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A solution containing a mixture of the compounds X and Y had an absorbance of 1.06 at 443 nm and an absorbance of 0.909 at 52
Transmittance (%) 2976 am 3030 cm! The IR infrared) spectra of two pure compounds (0.010 M compound A in solvent and 0,010 M
0 0
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Answer #1

wave number (cm-1)

A

B

unknown

3030

0.456

0.0315

0.434

2976

0.119

0.377

0.339

Absorbance = A = E x b x C

wave number

A

B

3030

E = 45.6 M-cm-1

3.15 M-1 cm-1

2976

E = 11.9 M-1 cm-1

37.7 M-1 cm-1

0.434 = 45.6 A + 3.15 B ----------------------(1)

0.339 = 11.9 A + 37.7 B ---------------------(2)

by solving these two

A = 0.00909 M

B = 0.00612 M

H = qbc 443nmi- 1:06 = 14860x1x x + 3507x1xy > 0 520nm- => 0.909 = v + 5818 y 3616 ~ from egration 0 0; we get. - x=4.04x10

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