6) Name each of the following, give the coordination number of the central cation, the geometry...
QUESTION 7 For [Fe(H20)4(NH3)C1) a) Name the following complexe b)give the coordination number of the central cation c) give the the geometry of the complex d) identify any isomers which may be present (yes/no) ammine tetraaqua chloro iron (11) Coctahedral ad. No
1. Name the following transition metal complexes AND give the coordination number for each metal in the complex ion: Name Coordination # (a) K[Fe(CN).] (b)Ks[Fe(ox).] (c) Cr(en).]C13 (d) (Cr(NH3):(HO)](NO3) (e)ky [Cr(NH3),Cla]
For each of the following i. Write the full name of the coordination compound (or complex) ii.Draw all of the isomers of the coordination compound (or complex) a. [Cr(NH3)3Br3] b. Fe(C2O4)2(CN)2 3-
For each of the following metal complexes, specify the number of ligands, the coordination number of the metal, the oxidation number of the metal, the geometry of the complex and draw the structure. Transition metal complexes with four ligands usually form tetrahedral structures unless the metal has a d8 configuration, in which case it can form either tetrahedral or square planar structures. NH4[Co(NCS)4(py)2] [RhBr(CO)5](NO3)2 K4[Fe(CN)6] [HgI4]2- [Cu(NH3)4]Cl2
Illustrate each of the following by giving formulas, geometry, or energy diagrams of: a. an octahedral complex of NiCit. b. cis and trans isomers of Ni(C0)2(CN)2. c. [Fe(H20)s] 3 + is a high-spin complex. d. a bidentate ligand. e. a coordination number of 2
the following coordination compound: K[CrCl4(en)]. a. Give the charge on the coordination sphere in this compound. b. Compute the OXIDATION NUMBER of the chromium cation in the complex. c. Give the COORDINATION NUMBER of the chromium cation in the complex. d. Sketch the structure of the complex ion.
4. Give chemical names for the following coordination complexes. a) [Cu(NH3)4]2+ b) [Pt(NH3). Cl]* c) [Mn(CN):)". d) (Co(en)2(PPha)]PO... e) [Ni(bipy)](NO3)2. 5. Give chemical formulas for the following coordination complexes. a) Triammineaquadichlorocobalt(III) chloride. b) Potassium diaquabis(oxalate)manganate(III). c) Tris(acetylacetonato Jiron(III). d) Tri--carbonylbis(tricarbonyliron(O)). e) Li-oxo-bis(pentaamminechromium(III)). 5. Draw a d-orbital energy-level diagram, and predict the number of unpaired electrons. a) [Fe(CN).] b) [Fe(H20):] c) (CoCil (tetrahedral) 6. Of the two complexes (a) (CoFs] and (b) (CoĊżen)] + one appears yellow and the other appears...
Question 10 5 pts Which of the following pairs of coordination compounds or complex ions are examples of linkage isomers? O [Fe(NH3)2(H20)4]Br2 and [Fe(NH3)2(H20)4]12 [Cu(NH3) 5Br]Cl and [Cu(NH3)5Cl]Br O [Mn(CO)5NO2)2+ and (Mn(CO)5ONO]2+ IV(H20)613+ and V(NH3)613 o [Fe(NH3)2(H20)4]Br2 and [Fe(NH3)4(H20)2Br2
Complex # of Coordination number Oxidation number Complex Structure ligands geometry NH4Co(NCS)(py): [RhBr(CO)s(NO) K[Fe(CN) [Hgl.] Cu(NH)Cl 3. What are the bond angles for the following geometries: Tetrahedral Linear Square planar_ Octahedral 4. A complex ion contains tungsten(II) bound to 4 water molecules and 2 fluoride ions. Using appropriate conventions write out its formula. 5. A complex ion contains copper(II) bonded to ethylenediamine and two water molecules. Using appropriate conventions write out its formula. Complex # of Coordination number Oxidation number...
1. (6 pts.) Consider the coordination compound Rh(C)(CO)(PPhs)2: Draw the two possible isomers for this square planar complex. What type of stereoisomers are these complexes? Why would no isomers exist for this complex if it had a tetrahedral geometry? a. b. c.