I have done it. See below.
If [Cr(H2O).]3+ is violet and [Cr(NH3)6]3+ is yellow, which one of these statements is false ?...
An octahedral metal complex absorbs light with wavelength 580 nm. a. What is the crystal field splitting A, in kJ/mol for the complex? (Hint: Energy is based on wavelength of light absorbed. See data sheet.) (3 marks) b. What color does the complex appear to the eye? (2 marks) 750 nm, 400 nm Red Violet 630 nm 430 nm Blue Orange 590 nm 480 nm Yellow Green 560 nm
Question 10 12 pts A) What is the name of the compound having the formula Naz[Fe(NH3)2Br2CICN) (m.m. of Fe = 26) B) What is the coordination number? C) What is the d electron configuration? D) Number of unpaired electrons. E) Is it paramagnetic or diamagnetic? F) What is the color of the solution? 750 400 Red Violet 630 430 Blue Orange 590 480 Yellow Green 560
3. The complex [Ti(H20)6]3+ is violet, while the analogous complex with another monodentate neutral ligand L, [Ti(L)6]3+ is orange. How many of the following statements are true? Explain briefly. (a) L is a stronger field ligand than H20. (b) [Ti(L)6]3+ is a high-spin complex. (c) [Ti(L)6]3+ absorbs yellow and red light. (d) Both complexes have two 3d electrons associated with the metal.
6. a) Which complex ion should have the larger crystal field splitting, A? Explain why. [Cr(H20).13+ or [CrCl.13- b) Which complex ion should absorb light of shorter wavelength? Explain why. [Cr(H20)613+ or [CrC1613 -
Please explain any background knowledge and approach to this problem! Very confused about this, my answers are all incorrect and I do not have a key! d) Of the following complex ions: [FeCl614-, [Fe(CN)6]4-, [Fe(H2O)e12+, [Fe(NH3)e]2+ one appears violet, one yellow, one blue-green and one orange. Assign which is which using the spaces below. Use the color wheel to answer the question (12pts). 1S0 nm,400 nm Red Violet Write Complex lon Below Given the Color of complex 630 nm 430...
The electronic absorption spectrum UI (Cr(NH3)6]3+ (aq) is shown in Figure 11.5. One of the observed peaks is centered at about 303 nm. 1.a. What is the approximate value of the wavelength for the two other peaks? Which one of these three peaks falls in the visible region of the electromagnetic spectrum? The wavelength at this peak is (Amax), and this transition accounts for the color of the complex ion in solution. The energy of the transition occurring at...
The spectrochemical series is < Br<< Cl<F-<OH" <H2O <NH3 <en <NO2- < CN- The complex [Ni(Cl)c] is green and the complex [Ni(en)]2+ is violet, where en corresponds to the ethylenediamine ligand. The reason for the difference in the color of these complexes is: Select one: A. The chloride ligand is green, and the ethylenediamine ligand is violet. B. The difference in the coordination numbers of the chloride complex and the en complex. C. The difference in the oxidation states of...
In the complex ion [ML6]n+, Mn+ has five d electrons and L is a strong field ligand. According to crystal field theory, the magnetic properties of the complex ion correspond to how many unpaired electrons? A. 0 B. 1 C. 2 D. 3 E. 5 Which one of these complex ions would absorb light with the shortest wavelength? A. [Co(H2O)6]2+ B. [Co(NH3)6]2+ C. [CoF6]4– D. [Co(CN)6]4– E. [Co(en)6]2+ The ion [Co(NH3)6]2+ is octahedral and high spin. This complex is (4pts)...
Date: 1117 mework 10 - Ch. 21-23 A) CN B)NO c)r D) CO Name: E ) en 24. Place the ligands, CN-, Br., H2O, and OH-in order from least to greatest according ability to split the d orbital energy level. A) CN-, OH, H2O, Br- C) Br,H20, CN-, OH- B) Br., OH, H2O, CN- D) None of the above 25. The charge on the central metal ion in (Cr(NH3)(CO3)2+ is A)-1. B) 0. C) 1. D) 3. E) 5 26....
Question 5 6 pts A student has three test tubes containing a metal (M) nitrate solution M(NO3)2 (aq) (where "M" represents a generic transition metal). The student adds aqueous ammonia (NH3) to one test tube, aqueous hydrochloric acid (HCI) to the second tube, and nothing more to the third tube, but forgets to label the tubes. After this, one test tube contains a red solution, one an orange solution, and one a yellow solution. Note: This metal, M, would follow...