Homework Answers
12. Cyclohexane is weak organic acid undergoes Elimination reaction with acid to produce cyclohexene and water.
13. Oxidation of Primary alcohol with PCC as oxidizing agent gives aldehyde while with tertiary alcohol no reaction.
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12. Fill the blank Cyclohexanol isacid undergoreaction with Acid to producand -, 13. Oxidation of primary...
Oxidation of Cyclohexanol to Adipic Acid (continued on the next page): (1) (2 pts) In this...
Oxidation of Cyclohexanol to Adipic Acid (continued on the next page): (1) (2 pts) In this experiment we could have used cylcohexene instead of cyclohexanol and we would have still gotten adipic acid. Draw an alkene and an alcohol each of which would react with nitric acid to give suberic acid. (4 pts) In the oxidation that you carried out in this experiment, nitric acid ends up as a mixture of oxides of nitrogen. Use the formula index of the...
Oxidation of alcohol Write an equation to represent the oxidation of an alcohol. Write a mechanism...
Oxidation of alcohol Write an equation to represent the oxidation of an alcohol. Write a mechanism for the oxidation of an alcohol. Identify the reagents that may be used to oxidize a given alcohol. Identify the specific reagent that is used to oxidize primary alcohols to aldehydes rather than to carboxylic acids. Identify the product formed from the oxidation of a given alcohol with a specified oxidizing agent. Identify the alcohol needed to prepare a given aldehyde, ketone or carboxylic...
ChemActivity 10: Oxidation and Reduction 145 Model 7: Primary (1°), Secondary (2°), and Tertiary (3°) Carbons...
ChemActivity 10: Oxidation and Reduction 145 Model 7: Primary (1°), Secondary (2°), and Tertiary (3°) Carbons The words methyl (0'), primary (1), secondary (2"), and tertiary (3) were used to describe the number of (nonhydrogen) R groups attached to a carbocation carbon (see CA 8). This same naming strategy is used to describe any carbon with one attached "heteroatom," Z (hetero other). H R Z any atom other than C or H (hetroatom) R- -z -Z н- alkyl (not H)...
ChemActivity 10: Oxidation and Reduction 145 Model 7: Primary (1°), Secondary (2°), and Tertiary (3°) Carbons...
ChemActivity 10: Oxidation and Reduction 145 Model 7: Primary (1°), Secondary (2°), and Tertiary (3°) Carbons The words methyl (0'), primary (1), secondary (2"), and tertiary (3) were used to describe the number of (nonhydrogen) R groups attached to a carbocation carbon (see CA 8). This same naming strategy is used to describe any carbon with one attached "heteroatom," Z (hetero other). H R Z any atom other than C or H (hetroatom) R- -z -Z н- alkyl (not H)...
1. Draw structures of one primary alcohol, one secondary alcohol and one tertiary alcohol and give...
1. Draw structures of one primary alcohol, one secondary alcohol and one tertiary alcohol and give the correct name for each structure you have drawn. 2. Describe the difference between alcohols and phenols. 3. Describe the difference between an aldehyde and a ketone, and indicate how each differs from an alcohol Describe what is meant by oxidation and reduction in relation to organic compounds, giving one example of oxidation of an organic compound and one example of reduetion of an...
POST-LABORATORY EXERCISES mic Acid Oxidation of Cyclohexanol Chromic Acid Oxid 1. Suppose instead of ead of...
POST-LABORATORY EXERCISES mic Acid Oxidation of Cyclohexanol Chromic Acid Oxid 1. Suppose instead of ead of using chromic acid as the oxidizing agent, you wed concentrated sulfuric acid. em to show the oxidation of cyclohexanol to cyclohexanone. W 1. Waite a mechanism to show the oxidatinast 개 wi 2. How would you carry out the following transformation? GENERAL EXPERIMENTAL ORGANIC CHEMIST action (If it has a name) and 3. Some of the reactions below are write the products of each...
12) Provide the structure of the major organic product in the reaction below. РОС Is 13)...
12) Provide the structure of the major organic product in the reaction below. РОС Is 13) Chromic acid oxidations are believed to proceed through a chromate ester intermediate. In its conversion to the intermediate aldehyde. Answer n-1-ol, provide the structure of this ester and give the mechanism for 14) What series of synthetic steps could be used to carry out the transformation shown below? Answer (three steps): 2. 3. 15) Reaction of ethylmagnesium bromide with which of the following compounds...
acid catalyzed hydration of 1 methylcyclohexene yields 2 alcohols. The major product does not undergo oxidation,...
acid catalyzed hydration of 1 methylcyclohexene yields 2
alcohols. The major product does not undergo oxidation, while the
minor product will undergo oxidation, explain.
3. Acid-catalyzed hydration of 1-methylcyclohexene yields two alcohols. The major product does not undergo oxidation, while the minor product will undergo oxidation. Explain. 4. Using 2-propanol as your only source of carbon, show how you would prepare 2-methyl- 2-pentanol. 5. Identify the reagents you would use to accomplish each of the following transformations: DH (4) tage...
15. llemlacetals are? produced on the oxidation of carboxylic acid b.result of the reaction between an...
15. llemlacetals are? produced on the oxidation of carboxylic acid b.result of the reaction between an sidchyde and a ketone are produced when an ether reacts with a kotone d composed from Ether and OH group care produced when an alcohol reacts with sketone 16. To what class of compounds does plucose belong cyclic ketoneb. cyclic aldehyde sydliehamiacetald . 17. The correct IUPAC same for this compound is OCH, CH, & in-cw con 3-methyl-4-diopetanal e-3-methyl-4-oxopentanol b. 3-methyl-4-oxopentanone d. 3-methyl-4-oxopentanal 18.Which...
13. Fill in the blank: The systems of the blood are the first line of defense...
13. Fill in the blank: The systems of the blood are the first line of defense against changes in pH. 14. True or False: Gastric bypass induces weight loss because the lower compartment of the stomach is so small that it soon becomes overdistended with food when the individual starts to eat. 15. Fill in the blank: A an extremely infectious RNA virus easily spread from person to person and by contaminated food or water. 16. Fill in the blank...
Oxidation of Cyclohexanol to Adipic Acid (continued on the next page): (1) (2 pts) In this experiment we could have used cylcohexene instead of cyclohexanol and we would have still gotten adipic acid. Draw an alkene and an alcohol each of which would react with nitric acid to give suberic acid. (4 pts) In the oxidation that you carried out in this experiment, nitric acid ends up as a mixture of oxides of nitrogen. Use the formula index of the...
Oxidation of alcohol Write an equation to represent the oxidation of an alcohol. Write a mechanism for the oxidation of an alcohol. Identify the reagents that may be used to oxidize a given alcohol. Identify the specific reagent that is used to oxidize primary alcohols to aldehydes rather than to carboxylic acids. Identify the product formed from the oxidation of a given alcohol with a specified oxidizing agent. Identify the alcohol needed to prepare a given aldehyde, ketone or carboxylic...
ChemActivity 10: Oxidation and Reduction 145 Model 7: Primary (1°), Secondary (2°), and Tertiary (3°) Carbons The words methyl (0'), primary (1), secondary (2"), and tertiary (3) were used to describe the number of (nonhydrogen) R groups attached to a carbocation carbon (see CA 8). This same naming strategy is used to describe any carbon with one attached "heteroatom," Z (hetero other). H R Z any atom other than C or H (hetroatom) R- -z -Z н- alkyl (not H)...
ChemActivity 10: Oxidation and Reduction 145 Model 7: Primary (1°), Secondary (2°), and Tertiary (3°) Carbons The words methyl (0'), primary (1), secondary (2"), and tertiary (3) were used to describe the number of (nonhydrogen) R groups attached to a carbocation carbon (see CA 8). This same naming strategy is used to describe any carbon with one attached "heteroatom," Z (hetero other). H R Z any atom other than C or H (hetroatom) R- -z -Z н- alkyl (not H)...
1. Draw structures of one primary alcohol, one secondary alcohol and one tertiary alcohol and give the correct name for each structure you have drawn. 2. Describe the difference between alcohols and phenols. 3. Describe the difference between an aldehyde and a ketone, and indicate how each differs from an alcohol Describe what is meant by oxidation and reduction in relation to organic compounds, giving one example of oxidation of an organic compound and one example of reduetion of an...
POST-LABORATORY EXERCISES mic Acid Oxidation of Cyclohexanol Chromic Acid Oxid 1. Suppose instead of ead of using chromic acid as the oxidizing agent, you wed concentrated sulfuric acid. em to show the oxidation of cyclohexanol to cyclohexanone. W 1. Waite a mechanism to show the oxidatinast 개 wi 2. How would you carry out the following transformation? GENERAL EXPERIMENTAL ORGANIC CHEMIST action (If it has a name) and 3. Some of the reactions below are write the products of each...
12) Provide the structure of the major organic product in the reaction below. РОС Is 13) Chromic acid oxidations are believed to proceed through a chromate ester intermediate. In its conversion to the intermediate aldehyde. Answer n-1-ol, provide the structure of this ester and give the mechanism for 14) What series of synthetic steps could be used to carry out the transformation shown below? Answer (three steps): 2. 3. 15) Reaction of ethylmagnesium bromide with which of the following compounds...
acid catalyzed hydration of 1 methylcyclohexene yields 2
alcohols. The major product does not undergo oxidation, while the
minor product will undergo oxidation, explain.
3. Acid-catalyzed hydration of 1-methylcyclohexene yields two alcohols. The major product does not undergo oxidation, while the minor product will undergo oxidation. Explain. 4. Using 2-propanol as your only source of carbon, show how you would prepare 2-methyl- 2-pentanol. 5. Identify the reagents you would use to accomplish each of the following transformations: DH (4) tage...
15. llemlacetals are? produced on the oxidation of carboxylic acid b.result of the reaction between an sidchyde and a ketone are produced when an ether reacts with a kotone d composed from Ether and OH group care produced when an alcohol reacts with sketone 16. To what class of compounds does plucose belong cyclic ketoneb. cyclic aldehyde sydliehamiacetald . 17. The correct IUPAC same for this compound is OCH, CH, & in-cw con 3-methyl-4-diopetanal e-3-methyl-4-oxopentanol b. 3-methyl-4-oxopentanone d. 3-methyl-4-oxopentanal 18.Which...
13. Fill in the blank: The systems of the blood are the first line of defense against changes in pH. 14. True or False: Gastric bypass induces weight loss because the lower compartment of the stomach is so small that it soon becomes overdistended with food when the individual starts to eat. 15. Fill in the blank: A an extremely infectious RNA virus easily spread from person to person and by contaminated food or water. 16. Fill in the blank...
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