1. The hydroperoxide (ROOH) was treated with Dimethyl Sulfide
(DMS) resulting in alcohol (OH). Please show the mechanism and
arrow-pushing of how the product was produce, thank
you!
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1. The hydroperoxide (ROOH) was treated with Dimethyl Sulfide
(DMS) resulting in alcohol (OH). Please show...
1. The 1,4-endoperoxide is treated with Dimethyl Sulfide (DMS). Please show the mechanism and arrow-pushing of...
1. The 1,4-endoperoxide is treated with Dimethyl Sulfide (DMS).
Please show the mechanism and arrow-pushing of how the product
(epoxide) was created as a result of the DMS. Thank you!
CH3 С. С НО — О О HO С НЫС S— СН3 О M О О H
1. 1,2-dihydro-6,6-dimethylfulvene undergoes singlet oxygenation (1O2) producing an unstable saturated endoperoxide. Please show the mechanism and...
1. 1,2-dihydro-6,6-dimethylfulvene undergoes singlet oxygenation
(1O2) producing an unstable
saturated endoperoxide. Please show the mechanism and arrow pushing
of how the endoperoxide was created. Thank you!
СН3 Н.С. CH3 ЭН CH, С. НО — О НО -О 1о, О О
Please explain. I need both part a and b. thank you. 2. Alcohol Reaction Mechanism Fill...
Please explain. I
need both part a and b. thank you.
2. Alcohol Reaction Mechanism Fill in the major organic product and draw a complete curved-arrow mechanism a. H-Br OH b. How would the above reaction change if sulfuric acid were used instead? Why?
1)Draw all alkene prodcuts that could form 2) Circle the major alkene product expected 3) Draw...
1)Draw all alkene prodcuts that could form
2) Circle the major alkene product expected
3) Draw a complete arrow pushing mechanism how the major
product is formed. (Show all srrows, intermediate structures,
formal charges)
2. (19pts) The alcohol dehydration product below is of the El type elimination. (i) Draw all of the alkene products that could possibly form. (ii) Circle the major alkene product expected. (ii) Draw a complete curved arrow-pushing mechanism illustrating how the major product is formed. Be...
2 problems REVIEW Topics [References) CH HC OCH Br2 CH3 B H3C CH,OH H₂C CH₂ Electrophilic...
2 problems
REVIEW Topics [References) CH HC OCH Br2 CH3 B H3C CH,OH H₂C CH₂ Electrophilic addition of hypohalous acids to alkenes yields a 1,2-haloalcohol called a halohydrin. Halohydrin formation, however, does not result from the addition of HOBr, for example. Instead the addition is done indirectly by reaction of the alkene with Br, in the presence of water. The reaction also works with Cl2 to give chlorohydrins instead of bromohydrins. The reaction proceeds through a cyclic intermediate known as...
(Review Topics 1. Hg(OAC)2, H20 2. NaBH, . H2O OH CHI CH3 H3C H3C Hoc Acid-catalyzed...
(Review Topics 1. Hg(OAC)2, H20 2. NaBH, . H2O OH CHI CH3 H3C H3C Hoc Acid-catalyzed addition of water to an alkene yields an alcohol with Markovnikov repiochemistry. The electrophilic adds to the sp? carbon with the most hydrogens to yield the most stable carbocation intermediate, which then adds water to give the product alcohol Because a carbocation intermediate is formed, rearrangements can occur prior to the addition of water To avoid the possibility of rearrangement and still give a...
CHO 1. NH2OH 2. Ac2o 3. CH,O CHO OH H- HO H HO H HCN H...
CHO 1. NH2OH 2. Ac2o 3. CH,O CHO OH H- HO H HO H HCN H OH OH H- OH H- -OH H- CH2OH CH2OH The Wohl degradation is a series of reactions that shorten an aldose chain by one carbon, it is almost the exact opposite of the Kiliani In this reaction the aldose aldehyde carbonyl group is converted into a nitrile. The resulting cyanohydrin loses HCN under basic cone Conversion of the aldehyde to a nitrile is accomplished...
please explain as soon as possible thank you!!!!! aq NaOH © Captas "OH 30. For 1...
please explain as soon as possible thank you!!!!!
aq NaOH © Captas "OH 30. For 1 pt extra credit each, give the color of the copper before and after the reaction occurs, and the name of this test. COOH 이 H- OH --OH H- OH CH,OH CH, OH Color blue to red, Benedict's test 31. Fill in both the intermediate structure and the structure of the final product. н,со он CH,OH/H" H.CO CH, OH OCH remove water 32. mild HS-CH3...
Can you please show me only step 1 with lone pairs and arrows if needed please....
Can
you please show me only step 1 with lone pairs and arrows if needed
please. I want to input it as it is asking. thank you!
Propose a plausible mechanism for the following transformation For the mechanism, draw the curved arrows as needed. Include lone pairs and charges in your answer. Do not draw out any hydrogen explicitly in your products. Do not use abbreviations such as Me or Ph. i + HI . MeOH + H20 ОН OMo...
Please show all work for Number 5: CH3OH and number 3, HF one. Thank you Complete...
Please show all work for
Number 5: CH3OH and number 3, HF one. Thank you
Complete the following reaction and provide forget resonance structures when applicable. a. a detailed arrow-pushing mechanism. Don't HF OH 5. (28 pt.) Complete the following reactions with the correct structures of starting material or product(s) Indicate 'major' and 'minor' if applicable. Don't forget to specify the stereochemistry and draw both enantiomers if applicable. Provide mechanism only if indicated. Cl2/H20 Et AV Use the provided template...
1. The 1,4-endoperoxide is treated with Dimethyl Sulfide (DMS).
Please show the mechanism and arrow-pushing of how the product
(epoxide) was created as a result of the DMS. Thank you!
CH3 С. С НО — О О HO С НЫС S— СН3 О M О О H
1. 1,2-dihydro-6,6-dimethylfulvene undergoes singlet oxygenation
(1O2) producing an unstable
saturated endoperoxide. Please show the mechanism and arrow pushing
of how the endoperoxide was created. Thank you!
СН3 Н.С. CH3 ЭН CH, С. НО — О НО -О 1о, О О
Please explain. I
need both part a and b. thank you.
2. Alcohol Reaction Mechanism Fill in the major organic product and draw a complete curved-arrow mechanism a. H-Br OH b. How would the above reaction change if sulfuric acid were used instead? Why?
1)Draw all alkene prodcuts that could form
2) Circle the major alkene product expected
3) Draw a complete arrow pushing mechanism how the major
product is formed. (Show all srrows, intermediate structures,
formal charges)
2. (19pts) The alcohol dehydration product below is of the El type elimination. (i) Draw all of the alkene products that could possibly form. (ii) Circle the major alkene product expected. (ii) Draw a complete curved arrow-pushing mechanism illustrating how the major product is formed. Be...
2 problems
REVIEW Topics [References) CH HC OCH Br2 CH3 B H3C CH,OH H₂C CH₂ Electrophilic addition of hypohalous acids to alkenes yields a 1,2-haloalcohol called a halohydrin. Halohydrin formation, however, does not result from the addition of HOBr, for example. Instead the addition is done indirectly by reaction of the alkene with Br, in the presence of water. The reaction also works with Cl2 to give chlorohydrins instead of bromohydrins. The reaction proceeds through a cyclic intermediate known as...
(Review Topics 1. Hg(OAC)2, H20 2. NaBH, . H2O OH CHI CH3 H3C H3C Hoc Acid-catalyzed addition of water to an alkene yields an alcohol with Markovnikov repiochemistry. The electrophilic adds to the sp? carbon with the most hydrogens to yield the most stable carbocation intermediate, which then adds water to give the product alcohol Because a carbocation intermediate is formed, rearrangements can occur prior to the addition of water To avoid the possibility of rearrangement and still give a...
CHO 1. NH2OH 2. Ac2o 3. CH,O CHO OH H- HO H HO H HCN H OH OH H- OH H- -OH H- CH2OH CH2OH The Wohl degradation is a series of reactions that shorten an aldose chain by one carbon, it is almost the exact opposite of the Kiliani In this reaction the aldose aldehyde carbonyl group is converted into a nitrile. The resulting cyanohydrin loses HCN under basic cone Conversion of the aldehyde to a nitrile is accomplished...
please explain as soon as possible thank you!!!!!
aq NaOH © Captas "OH 30. For 1 pt extra credit each, give the color of the copper before and after the reaction occurs, and the name of this test. COOH 이 H- OH --OH H- OH CH,OH CH, OH Color blue to red, Benedict's test 31. Fill in both the intermediate structure and the structure of the final product. н,со он CH,OH/H" H.CO CH, OH OCH remove water 32. mild HS-CH3...
Can
you please show me only step 1 with lone pairs and arrows if needed
please. I want to input it as it is asking. thank you!
Propose a plausible mechanism for the following transformation For the mechanism, draw the curved arrows as needed. Include lone pairs and charges in your answer. Do not draw out any hydrogen explicitly in your products. Do not use abbreviations such as Me or Ph. i + HI . MeOH + H20 ОН OMo...
Please show all work for
Number 5: CH3OH and number 3, HF one. Thank you
Complete the following reaction and provide forget resonance structures when applicable. a. a detailed arrow-pushing mechanism. Don't HF OH 5. (28 pt.) Complete the following reactions with the correct structures of starting material or product(s) Indicate 'major' and 'minor' if applicable. Don't forget to specify the stereochemistry and draw both enantiomers if applicable. Provide mechanism only if indicated. Cl2/H20 Et AV Use the provided template...
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