Which one is not a rxn pathway to alter the carbon skeleton of a ketone or...
Which one is not a rxn pathway to alter the carbon skeleton of a ketone or aldehyde?
a Wolff-kishner
b Grignard
c Wittig
d Cyanohydrin
d Cyanohydrin
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Which one is not a rxn pathway to alter the carbon skeleton of a
ketone or...
Need help on both A) and B). The carbonyl group of an aldehyde or ketone may...
Need help on both A) and B).
The carbonyl group of an aldehyde or ketone may be reduced via several different methods. Select all viable methods for aldehyde/ketone reduction. Na2Cr2O7 and H2SO4 Wolff-Kishner method Baeyer-Villiger method NH3, H2, and Raney Ni 1) LiAIH4, 2) H20 Clemmensen method KMnO4 and H2SO4 Of the reduction methods, which one would be best performed under acidic conditions? Clemmensen method Na2Cr2O7 and H2SO4 NH3, H2, and Raney Ni KMnO4 and H2SO4 Baeyer-Villiger method Wolff-Kishner method...
The carbonyl group of an aldehyde or ketone may be reduced via several different methods. a)...
The carbonyl group of an aldehyde or ketone may be reduced via several different methods. a) Select all viable methods for aldehyde/ketone reduction, O NH3, H2, and Raney Ni Na2Cr2O7 and H2SO4 Baeyer-Villiger method 1) LiAlH4, 2) H20 KMnO4 and H2SO4 Clemmensen method Wolff, Kishner method b) of the reduction methods, which one would be best performed under acidic conditions? O O O Wolff, Kishner method NH3, H2, and Raney Ni Na2Cr207 and H2SO4 1) LiAlH4, 2) H20 Clemmensen method...
4. The carbonyl group of an aldehyde or ketone may be reduced via several different methods....
4. The carbonyl group of an aldehyde or ketone may be reduced via several different methods. Circle ALL the methods for aldehyde/ketone reduction below. (0.5 p) Hint: search the index of textbook to find the sections that is focused on one of the methods below. a. Na,Cr O, and H SO4 f. Baeyer-Villiger method b. Clemmenson method g. NH3 and Na c. KMnO4 and H2SO4 h. H2 and Raney Ni d. LiAIH e. Wolff-Kishner method
30-What is the common name for 2-butanone? aa, methyl ethyl ketone b. isobutyl ketone c. diethyl...
30-What is the common name for 2-butanone? aa, methyl ethyl ketone b. isobutyl ketone c. diethyl ketone d. butyl ketone 31-What is the IUPAC name for ? CH3 CH2BECH2CHO a. 3-bromobutanal b.3-bromobutanone c. 2-bromobutanal d.2-bromobutanone 32- Benzaldehyde can be reduced by the Wolff- Kishner method, too. What is the product? a-Benzene bb- Toluene C-Benzyl alcohol (phenylmethanol) d-Cyclohexane 33-Addition of a Grignard reagent to formaldehyde followed by H30+ gives aa 1° alcohol b-2° alcohol c- 3° alcohol d-ketone
The carbonyl group of an aldehyde or ketone may be reduced via several different methods. Select...
The carbonyl group of an aldehyde or ketone may be reduced via several different methods. Select all viable methods for aldehyde/ketone reduction. 1) LiAIH 4, 2) H 2O NH 3, H 2. and Raney Ni Na 2Cr 2O 7 and H 2SO 4 Wolff-Kishner method Clemmensen method Baeyer-Villiger method KMnO 4 and H 2SO 4 Of the reduction methods, which one would be best performed under acidic conditions? KMnO 4 and H2 SO 4 NH 3, H 2, and Raney...
which one is true and which one is false ? T/F (7) In the Baeyer-Villiger oxidation,...
which one is true and which one is false ? T/F
(7) In the Baeyer-Villiger oxidation, the carbon migration will take place in both symmetric and asymmetric ketone or aldehyde. (17) Acyl chloride can be reduced by LAH or Grignard reagents to secondary alcohol.
DS-Chupane 13) 13) Which of the following cannot be made by the reduction of a ketone...
DS-Chupane 13) 13) Which of the following cannot be made by the reduction of a ketone or aldehyde with NaBH in methanol A) 2-methyl-2-propanol 3) 1-butanol 2-methyl-1-propanol D) 2-butanol 14) Which of the following reagents would react with a primary alcohol to produce an aldehyde as the final product? A) PCC B) H2SO4 CH2C04 D) CH3MgBr, followed by HCI 15) Which one of the following is not oxidized by K2Cr2O7 in H2SO4/H1207 A) isobutyl alcohol B) butyl alcohol C ebutyl...
13. What is M for 2-butanone? a) b ) 85 d) 58 O c) 72 Grignard...
13. What is M for 2-butanone? a) b ) 85 d) 58 O c) 72 Grignard reagent added to a aldehyde and H30* 14. What is the product of a Grignard reagent added to a al a) amine b) imine c) alcohol d) ketone 15. A ketal is formed from a a) amine b) imine c) alcohol d) ketone and aldehyde 16. p-Nitrobenzoic acid contains how many NO, groups? a) O b)1 c)2 d) 3 17. The carboxylic acid pentanoic...
CHEM 242 Score (100): TEST #3 July 24, 2014 (Thursday) NAME PART A. (3pt each) Please...
CHEM 242 Score (100): TEST #3 July 24, 2014 (Thursday) NAME PART A. (3pt each) Please circle the right answer. Where would be the absorption peak of a carbonyl, C-O, stretching in IR? a) at 3300 cm b) at 2980 cm cat 1700 crm d) at 1200 cm 2. Which one is the most reactive with a Grignard reagent in nucleophilic addition rxn? a) Acetone b) benzaldehyde c)Butanone d) acetophenone 3. What is the purpose of protonating a carbonyl? a)...
Which is the correct name for 2-3-iedopentan-2-alb-2-ledopeatan-3-one .B.Iodopentan-2-one 4-2-iodopentanal FLED THIS Which is the correct name...
Which is the correct name for 2-3-iedopentan-2-alb-2-ledopeatan-3-one .B.Iodopentan-2-one 4-2-iodopentanal FLED THIS Which is the correct name for a 2-lodobutan-3-al b-3-lodobutan-2-one c-2-lodobutan-3-one d-3-lodobutan-2-al Which is the correct name for? -butanone d-methylpropanal a ethylpropanalb-propanone 9. Which is the correct name for CH3CH2COCH2CH32 diethyl ketone b-pentan-4-one c-pentan-3-al d-pentan-3-one c.pentan-2-one 10 Which is the correct name for - CH3CH03 -ethanal a. Ethone b-ethanol c-vinger d-ketanal ICH-CH2-C-CH2-CH3 Which is the correct name for a. 5-iodopentan-2-one b. 1-iodopentan-2-one c-1-iodopentan-3-one d-5-iodopentan-3-one 12. Which of the following properly...
Need help on both A) and B).
The carbonyl group of an aldehyde or ketone may be reduced via several different methods. Select all viable methods for aldehyde/ketone reduction. Na2Cr2O7 and H2SO4 Wolff-Kishner method Baeyer-Villiger method NH3, H2, and Raney Ni 1) LiAIH4, 2) H20 Clemmensen method KMnO4 and H2SO4 Of the reduction methods, which one would be best performed under acidic conditions? Clemmensen method Na2Cr2O7 and H2SO4 NH3, H2, and Raney Ni KMnO4 and H2SO4 Baeyer-Villiger method Wolff-Kishner method...
The carbonyl group of an aldehyde or ketone may be reduced via several different methods. a) Select all viable methods for aldehyde/ketone reduction, O NH3, H2, and Raney Ni Na2Cr2O7 and H2SO4 Baeyer-Villiger method 1) LiAlH4, 2) H20 KMnO4 and H2SO4 Clemmensen method Wolff, Kishner method b) of the reduction methods, which one would be best performed under acidic conditions? O O O Wolff, Kishner method NH3, H2, and Raney Ni Na2Cr207 and H2SO4 1) LiAlH4, 2) H20 Clemmensen method...
4. The carbonyl group of an aldehyde or ketone may be reduced via several different methods. Circle ALL the methods for aldehyde/ketone reduction below. (0.5 p) Hint: search the index of textbook to find the sections that is focused on one of the methods below. a. Na,Cr O, and H SO4 f. Baeyer-Villiger method b. Clemmenson method g. NH3 and Na c. KMnO4 and H2SO4 h. H2 and Raney Ni d. LiAIH e. Wolff-Kishner method
30-What is the common name for 2-butanone? aa, methyl ethyl ketone b. isobutyl ketone c. diethyl ketone d. butyl ketone 31-What is the IUPAC name for ? CH3 CH2BECH2CHO a. 3-bromobutanal b.3-bromobutanone c. 2-bromobutanal d.2-bromobutanone 32- Benzaldehyde can be reduced by the Wolff- Kishner method, too. What is the product? a-Benzene bb- Toluene C-Benzyl alcohol (phenylmethanol) d-Cyclohexane 33-Addition of a Grignard reagent to formaldehyde followed by H30+ gives aa 1° alcohol b-2° alcohol c- 3° alcohol d-ketone
The carbonyl group of an aldehyde or ketone may be reduced via several different methods. Select all viable methods for aldehyde/ketone reduction. 1) LiAIH 4, 2) H 2O NH 3, H 2. and Raney Ni Na 2Cr 2O 7 and H 2SO 4 Wolff-Kishner method Clemmensen method Baeyer-Villiger method KMnO 4 and H 2SO 4 Of the reduction methods, which one would be best performed under acidic conditions? KMnO 4 and H2 SO 4 NH 3, H 2, and Raney...
which one is true and which one is false ? T/F
(7) In the Baeyer-Villiger oxidation, the carbon migration will take place in both symmetric and asymmetric ketone or aldehyde. (17) Acyl chloride can be reduced by LAH or Grignard reagents to secondary alcohol.
DS-Chupane 13) 13) Which of the following cannot be made by the reduction of a ketone or aldehyde with NaBH in methanol A) 2-methyl-2-propanol 3) 1-butanol 2-methyl-1-propanol D) 2-butanol 14) Which of the following reagents would react with a primary alcohol to produce an aldehyde as the final product? A) PCC B) H2SO4 CH2C04 D) CH3MgBr, followed by HCI 15) Which one of the following is not oxidized by K2Cr2O7 in H2SO4/H1207 A) isobutyl alcohol B) butyl alcohol C ebutyl...
13. What is M for 2-butanone? a) b ) 85 d) 58 O c) 72 Grignard reagent added to a aldehyde and H30* 14. What is the product of a Grignard reagent added to a al a) amine b) imine c) alcohol d) ketone 15. A ketal is formed from a a) amine b) imine c) alcohol d) ketone and aldehyde 16. p-Nitrobenzoic acid contains how many NO, groups? a) O b)1 c)2 d) 3 17. The carboxylic acid pentanoic...
CHEM 242 Score (100): TEST #3 July 24, 2014 (Thursday) NAME PART A. (3pt each) Please circle the right answer. Where would be the absorption peak of a carbonyl, C-O, stretching in IR? a) at 3300 cm b) at 2980 cm cat 1700 crm d) at 1200 cm 2. Which one is the most reactive with a Grignard reagent in nucleophilic addition rxn? a) Acetone b) benzaldehyde c)Butanone d) acetophenone 3. What is the purpose of protonating a carbonyl? a)...
Which is the correct name for 2-3-iedopentan-2-alb-2-ledopeatan-3-one .B.Iodopentan-2-one 4-2-iodopentanal FLED THIS Which is the correct name for a 2-lodobutan-3-al b-3-lodobutan-2-one c-2-lodobutan-3-one d-3-lodobutan-2-al Which is the correct name for? -butanone d-methylpropanal a ethylpropanalb-propanone 9. Which is the correct name for CH3CH2COCH2CH32 diethyl ketone b-pentan-4-one c-pentan-3-al d-pentan-3-one c.pentan-2-one 10 Which is the correct name for - CH3CH03 -ethanal a. Ethone b-ethanol c-vinger d-ketanal ICH-CH2-C-CH2-CH3 Which is the correct name for a. 5-iodopentan-2-one b. 1-iodopentan-2-one c-1-iodopentan-3-one d-5-iodopentan-3-one 12. Which of the following properly...
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