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6. Suppose that the electron in a hydrogen atom is perturbed by a...
Problem 3: Time-Independent Perturbation Theory Consider the particle in a 1D box of size L, as...
Problem 3: Time-Independent Perturbation Theory Consider the particle in a 1D box of size L, as in Fig. 3. A perturbation of the form. V,δ ((x-2)2-a2) with a < L is applied to the unperturbed Hamiltonian of the 1D particle in a box (solutions on the equation sheet). Here V is a constant with units of energy. Remember the following propertics of the Dirac delta function m,f(x)6(x-a)dx f(a) 6(az) が(z) = = ds( dz E, or Ψ(x)-En 10 0.0 0.2...
Please thoroughly explain these answers. the correct answers are marked, but i do not understand....
please thoroughly explain these answers. the correct answers are
marked, but i do not understand. also, when is the perturbation
theory preferred over the variation theory and why?
Question A: A particle of mass m in a box of length a has a potential energy inside the box that can be expressed as a linear function of position, i.c, v -kx, where k is a constant. (Assume that the system can be treated using perturbation theory)mo v 1. What would...
4. This problems deals with sudden approximation, please do not use perturbation theory. (a) (1 p...
4. This problems deals with sudden approximation, please do not use perturbation theory. (a) (1 point) The system is described by the Hamiltonian t < 0, Ho+V, t>0 - and neither Ho nor V depends on time. Assuming that the system was in the eigenstate n) of Ho at t < 0, find the probability to find the system in the eigenstate V) of Ho V at t>0. (b) (5 points) Consider a particle in the ground state an infinite...
3. A particle of mass m moves in one dimension, and has position r(t) at time t. The particle has...
Mechanics.
3. A particle of mass m moves in one dimension, and has position r(t) at time t. The particle has potential energy V(x) and its relativistic Lagrangian is given by where mo is the rest mass of the particle and c is the speed of light (a) Writing qr and denoting by p its associated canonical momenta, show that the Hamiltonian is given by (show it from first principles rather than using the energy mzc2 6 marks (b) Write...
1. A particle, initially (t -> 0) in the ground state of an infinite, 1D potential...
1. A particle, initially (t -> 0) in the ground state of an infinite, 1D potential box with walls at r 0 and = a, is subjected at time t = 0 to a time-dependent perturbation V (r, t) et/7, with eo a small real number a) Calculate to first order the probability of finding the particle in an excited state for t 0. Consider all final states. Are all possible transitions allowed? b) Examine the time dependence of the...
4. Estimate the transition frequency for the poryphyrin molecule from m-11 to m 12, assuming that the pi electrons can be modeled as a particle in a ring of radius 440 picometers. (C 7. The...
4. Estimate the transition frequency for the poryphyrin molecule from m-11 to m 12, assuming that the pi electrons can be modeled as a particle in a ring of radius 440 picometers. (C 7. The most probable distance of the electron from the nucleus in a 1ls state hydrogen atom (with wavefunction V1) can be determined by 21. A (A) solving the eigenvalue equation: Rvw rV., finding the maximum in the 1s radial distribution function by differentiation. (C) substituting vi,...
1. A particle of mass m moves in three dimensions, and has position r(t)-(x(t), y(t), z(t)) at ti...
Mechanics. Need help with c) and d)
1. A particle of mass m moves in three dimensions, and has position r(t)-(x(t), y(t), z(t)) at time t. The particle has potential energy V(x, y, 2) so that its Lagrangian is given by where i d/dt, dy/dt, dz/dt (a) Writing q(q2.93)-(r, y, z) and denoting by p (p,P2, ps) their associated canonical momenta, show that the Hamiltonian is given by (show it from first principles rather than using the energy) H(q,p)H(g1, 92,9q3,...
Consider a particle in a 1-d well with potential V(x) =-U for-d < x < d,...
Consider a particle in a 1-d well with potential V(x) =-U for-d < x < d, and V(z) 0 elsewhere. We will use the variational wave function v(z) = A(b + r), t(x)-A(b-x), -b < r < 0, 0 < x < b, to show that a bound state exists for any U0. a) Normalize the wave function. Find the expectation values of the kinetic and potential energies b) Show that for sufficiently large b, with b> d, the expectation...
3. Consider a particle of mass m moving in a potential given by: W (2, y,...
3. Consider a particle of mass m moving in a potential given by: W (2, y, z) = 0 < x <a,0 < y <a l+o, elsewhere a) Write down the total energy and the 3D wavefunction for this particle. b) Assuming that hw > 312 h2/(2ma), find the energies and the corresponding degen- eracies for the ground state and the first excited state. c) Assume now that, in addition to the potential V(x, y, z), this particle also has...
Question 8 please 5. We start with Schrodinger's Equation in 2(x,t) = H¥(x,t). We can write...
Question 8 please
5. We start with Schrodinger's Equation in 2(x,t) = H¥(x,t). We can write the time derivative as 2.4(x, t) = V(x,+) - (xt), where At is a sufficiently small increment of time. Plug the algebraic form of the derivative into Schrodinger's Eq. and solve for '(x,t+At). b. Put your answer in the form (x,t+At) = T '(x,t). c. What physically does the operator T do to the function '(x,t)? d. Deduce an expression for '(x,t+24t), in terms...
Problem 3: Time-Independent Perturbation Theory Consider the particle in a 1D box of size L, as in Fig. 3. A perturbation of the form. V,δ ((x-2)2-a2) with a < L is applied to the unperturbed Hamiltonian of the 1D particle in a box (solutions on the equation sheet). Here V is a constant with units of energy. Remember the following propertics of the Dirac delta function m,f(x)6(x-a)dx f(a) 6(az) が(z) = = ds( dz E, or Ψ(x)-En 10 0.0 0.2...
please thoroughly explain these answers. the correct answers are
marked, but i do not understand. also, when is the perturbation
theory preferred over the variation theory and why?
Question A: A particle of mass m in a box of length a has a potential energy inside the box that can be expressed as a linear function of position, i.c, v -kx, where k is a constant. (Assume that the system can be treated using perturbation theory)mo v 1. What would...
4. This problems deals with sudden approximation, please do not use perturbation theory. (a) (1 point) The system is described by the Hamiltonian t < 0, Ho+V, t>0 - and neither Ho nor V depends on time. Assuming that the system was in the eigenstate n) of Ho at t < 0, find the probability to find the system in the eigenstate V) of Ho V at t>0. (b) (5 points) Consider a particle in the ground state an infinite...
Mechanics.
3. A particle of mass m moves in one dimension, and has position r(t) at time t. The particle has potential energy V(x) and its relativistic Lagrangian is given by where mo is the rest mass of the particle and c is the speed of light (a) Writing qr and denoting by p its associated canonical momenta, show that the Hamiltonian is given by (show it from first principles rather than using the energy mzc2 6 marks (b) Write...
1. A particle, initially (t -> 0) in the ground state of an infinite, 1D potential box with walls at r 0 and = a, is subjected at time t = 0 to a time-dependent perturbation V (r, t) et/7, with eo a small real number a) Calculate to first order the probability of finding the particle in an excited state for t 0. Consider all final states. Are all possible transitions allowed? b) Examine the time dependence of the...
4. Estimate the transition frequency for the poryphyrin molecule from m-11 to m 12, assuming that the pi electrons can be modeled as a particle in a ring of radius 440 picometers. (C 7. The most probable distance of the electron from the nucleus in a 1ls state hydrogen atom (with wavefunction V1) can be determined by 21. A (A) solving the eigenvalue equation: Rvw rV., finding the maximum in the 1s radial distribution function by differentiation. (C) substituting vi,...
Mechanics. Need help with c) and d)
1. A particle of mass m moves in three dimensions, and has position r(t)-(x(t), y(t), z(t)) at time t. The particle has potential energy V(x, y, 2) so that its Lagrangian is given by where i d/dt, dy/dt, dz/dt (a) Writing q(q2.93)-(r, y, z) and denoting by p (p,P2, ps) their associated canonical momenta, show that the Hamiltonian is given by (show it from first principles rather than using the energy) H(q,p)H(g1, 92,9q3,...
Consider a particle in a 1-d well with potential V(x) =-U for-d < x < d, and V(z) 0 elsewhere. We will use the variational wave function v(z) = A(b + r), t(x)-A(b-x), -b < r < 0, 0 < x < b, to show that a bound state exists for any U0. a) Normalize the wave function. Find the expectation values of the kinetic and potential energies b) Show that for sufficiently large b, with b> d, the expectation...
3. Consider a particle of mass m moving in a potential given by: W (2, y, z) = 0 < x <a,0 < y <a l+o, elsewhere a) Write down the total energy and the 3D wavefunction for this particle. b) Assuming that hw > 312 h2/(2ma), find the energies and the corresponding degen- eracies for the ground state and the first excited state. c) Assume now that, in addition to the potential V(x, y, z), this particle also has...
Question 8 please
5. We start with Schrodinger's Equation in 2(x,t) = H¥(x,t). We can write the time derivative as 2.4(x, t) = V(x,+) - (xt), where At is a sufficiently small increment of time. Plug the algebraic form of the derivative into Schrodinger's Eq. and solve for '(x,t+At). b. Put your answer in the form (x,t+At) = T '(x,t). c. What physically does the operator T do to the function '(x,t)? d. Deduce an expression for '(x,t+24t), in terms...
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