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Question Three a. For each chiral centre in the...
3. (4 pts) Complete the Fischer projection drawn below by adding the four substituents to the chiral carbon of (s)...
3. (4 pts) Complete the Fischer projection drawn below by adding the four substituents to the chiral carbon of (s)-2-methyl-3-bromo-hexane. 4. (4 pts) Draw a wedge and dash structure representing (1R 2R,3S)-1,2- dichloro3-ethylcyclohexane. 5. (4pts) 2-bromobutane is shown below. Is this (R)-2-bromobutane or (S)-2 bromobutane? 6. (6 pts) For each chiral carbon in ascorbic acid (vitamin C), shown below, assign Ror S to each stereocenter. How many stereoisomers of ascorbic acid are possible? OH HO ОН 7. (9 pts) (Are...
7. (9 pts) (Are the following optically active or meso? meso HyCHC OH HO opticaly actve...
7. (9 pts) (Are the following optically active or meso? meso HyCHC OH HO opticaly actve active opti call active 8. (3 pts) How many stereoisomers are there of 2,3-dibromobutane? 4 sleeoisamvers (8 pts) Circle the letter of the statements that are true. a. Racemic mixtures are optically active Enantiomers have specific rotations that are equal, but have opposite signs 9. o adtc) Achiral molecules are optically inactive d Meso compounds contain equal amounts of enantiomers 4pts) Complete the Fischer...
4. (26 points) Identify each chiral carbon in the molecules below with an asterisk (*) and...
4. (26 points) Identify each chiral carbon in the molecules below with an asterisk (*) and assign R or s absolute configuration to each chiral carbon. Then, state (in the box provided) whether the molecules are enantiomers, identical, diastereomers, or not related. Hint: if it looks like a Fischer projection then it is a Fischer projection. ...1111 O піон аnd and .Ley O Era o C CHO CH,OH C. H oH and OHCH IH Сн,он
19-26 thanks! 19-29* PART 3: 2,3-BUTANEDIOL CH-CH(OH)-CH(OH)-CH, mirror images, not superimposable Build as many models of...
19-26 thanks!
19-29*
PART 3: 2,3-BUTANEDIOL CH-CH(OH)-CH(OH)-CH, mirror images, not superimposable Build as many models of 2,3-butanediol as you can. First, attach two carbons with a single bond. To each carbon add one carbon, one hydrogen, and one oxygen. To complete the structure, Ti the remaining hydrogen atoms. Remember, a model is not different if it is completely superimposable on one already constructed! 13. How many stereochemically different models are possible for 2,3-butanediol? 14. What characteristic does one of these...
Analyze each pair of compounds structures represent. Your cho cach pair of compounds below. Identify which...
Analyze each pair of compounds structures represent. Your cho cach pair of compounds below. Identify which class of isomers each pair of s represent. Your choices are: (i) constitutional, (ii) conformational, (iii) omers, (iv) diastereomer or (v) identical (non-isomers). Only one label for each pair should be used. For each case show work (drawings, (R)/(S), rotation of bonds, chair- "ps, etc) which led you to each answer for the pairs below. Any differences of answers between you and your peers...
H 9. For each molecule: 1) Identify all possible enantiomers and distinguish those that are enantiomers, diastereomers...
H 9. For each molecule: 1) Identify all possible enantiomers and distinguish those that are enantiomers, diastereomers and meso compounds. II) Assign the absolute configuration of chiral carbons in each molecule OCH3 HO+Br HS+CN H2N-CH3 HOSH Он HO+CH3 н OCH3 Сн, ососна Br +D HOCH HC-BrHN+Br CH 8. For the following compounds, assign the absolute configuration for those with chiral carbons and identify those that are NOT enantiomers HO C-C-OHY -CCIN 13CH3 HAN CH3 CH3 осі H-CH3 H2N+CH H O+COOH...
4. Absolute Configuration and R/S Sequence Rules. In 3 you constructed models with two stereocenters that...
4. Absolute Configuration and R/S Sequence Rules. In 3 you constructed models with two stereocenters that represented 4 stereoisomers. 2,3-Dibromobutanoic acid exemplifies such a compound, Make models for the isomers of this compound. a. Draw solid/dashed-wedge structures for the 4 possible stereoisomers and label the enantiomers and diastereomers. b. Specify the sequence priority for the substituents on carbon-2 and carbon-3. Label each structure with the proper R/S notation in the drawings above, for example (2R, 35). d. Draw Newman projections...
A. Which of the following Newman projections would represent the least stable conformer of 2,2,3....
PLEASE HELP WITH ALL.
A. Which of the following Newman projections would represent the least stable conformer of 2,2,3.3-tetramethylbutane, looking down the 2,3 bond? H3C H3C H3C H3C CH3 b) CH3 H3C e) a) c) CH3 H3C CH3 CH CH3 CH о он B. which one of the following compounds would be chiral? Br он о он a) но HO O он HO C C. which of the following could potentially be used to distinguish between enantiomers? b) NMR c)...
Key concepts: molecular represenations, stereolsomers, RS enantiomeric excess, IPAC naming covention Provide the IUPAC name for...
Key concepts: molecular represenations, stereolsomers, RS enantiomeric excess, IPAC naming covention Provide the IUPAC name for each of the following molecules 0% HJC BM How similar are the names for B and C, even though there is the single change to the structure 2 Rank the priorities of these functional groups and substituents using Cahn-Ingold-Prelog nomenclature. Highest priority will be 1 and lowest will be 5; show your rationale CH:CH:CH CH CHCH:CH CHs,-SCH,-CH: CH:CH:CHCH CHCH, -CH2NHOH,-CH:NO Draw dash/wedge representations for...
3. (4 pts) Complete the Fischer projection drawn below by adding the four substituents to the chiral carbon of (s)-2-methyl-3-bromo-hexane. 4. (4 pts) Draw a wedge and dash structure representing (1R 2R,3S)-1,2- dichloro3-ethylcyclohexane. 5. (4pts) 2-bromobutane is shown below. Is this (R)-2-bromobutane or (S)-2 bromobutane? 6. (6 pts) For each chiral carbon in ascorbic acid (vitamin C), shown below, assign Ror S to each stereocenter. How many stereoisomers of ascorbic acid are possible? OH HO ОН 7. (9 pts) (Are...
7. (9 pts) (Are the following optically active or meso? meso HyCHC OH HO opticaly actve active opti call active 8. (3 pts) How many stereoisomers are there of 2,3-dibromobutane? 4 sleeoisamvers (8 pts) Circle the letter of the statements that are true. a. Racemic mixtures are optically active Enantiomers have specific rotations that are equal, but have opposite signs 9. o adtc) Achiral molecules are optically inactive d Meso compounds contain equal amounts of enantiomers 4pts) Complete the Fischer...
4. (26 points) Identify each chiral carbon in the molecules below with an asterisk (*) and assign R or s absolute configuration to each chiral carbon. Then, state (in the box provided) whether the molecules are enantiomers, identical, diastereomers, or not related. Hint: if it looks like a Fischer projection then it is a Fischer projection. ...1111 O піон аnd and .Ley O Era o C CHO CH,OH C. H oH and OHCH IH Сн,он
19-26 thanks!
19-29*
PART 3: 2,3-BUTANEDIOL CH-CH(OH)-CH(OH)-CH, mirror images, not superimposable Build as many models of 2,3-butanediol as you can. First, attach two carbons with a single bond. To each carbon add one carbon, one hydrogen, and one oxygen. To complete the structure, Ti the remaining hydrogen atoms. Remember, a model is not different if it is completely superimposable on one already constructed! 13. How many stereochemically different models are possible for 2,3-butanediol? 14. What characteristic does one of these...
Analyze each pair of compounds structures represent. Your cho cach pair of compounds below. Identify which class of isomers each pair of s represent. Your choices are: (i) constitutional, (ii) conformational, (iii) omers, (iv) diastereomer or (v) identical (non-isomers). Only one label for each pair should be used. For each case show work (drawings, (R)/(S), rotation of bonds, chair- "ps, etc) which led you to each answer for the pairs below. Any differences of answers between you and your peers...
H 9. For each molecule: 1) Identify all possible enantiomers and distinguish those that are enantiomers, diastereomers and meso compounds. II) Assign the absolute configuration of chiral carbons in each molecule OCH3 HO+Br HS+CN H2N-CH3 HOSH Он HO+CH3 н OCH3 Сн, ососна Br +D HOCH HC-BrHN+Br CH 8. For the following compounds, assign the absolute configuration for those with chiral carbons and identify those that are NOT enantiomers HO C-C-OHY -CCIN 13CH3 HAN CH3 CH3 осі H-CH3 H2N+CH H O+COOH...
4. Absolute Configuration and R/S Sequence Rules. In 3 you constructed models with two stereocenters that represented 4 stereoisomers. 2,3-Dibromobutanoic acid exemplifies such a compound, Make models for the isomers of this compound. a. Draw solid/dashed-wedge structures for the 4 possible stereoisomers and label the enantiomers and diastereomers. b. Specify the sequence priority for the substituents on carbon-2 and carbon-3. Label each structure with the proper R/S notation in the drawings above, for example (2R, 35). d. Draw Newman projections...
PLEASE HELP WITH ALL.
A. Which of the following Newman projections would represent the least stable conformer of 2,2,3.3-tetramethylbutane, looking down the 2,3 bond? H3C H3C H3C H3C CH3 b) CH3 H3C e) a) c) CH3 H3C CH3 CH CH3 CH о он B. which one of the following compounds would be chiral? Br он о он a) но HO O он HO C C. which of the following could potentially be used to distinguish between enantiomers? b) NMR c)...
Key concepts: molecular represenations, stereolsomers, RS enantiomeric excess, IPAC naming covention Provide the IUPAC name for each of the following molecules 0% HJC BM How similar are the names for B and C, even though there is the single change to the structure 2 Rank the priorities of these functional groups and substituents using Cahn-Ingold-Prelog nomenclature. Highest priority will be 1 and lowest will be 5; show your rationale CH:CH:CH CH CHCH:CH CHs,-SCH,-CH: CH:CH:CHCH CHCH, -CH2NHOH,-CH:NO Draw dash/wedge representations for...
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