Suppose that the organic acid shown below has 3 acidic groups with pKa = 2, 4...
Suppose that the organic acid shown below has 3 acidic groups with pKa = 2, 4 and 10. If a solution containing this acid were adjusted to pH 10, what would the average net charge on each molecule be? Round your answer to 3 significant figures, and include the sign (no sign if the net charge is 0 or positive, use the
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Suppose that the organic acid shown below has 3 acidic groups
with pKa = 2, 4...
Organic Chemistry 4. Below are two molecules, B and C. Explain the differences in pKa of...
Organic Chemistry
4. Below are two molecules, B and C. Explain the differences in pKa of the two molecules by drawing the conjugate base of molecule C and a resonance structure that would not be found in molecule B. Hint: Draw out the NO2 group. conjugate base of molecule C pKa- 29.5 molecule B NO2 pka= 8.6 molecule C 5. Below is the molecule Abilify, which is a top selling drug that is used to treat schizophrenia, bipolar disorder and...
Biochemistry 4. The ionization of p-nitrophenol is shown below (pKa = 7.0): NO2 он weak acid...
Biochemistry
4. The ionization of p-nitrophenol is shown below (pKa = 7.0): NO2 он weak acid conjugate base a. (4 points) Identify the weak acid and conjugate base. b. (4 points)At pH 7, what are the relative concentrations of ionized and un-ionized p- nitrophenol? c. (4 points)If enough concentrated hydrochloric acid is added to a solution of p-nitrophenol to lower the pH from 7 to 5, what will happen to the relative concentrations of the ionized and un-ionized forms? d....
2. A structure of Luminol is shown with all functional groups protonated and their pka labeled....
2. A structure of Luminol is shown with all functional groups protonated and their pka labeled. Use words and structures to answer a and b. Luminol pke 2 9 a. Acetic acid was added at the end of the reduction step to obtain a pH of - 3-4.2pts i. Draw the structure of the luminol at pH 3. ii. Refering to the structure in a.i.), explain why the luminol precipitates from the aqueous solution at this pH. NH₂ NH N-H...
2. Soda has a pH between 3 and 4. Soda makers often add citric acid to give a tart taste to soda....
2. Soda has a pH between 3 and 4. Soda makers often add citric acid to give a tart taste to soda. 20 ml of 0.1 M citric acid (H 3C6H57, pa 3.1, pKa2 4.7, pKa3 6.4) is titrated with 0.1 M NaOH a2 4.7, pka3 6.4) is titrated pH 0 10 20 30 40 50 60 volume of NaOH Citric acid can be used as a buffer. The formula and charge of citric acid (H3CsH5o7, H2C6Hso, HCGH,o, CH3) depends...
13. Imagine there is one large molecule with 4 carboxylic acids. It has 4 pKas: 2,...
13. Imagine there is one large molecule with 4 carboxylic acids. It has 4 pKas: 2, 4, 6, 8. What is the overall net charge of the molecule in a solution with a pH of 1? A. O B. -1 C. +1 D. -2 E. + 2 F. -3 G. +3 H.-4 14. For the same molecule in the above question, what is its overall net charge in a neutral solution? A. O B. -1 1 C. + D ....
Integrated Problems #12 Common aspirin is acetylsalicylic acid, which has the structure shown below and a...
Integrated Problems #12 Common aspirin is acetylsalicylic acid, which has the structure shown below and a pKa of 3.5. The acidic hydrogen is indicated with the star. H 30: ö-H ö-C-C-H :0: H 1) What is the shape and hybridization around the carbon 1, carbon 2. oxygen 3. 2) What is the bond angle at 1, 2, 3? 3) What types of intermolecular interactions is this molecule capable? 4) Is acetylsalicylic acid a strong or weak acid? 5) Write a...
2. Soda has a pH between 3 and 4. Soda makers often add citric acid to give a tart taste to soda....
2. Soda has a pH between 3 and 4. Soda makers often add citric acid to give a tart taste to soda. 20 ml of 0.1 M citric acid (H 3CGH5 with 0.1 M NaOH pKa1 3.1, pKa2 4.7, pKa3 6.4) is titrated pH 0 10 20 30 40 50 60 volume of NaOH Citric acid can be used as a buffer. The formula and charge of citric acid (H3CHso7, H2CsH,0, H,o,2, CgH,o,3) depends on the pH. d. What is...
5. D-sorbital is found in 'sugar-free' chewing gum. It is formed by reducing D-glucose with NaBH Draw the structure of D-sorbital. s. (4 pts) Classify the following amino acid as polar, n...
5. D-sorbital is found in 'sugar-free' chewing gum. It is formed by reducing D-glucose with NaBH Draw the structure of D-sorbital. s. (4 pts) Classify the following amino acid as polar, non- polar, acidic, or basic: 6 (4 pts) The amino acid threonine (thr) has two chiral carbons. Draw a Fischer projection of the 2S,3S configuration of threonine. キ 7.(11 pts) Draw the tripeptide lys-asp-ser at physiological pH 8. (8 pts) The pK, values for aspartic acid are 2.10, 9.82...
2. A particular sample of vinegar has a pH of 2.95. Part A If acetic acid...
2. A particular sample of vinegar has a pH of 2.95. Part A If acetic acid is the only acid that vinegar contains (Ka=1.8×10−5), calculate the concentration of acetic acid in the vinegar. Express your answer using two significant figures. 3.A new potential heart medicine, code-named X-281, is being tested by a pharmaceutical company, Pharma-pill. As a research technician at Pharma-pill, you are told that X-281 is a monoprotic weak acid, but because of security concerns, the actual chemical formula...
5. The Latimer diagram for nitrogen in acidic solutions is shown below: +5 +4 +3 +2...
5. The Latimer diagram for nitrogen in acidic solutions is shown below: +5 +4 +3 +2 +1 0 -1 -2 -3 0.80 1.07 1.00 1.59 1.77 -1.87 1.41 1.28 NO3- ? N2O4 ? HNO2 ? NO ? N2O ? N2 ? NH3OH+ ? N2H5+ ? NH4+ (a) Write a balanced half reaction for reduction of NO to NH4+ in acid. (b) What is the value of Eo for the half reaction in part (a)? (c) Is this half reaction more...
Organic Chemistry
4. Below are two molecules, B and C. Explain the differences in pKa of the two molecules by drawing the conjugate base of molecule C and a resonance structure that would not be found in molecule B. Hint: Draw out the NO2 group. conjugate base of molecule C pKa- 29.5 molecule B NO2 pka= 8.6 molecule C 5. Below is the molecule Abilify, which is a top selling drug that is used to treat schizophrenia, bipolar disorder and...
Biochemistry
4. The ionization of p-nitrophenol is shown below (pKa = 7.0): NO2 он weak acid conjugate base a. (4 points) Identify the weak acid and conjugate base. b. (4 points)At pH 7, what are the relative concentrations of ionized and un-ionized p- nitrophenol? c. (4 points)If enough concentrated hydrochloric acid is added to a solution of p-nitrophenol to lower the pH from 7 to 5, what will happen to the relative concentrations of the ionized and un-ionized forms? d....
2. A structure of Luminol is shown with all functional groups protonated and their pka labeled. Use words and structures to answer a and b. Luminol pke 2 9 a. Acetic acid was added at the end of the reduction step to obtain a pH of - 3-4.2pts i. Draw the structure of the luminol at pH 3. ii. Refering to the structure in a.i.), explain why the luminol precipitates from the aqueous solution at this pH. NH₂ NH N-H...
2. Soda has a pH between 3 and 4. Soda makers often add citric acid to give a tart taste to soda. 20 ml of 0.1 M citric acid (H 3C6H57, pa 3.1, pKa2 4.7, pKa3 6.4) is titrated with 0.1 M NaOH a2 4.7, pka3 6.4) is titrated pH 0 10 20 30 40 50 60 volume of NaOH Citric acid can be used as a buffer. The formula and charge of citric acid (H3CsH5o7, H2C6Hso, HCGH,o, CH3) depends...
13. Imagine there is one large molecule with 4 carboxylic acids. It has 4 pKas: 2, 4, 6, 8. What is the overall net charge of the molecule in a solution with a pH of 1? A. O B. -1 C. +1 D. -2 E. + 2 F. -3 G. +3 H.-4 14. For the same molecule in the above question, what is its overall net charge in a neutral solution? A. O B. -1 1 C. + D ....
Integrated Problems #12 Common aspirin is acetylsalicylic acid, which has the structure shown below and a pKa of 3.5. The acidic hydrogen is indicated with the star. H 30: ö-H ö-C-C-H :0: H 1) What is the shape and hybridization around the carbon 1, carbon 2. oxygen 3. 2) What is the bond angle at 1, 2, 3? 3) What types of intermolecular interactions is this molecule capable? 4) Is acetylsalicylic acid a strong or weak acid? 5) Write a...
2. Soda has a pH between 3 and 4. Soda makers often add citric acid to give a tart taste to soda. 20 ml of 0.1 M citric acid (H 3CGH5 with 0.1 M NaOH pKa1 3.1, pKa2 4.7, pKa3 6.4) is titrated pH 0 10 20 30 40 50 60 volume of NaOH Citric acid can be used as a buffer. The formula and charge of citric acid (H3CHso7, H2CsH,0, H,o,2, CgH,o,3) depends on the pH. d. What is...
5. D-sorbital is found in 'sugar-free' chewing gum. It is formed by reducing D-glucose with NaBH Draw the structure of D-sorbital. s. (4 pts) Classify the following amino acid as polar, non- polar, acidic, or basic: 6 (4 pts) The amino acid threonine (thr) has two chiral carbons. Draw a Fischer projection of the 2S,3S configuration of threonine. キ 7.(11 pts) Draw the tripeptide lys-asp-ser at physiological pH 8. (8 pts) The pK, values for aspartic acid are 2.10, 9.82...
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