Question

An aqueous solution contains two absorbing species, X and Y. When a solution of this mixture is put into a 5.000 cm cell, the total absorbance of a mixture of X and Y at 300 nm is 0.372, while at 250 nm it is 0.478. The individual molar absorptivities of X and Y are as listed below. What are the individual concentrations of X and Y in this mixture?

250 nm

300 nm

eX

4.05 x 104 M-1 cm-1

3.22 x 104 M-1 cm-1

eY

3.76 x 104 M-1 cm-1

2.86 x 104 M-1 cm-1

2. An aqueous solution contains two absorbing species, X and Y. When a solution of this mixture is put into a 5.000 cm cell, the total absorbance of a mixture of X and Y at 300 nm is 0.372, while at 250 nm it is 0.478. The individual molar absorptivities of X and Y are as listed below. What are the individual concentrations of X and Y in this mixture? 250 nm 4.05 x 104 M-1 cm-1 3.76 x 104 Mi cm 300 nm 3.22 x 104 M-1 cm-1 2.86 x 104 M -1 cm -1 EY

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