Question

A solution containing a mixture of the compounds X and Y had an absorbance of 0.885 at 443 nm and arn absorbance of 0.760 at 520 nm when measured with a 1.00 cm cell. The molar absorptivities (e)of X and Y at each wavelength are shown in the table below. Wavelength Molar Absorptivity (E, Mcm) A, nm 443 520 16910 3989 4114 6619 What are the concentrations of X and Y in this mixture? Number Number

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Answer #1

The absorbance of the mix ture at any wavelength is the sum of absorbances of each component at that wavelength. The absorpti

F6 f -MMULT(MINVERSE(C5:D6),ES:E6)) 1) 2 bsorbance Concentration 4 Wavelength Concentration Matrix of unknown in mixtur 0.885

Therefore,

[X] = 2.96x10-5 M and [Y] = 9.64x10-5 M.

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