With MeOH/H+ , hydroxylation occurs at para to OH group then Kmno4 oxidize the benzyl carbon to COOH group which inturn reduced to Alcohol by LiAlH4
Pyridinium chlorochromate is a mild oxidising agent and oxidize the Alcohol to aldehyde.
Fill in structures for A-O in the following reaction scheme part of which was recently reported...
B12 1.D SOCI Mg THE G- Light 3. A recent reporting forming cart than OH 2. H2O 1. LAH, THE H Cro MeOH - М 2. H2O excess 2. Fill in structures for A-O in the following reaction scheme part of which was recently reported in the chemical literature (JOC, 2011, 57-64). (15 x 3 = 45 pt) CH3OH KMnO4 1. LAH A B НО heat 2. H2O Cro, ci
"ОН Step 1 Fill in the following reaction scheme based on the Roman numerals provided below: но Η Ν. HO HOH НО-Н Step 2 H-OH H-OH H ОН HO -Η HO -H НО. H HOH HO -H HO+H CH, OH CH OH CH OH Step 3 HCN cat. HCI H,0 HIO NH,OH NaBHA EROH - 11 III IV V NaOCH, Bra H.0 VII cat HCI CH,OH но" Pa/Baso Hy XI VI VIII х HNO H.O heat XI H,02 Fox(50) XII...
Which one of the following structures is an intermediate in the mechanism of the following reaction? 0 НО. о во. ОН ОН А) B) 1) KOH, H20, heat 2) dil, aq HCI Но ОН но Но, он C) D)
OH Fill in the following reaction scheme based on the Roman numerals provided below: но H OH HO HO-H Step 1 HO-H Step 2 H H-OH H OH HOH HOH Step 3 HOH нон но-н HO-H CH, OH CH, OH CH, OH cal HCI HCN HIO NH, OH NaBH но EROH IV V NaOCH PdBaso H,09 BE HO VII cat HCI CH,OH VIII VI XI X HO, HNO, H.O heat XI Fe (50 XII BnB Nah DMF heat XIII ....
Which one of the following structures is an intermediate in the mechanism of the following reaction? OH A) B) H2SO4 H20 OH ОН C) D) Which one of the following structures is an intermediate in the mechanism of the following reaction? НО. ОН ОН А) B) 1) Кон, Н-0, heat 2) dl. aq Hсі Он но ТОН НО он НО C) D)
wone br Provide the products of the following reaction scheme. 5' x 9 45 1)O 2) DIAS 1) OsO 2) NAHSO но нх HDr лOOR но 1) RCO H 2) но 1) Hg(OAc) HO NabH "он Big H,O 1) вн, тHP 2) HO NaoH 7 6 5
Which one of the structures below is not an intermediate in the mechanism of the following reaction? но А) B) НО. ОН NH НО dil, aq. H2SO4 heat HN ОН НО НО ОН NH С) не D) Identify the product of the following transformation, A) B) 1) SOCH 2) CH, OH OH c)
2. (12 pts) Reactions Give the reagents or products to the following systems. If a reaction does not give a product, write "NR" for No Reaction. Provide the product with the highest yield. Assume 1 to 1 stoichiometry unless otherwise stated. Provide stereochemistry if applicable. NC heat но но H ETOH 1. SOCI2 2. Heat, Hас -о н Но H но ETOH 1. TsCl NC H но но Н 2. CH,ок, CH,он
Ch 16.1
Give the major product(s) or the following reaction ao,a OH N ? OH io OH H There is no reaction under these conditions or the correct product is not listed here Gve the major product(s) of the following reaction COCH OH N H OH 0 OH H There is no reaction under these conditions or the correct product is not listed here. В 1) BAIH (-Bu), (-78°C) (0.5 moles) 2) ное ? оо н ОН ОН OCH, OH...
please help in all sections asap!!!!
Which of the following reagent(s) could not be used to carry out the following transformation? HSCH2CH2SH, BFy; then Raney NI (H) 1. NH NH/H"; 2. KOH/H20/heat LAH, ether Zn(Hg), HCI Predict the product for the following reaction. О, Н excess 1. NH2NH2/H 2. KOH/ H2O/A NNH2 HO. Η ΝΗΝΗΣ NH2 CH OH CH CH HOCHNHNH OH NH2 NNH2 IN V We were unable to transcribe this imagePredict the product(s) for the following reaction. NaOH...