 15 present, if needed CIP CU CH3X X CI E A B EE Ketones. Aldehydes and Epoxides: Assume "then H20" is included if a protonation step is needed F A A K 0 MN Р Grignard, Wittig and Organocuprate Reagents: Assume...
Propose an efficient synthesis for the transformation below, using two sequential reductive aminations. Enter the appropriate number...
Propose an efficient synthesis for the transformation below,
using two sequential reductive aminations. Enter
the appropriate number or letter from the reagent list handout.
Propose an efficient synthesis for the transformation below, using two sequential reductive aminations. Enter the appropriate number or letter from the reagent list handout. Step 1 + NaBH3CN, H+, Step 2 - NaBH3CN, H+ Reagent List (Updated 4/30/2020) Enter # or letter in the appropriate boxes. Note: Exam responses are case insensitive Alkyl Halides (X = Cl,...
Predict the major product(s) of the following reactions. Show stereochemistry where appropriate. 3 CO3H i) OsO4...
Predict the major product(s) of the following reactions. Show stereochemistry where appropriate. 3 CO3H i) OsO4 H ii) NaHSO3, H2O CHC13, KOH any cha, kot i) BH3, THF CECH 11) H2O2, NaOH Li NH (liquid) cm X Ft, H/HO (vii) Two Markovnikov products Draw the structure of alkene for each of the following reactions. OH i) BH, THF 11) H202, NaOH 1) Hg(OAc)2, H20 ii) NaBH4 1) 03 ii) Zn/H Styrene undergoes propagation to give polystyrene. Showing electron-flow using half-headed...
CHEM 2343A HOMEWORK W13 Name: DUE 11/18/19 at 9:10 AM There are total of 4 questions...
CHEM 2343A HOMEWORK W13 Name: DUE 11/18/19 at 9:10 AM There are total of 4 questions on this homework assignment 1. For the reaction outlined below in la and I draw out the reaction mechanism using arrow formalism to describe how the reaction below occurs. Be sure to draw out all action intermediates & the moment of all electrons needed to justify the formation of the indicand product. You do not need to add in any reagents that are not...
Draw the two major allylic alcohol intermediates and the two
final products in the following two-step synthesis. Show the
correct stereochemistry of each compound; if applicable, use
wedge/dash bonds to indicate chirality centers, and you must show
hydrogens on these centers.
Map Draw the two major allylic alcohol intermediates and the two final products in the following two-step synth Show the correct stereochemistry of each compound; if applicable, use wedge/dash bonds to indicate chirality centers, and you must show hydrogens...
C. REACTIONS: (8 points each; 40 points total) For each of the following reactions or series of reactions, draw the final major organic product, reactant, or reagents in the box. Be sure to indicate STEREOCHEMISTRY where pertinent. In multiple step reactions, you may place intermediate products below the reaction for partial credit. 1. NH2 2. 1) NBS, hv 2) NaCN 0.5 eq 3) NaOH, H20 4) HCI 3. 1) NaBH4 2) MCPBA 3) NaOH 4) excess acetic acid, H+
5. Draw the intermediates and final product for the following synthesis (Full: all products correct with no more than 1 minor error, partial: 3 out of 4 correct with no more than 1 minor error) Mg, Et,0 Br 1, CO, 2. H, H20 SOCI NH2
please help
3. Draw the major product of the final step of the following scheme in the box provided. 1. NBS, ROOR or NBS, cat AIBN, CCls, heat 2. DBN 3. Hydroboration-oxidation 4. PBr3 5. Mg, Et2o 6. PhCHO, then workup 7. Jones reagent 8. PhLi, Et O, then H30 9. TsOH, heat 10. NBS, HOH 11. NaOH (intramolecular SN2) 12. MeMgBr (excess), then workup 13. E2 14. HBr 15. Mg, ether 16. dry ice, then workup 17. LiAlH4, ether,...
The scheme below shows the synthesis of an antihypertensitive agent (drug used to treat high blood pressure). Answer the questions that follows. a Br 1 Br CI с CO Me + Meo H2NCO Me (Question 3) B OME CN CN CN CN 6 2 3 4 5 CO Me CO Me Buz SnNz d Final product (9) (1) KOH, heat (2) H+ work up partial hydrolysis (Question 4) CAH, CAH, CN 7 NH NEN 8 Question 1 Select the best...
This is for Organic II. Thank you!
Give the primary product that would result from the following reactions: NOTE: If the problem involves multiple reactions, and you cannot determine the final product, draw the structure of any of the intermediate products (and indicate which reaction the product is for, i.e. Step # 1 , Step # 2 , etc.) 1) BHs, THF 2) н.о,. он-) 3) (CH3)2NH 4) H2, Pt/C Cat. н. он N-CH3 b) 1) н,о'*) 2) Na2Cr o,,...
Propose an efficient synthesis for the transformation below. Enter the appropriate number of letter from the reagent list handout Step 1 Step 2 Step 3 OH Alkyl Halides (X = CI, Br or 1) and Acyl chlorides: Assume Allig 15 present, if needed CIP CU CH3X X CI E A B EE Ketones. Aldehydes and Epoxides: Assume "then H20" is included if a protonation step is needed F A A K 0 MN Р Grignard, Wittig and Organocuprate Reagents: Assume...
Propose an efficient synthesis for the transformation below,
using two sequential reductive aminations. Enter
the appropriate number or letter from the reagent list handout.
Propose an efficient synthesis for the transformation below, using two sequential reductive aminations. Enter the appropriate number or letter from the reagent list handout. Step 1 + NaBH3CN, H+, Step 2 - NaBH3CN, H+ Reagent List (Updated 4/30/2020) Enter # or letter in the appropriate boxes. Note: Exam responses are case insensitive Alkyl Halides (X = Cl,...
Predict the major product(s) of the following reactions. Show stereochemistry where appropriate. 3 CO3H i) OsO4 H ii) NaHSO3, H2O CHC13, KOH any cha, kot i) BH3, THF CECH 11) H2O2, NaOH Li NH (liquid) cm X Ft, H/HO (vii) Two Markovnikov products Draw the structure of alkene for each of the following reactions. OH i) BH, THF 11) H202, NaOH 1) Hg(OAc)2, H20 ii) NaBH4 1) 03 ii) Zn/H Styrene undergoes propagation to give polystyrene. Showing electron-flow using half-headed...
CHEM 2343A HOMEWORK W13 Name: DUE 11/18/19 at 9:10 AM There are total of 4 questions on this homework assignment 1. For the reaction outlined below in la and I draw out the reaction mechanism using arrow formalism to describe how the reaction below occurs. Be sure to draw out all action intermediates & the moment of all electrons needed to justify the formation of the indicand product. You do not need to add in any reagents that are not...
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