Question 1: Write an example of each mechanism:
g. Deprotonation of an alcohol and subsequent reaction
h. Deprotonation of an alkyne and subsequent reaction
i. Basic ring opening of an epoxide
j. Acid catalyzed ring opening of an epoxide
Question 1: Write an example of each mechanism: g. Deprotonation of an alcohol and subsequent reaction...
19. Draw the mechanism of the acid-catalyzed reaction shown below. Note that it occurs in 6 steps, and that in each step only one of the four basic mechanistic processes occurs (protonation, deprotonation, nucleophilic attack, elimination).
Notes: A ‘detailed’ mechanism should illustrate all intermediates, by-products, and electron-pushing arrows. The marking scheme is given for each question as a guide; It is subject to minor changes. In class, we learned how to synthesize epoxides from alkenes using meta-chloroperbenzoic acid (mCPBA). Epoxides, like bromonium ions and mercuronium ions, can be ring-opened with various nucleophiles. The stereochemistry of the product depends on if the ring-opening occurs under acidic or basic conditions. The following two reactions – ring opening of...
Can I somebody to write out a reaction mechanism for the following reaction series? 5-methyl-4-bromo-trans-2-hexene is subjected to MCPBA, then that epoxide product is opened under basic conditions, and finally the new product with an alcohol is oxidized using Pyridinium Dichromate. Thank you.
Page - 3 - of 9 ЗА) To get an anti - 1, 2 diol configuration, you have to go through an epoxide ring-opening reaction. In class, we showed this reaction happening in acidic or in basic conditions with a different mechanism. Below, DRAW a good arrow-pushing mechanism, showing all steps, for the epoxide ring- opening under both conditions, separately. Of course, the same two (2) products form in either mechanism below. Mechanism: OH-/H2O H2O + mil H-O O Mechanism:...
Write a mechanism for the acid-catalyzed reaction of formaldehyde with to form a hydrate. Us electrons. When you are done, scan the answer to a pdf file and upload it here. The answer i H OH H НОН
How would you write the mechanism for the opening of an epoxide for 1,2-epoxy-1-methylcyclopentane with methanol and sulfuric acid.
Question 3.53 a. alkene b. alkyne c. arene d. halide e. alcohol f. ester g. ether h. amine i. amide j. nitrile k. carboxylic acid l. thiol HN Cimetidine (Tagamet) From the list provided, identify the functional groups in this molecule. Enter your answer as an alphabetical series with no commas or spaces Groups present:
1. Answer with octyl ethanoate as the esterfication reaction (alcohol: 1-octanol, 3.25ml and carboxylic acid: ethanoic acid, 1.25ml) (a) Write a complete chemical equation for the esterfication reaction, use structural formulas and write the name of each compound under the formula. (b) define if the esther is polar or non-polar (c) determine the molar ratio of the two reactants, alcohol and carboxylic acid using the balanced chemical reaction (d) calculate the molar mass of the alcohol and carboxylic acid (e)...
1. (10 marks the wol 1. (10 marks) The Wolff-Kishner reduction is a method to transform ketones into alkanes. An example is provided below. step 1 step 2 NH oh oh oh oon HẠN-NH, KOH/H20 A mechanism for the Wolff-Kishner reduction is proposed online at the following website: However, all steps and all electron-pushing arrows are not clearly illustrated in this mechanism. Propose a detailed mechanism with all electron-pushing arrows for both steps of the Wolff-Kishner reduction. Notice the first...
Write a mechanism for the acid-catalyzed reaction of
formaldehyde with to form a hydrate. Use curved arrows to show
movement of electrons
н* н он й нон + H,0 - Hс нон