Major Products for all of these 1. a. AICl3 CH3 b. then H30+/H2O 2. Zn(Hg), HCI...
Draw the major product for each reaction. он. CH3 heat N(CH3)3 a. LiAIH4, Et20 b. H30*/H20 1. NaCN, DMSO Br 2. a. LiAIH4. THF b. H3O+/H2O 1. NaN3, DMSO Br 2. a. LiAIH4, THF b. H3O /H20 1. HNO3, H2SO4 2. SnCl2 3. Br2 4. a. HNO2, H2SO4 H3C b. H2PO2 NH2 1. NaNO2, HCI, H20 но 2. HBF4
1. Predict the major product for the following reaction. (12 points) CN Zn(Hg/HCI 1. LIAIHA 2. H3O+ a 1. LIAIH mCPBA NaN3 b 2. H20 + enantiomer С. NH2 N,CI CN COOH d NaCN 1. LIAIHA Br 2. H20 e. (CH3)2NH H2SO4 2. H30*
Draw the major product(s) of the following reactions. 1) HNO3 H2S0 2) Zn, HCi Br 1) AICl3, CI 2) Zn(Hg), HCl, heat 1) CH3CI, AICI3 2) KMnO4, NaOH, heat 3) H3o 1)CH3C, AIC 2) Excess NBS
1. Predict the major product for the following reaction. (12 points) CN Zn(Hg) HCI 1. LIAH 2. H30+ 1. LIAIHA mCPBA NaN, 2. H₂O + enantiomer NH2 ON & CN COOH NaCN 1. LIAIH 2. H20 Br (CH3)2NH H2SO4 2. H30*
4. Provide sturctures for ALL major products (3 points each) CEN HC NaOEVETOH HEC CH2 0.05eq. NOE CH3 EtOH Cl2 Нас Br2 CH3COOH сн. H,O, HCI H3C CHE H₃C H20 OCH heat 1. LDA THF CHE 2. CH31 CHE + CH3 сн. CH3 CH; 2. H2O CH3
1) Reactions. Provide the major products for each reaction sequence, account for stereochemistry 1) KMnO4, A 2) SOCI, CH2Cl2 3) 2 equiv. 1) ethylene oxide, THF 2) H3O+ workup Culi 3) DIBAL-H, THF 4) H3O+ workup 5) cat. TsOH, THF H3CCHE (c) HN COH 1) excess LAH, THE 2) H30+ workup 3) 1 equiv. EtN, DMF 4) pyridine i ( " culi , THF (d) PC Ph 2) H3O+/H2O workup 3) KMnO4, A 4) CH,OH, cat. H2SO4 5) cat. TsOH,...
2) Provide the structure of the major organic product of the reaction below. -CH3 Br2, H2O 3) Draw the major organic product generated in the reaction below. Pay particular attention to regio- and stereochemical detail. H, H20 dilute aqueous acid 4) Draw the major organic product generated in the reaction below. Pay particular attention to regio- and stereochemical detail. CH3 1. Hg(OAc)2, H20 2. NaBH 5) Provide the structure of the major organic product of the reaction below. 1. BH3...
Problem #1 Predict the major product(s) from the following reactions: M CH₂ 1.03 ? 2. DMS b) CH3 НАС 1. CH2CO3H 2. H30+ CH3
CH3 CH3 1. Hg(OAC), H20 2. NaBH НО, І CH3 CH, Hoc H₃C/ Acid-catalyzed addition of water to an alkene yields an alcohol with Markovnikov regiochemistry. The electrophilic H adds to the sp carbon with the most hydrogens to yield the most stable carbocation intermediate, which then adds water to give the product alcohol. Because a carbocation intermediate is formed, rearrangements can occur prior to the addition of water. To avoid the possibility of rearrangement and still give a Markovnikov...
draw final products and intermediates a) O 1. C1 CH3, AlCl3 2. Br2, FeBrz 3. Ph-B(OH)2 Pd(OAc)2, PPh3, NaOH 4. Zn(Hg), HCI