Homework Answers
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3. a. List the and state if( ) (10 pts ca.) i. Nucleophile (strong/weak), Basicity (strong/weak)...
2. (1.5 pts) Label the following reagents as Good or Poor Nucleophiles AND as Strong or Weak Base...
2. (1.5 pts) Label the following reagents as Good or Poor Nucleophiles AND as Strong or Weak Bases. OK Na SH 3. (1.5 pt) Predict the productts) of the following reactions, if there are multiple products indicate which, if any, is the major product. Be sure to clearly mark the stereochemistry of chiral carbon atoms and draw multiple products if there is more than one stereoisomer that forms. HCI MeOH H2SO H2 Pd/BaSO4 quinoline 4. (3 pt) For the following...
(3 pt) For the following reactions: a) Label the substrate (1°, 2°, 3°), reagent (Good/Poor Nu,...
(3 pt) For the following reactions:
a) Label the substrate (1°, 2°, 3°), reagent (Good/Poor Nu,
Strong/Weak Base) and solvent (protic, aprotic).
b) Determine what mechanism will predominate (SN1, SN2, E1, or
E2).
c) Draw the product(s) you would expect to form, paying
attention to regioselectivity and stereoselectivity.
4. (3 pt) For the following reactions: a) Label the substrate (1º, 2º, 3º), reagent (Good/Poor Nu, Strong/Weak Base) and solvent (protic, aprotic). b) Determine what mechanism will predominate (SN1, SN2, E1,...
strong nucleophile weak base strong bulky base strong nucleophile strong base Promote SN2/E2 weak nucleophile weak...
strong nucleophile weak base strong bulky base strong nucleophile strong base Promote SN2/E2 weak nucleophile weak base Promote SN1/E1 Promote SN2 Promote E2 CH Br HS NCT HO CHO CHÚCHO NaNO NaOH NOME Noe HOORS Conjugate acids have pka 16-18 Conjugate acids Recall, you make hydroxide have pka 11 or alkoxide ons from the corresponding alcohol or water and Nat CH,OH (MOH) HO CH,CH,OH (EXOH) | HC-Ć-o to CH tert-BUOK NOCH KOHBU NEOBU The structures above are all ways of...
Look at the given reaction and select the most appropriate answer from the dropdown menus to...
Look at the given reaction and
select the most appropriate answer from the dropdown menus to fill
in the analysis.
The substrate haloalkane is a ["methyl", "primary (unhindered)",
"primary (hindered)", "secondary", "tertiary"] haloalkane. The
nucleophile is a ["poor", "weakly basic", "strongly basic
(unhindered)", "strongly basic (hindered)"] nucleophile. And the
solvent is ["protic", "aprotic"].
This means the reaction likely follows a(n) ["SN2", "SN1", "E2",
"E1", "SN2 and E2", "SN1 and E1", "No reaction"] mechanism(s),
which will result in the stereochemistry at...
Look at the given reaction and select the most appropriate answer from the dropdown menus to...
Look at the given reaction and select the most appropriate
answer from the dropdown menus to fill in the analysis. Choose one
of the answers in the bracket:
The substrate haloalkane is a ["methyl", "primary (unhindered)",
"primary (hindered)", "secondary", "tertiary"] haloalkane. The
nucleophile is a ["poor", "weakly basic", "strongly basic
(unhindered)", "strongly basic (hindered)"] nucleophile. And the
solvent is ["protic", "aprotic"] .
This means the reaction likely follows a(n) ["SN2", "SN1", "E2",
"E1", "SN2 and E2", "SN1 and E1", "No...
Dropdown Menus: 1. methyl, primary (unhindered), primary (hindered), secondary, tertiary 2. poor, weakly basic, strong...
Dropdown Menus:
1. methyl, primary (unhindered), primary (hindered), secondary,
tertiary
2. poor, weakly basic, strongly basic (hindered), strongly basic
(unhindered)
3. protic, aprotic
4. SN2, SN1, E1, E2, SN2 AND E2, SN1 AND E1, No Reaction
5. randomized, inverted, predictable but not inverted,
unchanged
6. a planar carbocation intermediate, backside attack transition
state, anti-periplanar transition state, other
CH3CH2ONa ??? CH3CH2OH Br OH OH OH De on an or rega ang Look at the given reaction and select the most appropriate...
2. Predict the product(s) of each of the reaction conditions below. Specify the substrate type (primary,...
2. Predict the product(s) of each of the reaction conditions
below. Specify the substrate type (primary, secondary, or tertiary
alkyl halide), nucleophile (strong or poor), and the solvent type
(protic or aptrotic). Specify the type of reaction mechanism (SN1
or SN2), show the curved arrow mechanism and draw the products as
3D structures to illustrate stereochemistry.
Predict the product(s) of each of the reaction conditions below. Specify the substrate type (1º, 2º, or 3 alkyl halide). mucleophile (strong or poor),...
+ Fit to page Page view 1. (10 pts) For the following reactions: a. Label the...
+ Fit to page Page view 1. (10 pts) For the following reactions: a. Label the Nucleophile (Nu) and whether it is strong or weak b. Label the Electrophile (E) and whether it is primary, secondary, or tertiary and circle the leaving group c. Label the Solvent and whether it is polar protic or polar aprotic d. Categorize each as preferring SN1, Preferring SN2, or could do either e Draw the product of the reaction, based upon your categorization, remember...
5. REACTIONS (30PTS, 6PT EA): For the following reactions indicate what substituted alkyl halide sol are...
5. REACTIONS (30PTS, 6PT EA): For the following reactions indicate what substituted alkyl halide sol are provided and choose indicated reaction conditions, 2) then provide the major product or indicate dicate what substituted alkyl halide, solvent, and nucleopa cmajor product or indicate NO REACTION Closed Inuci NaOEt alkoi halide: 1.1.3 Salt Polar Proti Polar Agrote Noclegile strong wak Br EtOH Of Shade one — SI E2 S 2 EI Circle one cach alky balide 1º, 2º, 3º Solvent Polar Prote/Polar...
HWS 5: Due 10/30/2019 15 points total SN1, SN2, Elimination pt 1 1. (10 pts) For...
HWS 5: Due 10/30/2019 15 points total SN1, SN2, Elimination pt 1 1. (10 pts) For the following reactions: a. Label the Nucleophile (Nu) and whether it is strong or weak b. Label the Electrophile (E) and whether it is primary, secondary, or tertiary and circle the leaving group C. Label the Solvent and whether it is polar protic or polar aprotic d. Categorize each as preferring SN1, Preferring SN2, or could do either e. Draw the product of the...
2. (1.5 pts) Label the following reagents as Good or Poor Nucleophiles AND as Strong or Weak Bases. OK Na SH 3. (1.5 pt) Predict the productts) of the following reactions, if there are multiple products indicate which, if any, is the major product. Be sure to clearly mark the stereochemistry of chiral carbon atoms and draw multiple products if there is more than one stereoisomer that forms. HCI MeOH H2SO H2 Pd/BaSO4 quinoline 4. (3 pt) For the following...
(3 pt) For the following reactions:
a) Label the substrate (1°, 2°, 3°), reagent (Good/Poor Nu,
Strong/Weak Base) and solvent (protic, aprotic).
b) Determine what mechanism will predominate (SN1, SN2, E1, or
E2).
c) Draw the product(s) you would expect to form, paying
attention to regioselectivity and stereoselectivity.
4. (3 pt) For the following reactions: a) Label the substrate (1º, 2º, 3º), reagent (Good/Poor Nu, Strong/Weak Base) and solvent (protic, aprotic). b) Determine what mechanism will predominate (SN1, SN2, E1,...
strong nucleophile weak base strong bulky base strong nucleophile strong base Promote SN2/E2 weak nucleophile weak base Promote SN1/E1 Promote SN2 Promote E2 CH Br HS NCT HO CHO CHÚCHO NaNO NaOH NOME Noe HOORS Conjugate acids have pka 16-18 Conjugate acids Recall, you make hydroxide have pka 11 or alkoxide ons from the corresponding alcohol or water and Nat CH,OH (MOH) HO CH,CH,OH (EXOH) | HC-Ć-o to CH tert-BUOK NOCH KOHBU NEOBU The structures above are all ways of...
Look at the given reaction and
select the most appropriate answer from the dropdown menus to fill
in the analysis.
The substrate haloalkane is a ["methyl", "primary (unhindered)",
"primary (hindered)", "secondary", "tertiary"] haloalkane. The
nucleophile is a ["poor", "weakly basic", "strongly basic
(unhindered)", "strongly basic (hindered)"] nucleophile. And the
solvent is ["protic", "aprotic"].
This means the reaction likely follows a(n) ["SN2", "SN1", "E2",
"E1", "SN2 and E2", "SN1 and E1", "No reaction"] mechanism(s),
which will result in the stereochemistry at...
Look at the given reaction and select the most appropriate
answer from the dropdown menus to fill in the analysis. Choose one
of the answers in the bracket:
The substrate haloalkane is a ["methyl", "primary (unhindered)",
"primary (hindered)", "secondary", "tertiary"] haloalkane. The
nucleophile is a ["poor", "weakly basic", "strongly basic
(unhindered)", "strongly basic (hindered)"] nucleophile. And the
solvent is ["protic", "aprotic"] .
This means the reaction likely follows a(n) ["SN2", "SN1", "E2",
"E1", "SN2 and E2", "SN1 and E1", "No...
Dropdown Menus:
1. methyl, primary (unhindered), primary (hindered), secondary,
tertiary
2. poor, weakly basic, strongly basic (hindered), strongly basic
(unhindered)
3. protic, aprotic
4. SN2, SN1, E1, E2, SN2 AND E2, SN1 AND E1, No Reaction
5. randomized, inverted, predictable but not inverted,
unchanged
6. a planar carbocation intermediate, backside attack transition
state, anti-periplanar transition state, other
CH3CH2ONa ??? CH3CH2OH Br OH OH OH De on an or rega ang Look at the given reaction and select the most appropriate...
2. Predict the product(s) of each of the reaction conditions
below. Specify the substrate type (primary, secondary, or tertiary
alkyl halide), nucleophile (strong or poor), and the solvent type
(protic or aptrotic). Specify the type of reaction mechanism (SN1
or SN2), show the curved arrow mechanism and draw the products as
3D structures to illustrate stereochemistry.
Predict the product(s) of each of the reaction conditions below. Specify the substrate type (1º, 2º, or 3 alkyl halide). mucleophile (strong or poor),...
+ Fit to page Page view 1. (10 pts) For the following reactions: a. Label the Nucleophile (Nu) and whether it is strong or weak b. Label the Electrophile (E) and whether it is primary, secondary, or tertiary and circle the leaving group c. Label the Solvent and whether it is polar protic or polar aprotic d. Categorize each as preferring SN1, Preferring SN2, or could do either e Draw the product of the reaction, based upon your categorization, remember...
5. REACTIONS (30PTS, 6PT EA): For the following reactions indicate what substituted alkyl halide sol are provided and choose indicated reaction conditions, 2) then provide the major product or indicate dicate what substituted alkyl halide, solvent, and nucleopa cmajor product or indicate NO REACTION Closed Inuci NaOEt alkoi halide: 1.1.3 Salt Polar Proti Polar Agrote Noclegile strong wak Br EtOH Of Shade one — SI E2 S 2 EI Circle one cach alky balide 1º, 2º, 3º Solvent Polar Prote/Polar...
HWS 5: Due 10/30/2019 15 points total SN1, SN2, Elimination pt 1 1. (10 pts) For the following reactions: a. Label the Nucleophile (Nu) and whether it is strong or weak b. Label the Electrophile (E) and whether it is primary, secondary, or tertiary and circle the leaving group C. Label the Solvent and whether it is polar protic or polar aprotic d. Categorize each as preferring SN1, Preferring SN2, or could do either e. Draw the product of the...
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