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If 0.360 moles of a monoprotic weak acid (Ka = 8.6 × 10-5) is titrated with...

If 0.360 moles of a monoprotic weak acid (Ka = 8.6 × 10-5) is titrated with NaOH, what is the pH of the solution at the half-equivalence point?

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Answer #1

at half equivalence point 50% acid becomes salt

so at half equivalence point [salt] = [acid]

for acidic buffer

pH = pKa + log [salt] / [acid]

pKa = - log Ka = - log [8.6 x 10-5]

pKa = 4.06

as [salt] = [acid]

log [salt] /[acid] = 0

pH = pKa

pH = 4.06

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