What is the role of THF in alkene reactions?
On the picture below, I see different reagents for oxymercuration reactions, but how do I know if I'm supposed to use THF or NaOH/H2O?
Homework Answers
THF is used as the solvent and it is not a reagent in alkene reaction.
For oxymercuration and demercuration the reagent sequence is Hg(OAc)2, H2O followed by NaBH4 in NaOH, H2O.
Here NaOH, H2O used for the hydrolysis in final step after demercuration.
So you suppose to use NaOH/H2O. Not THF
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What is the role of THF in alkene reactions?
On the picture below, I see different...
What are the best reagents to complete this synthesis? O 1. BH3 – THF; 2. H2O2,...
What are the best reagents to complete this synthesis? O 1. BH3 – THF; 2. H2O2, NaOH; 3. PCC O 1. BHz – THF; 2. H2O2, NaOH; 3. H, CrO4 01. 03; 2. DMS 01. Hg(OAC)2, H2O; 2. NaBH4; 3. PCC Predict the product of the following reaction scheme: 2LIATH H2O OH OH Predict the product for the following reaction | | Identify the reaction sequence of reactions that can achieve the following transformation a- O (1) Br2, CCl4: (2)...
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Hello! Just double checking the answers my organic chemistry
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21. Provide reagents (including solvent and/or special conditions, such as light) to complete the following reaction scheme. CH3-CCH-CH2 CH3 H3C CO+Ho -CH CH OH Page 8 of 9 HC H3C gOCH2CH3 18. Draw the structure of the alkene...
2. Draw the major product(s) from the reaction of the starting material below with the following...
2. Draw the major product(s) from the reaction of the starting material below with the following reagents: (12 marks) (a) (b) (1) BH3, THF (2) H2O2, NaOH, H2O Cl in excess EtOH (0) I-CI (d) (1) O3. CH CI: (2) Zn, acetic acid (e) (1) (1) OsO4, THF (2) H2S (1) Hg(OOCCH3)2, H2O (2) NaBH4, NaOH, H2O
Predict the major product(s) of the following reactions. Show stereochemistry where appropriate. 3 CO3H i) OsO4...
Predict the major product(s) of the following reactions. Show stereochemistry where appropriate. 3 CO3H i) OsO4 H ii) NaHSO3, H2O CHC13, KOH any cha, kot i) BH3, THF CECH 11) H2O2, NaOH Li NH (liquid) cm X Ft, H/HO (vii) Two Markovnikov products Draw the structure of alkene for each of the following reactions. OH i) BH, THF 11) H202, NaOH 1) Hg(OAc)2, H20 ii) NaBH4 1) 03 ii) Zn/H Styrene undergoes propagation to give polystyrene. Showing electron-flow using half-headed...
I. OH HIO4 OH OH 1. NaBH4 2 Ho 1. LiAH THF 2. aq. HCl он SOC1 IV. Cl How many of the following reactions are correct? Only numerical answers are accepted. For example, if the answer is four, do not w...
I. OH HIO4 OH OH 1. NaBH4 2 Ho 1. LiAH THF 2. aq. HCl он SOC1 IV. Cl How many of the following reactions are correct? Only numerical answers are accepted. For example, if the answer is four, do not write "Four"; instead, write "4" only. Answer
I. OH HIO4 OH OH 1. NaBH4 2 Ho 1. LiAH THF 2. aq. HCl он SOC1 IV. Cl How many of the following reactions are correct? Only numerical answers are accepted....
Select the reagents you would use to accomplish the syntheses shown below in no more than...
Select the reagents you would use to accomplish the syntheses shown below in no more than the number of steps specified. List the letters of the reagents in the order that they are used; example: fa. Reagents Available a. HBr b. PBr3 C. (CH3CH2CH2CH2)2Culi f. CH31 g. Hg(OAC)2, H2O, THF; then NaBH4 h. Cl2, light d. (CH3)2Culi I. KOH j. NBS (N-bromosuccinimide) e. BH3, THF; then H202, OH - он CH3 Use 2 steps: V - M Use 3 steps:
Predict the product(s) using the same alkene reactant for the following reactions: 2. н, (a) Pt/C...
Predict the product(s) using the same alkene reactant for the following reactions: 2. н, (a) Pt/C D, (b) Pt/C Cl, (c) CH,Cl, Br, (d) Н.о Cl, (e) CH,OH HI (0 DBr (g) НВr (h) нолу ноно (0) 1. Hg". THF-H,O 2. NaBH/NaOH 1. В, Н, ТHF (k) 2. H,O/NaOH кMпо, H,о (I) cold 1. OsO, (m) 2. NaHSO, 1. KMnO/OH/heat (n) 2. Н.О" 1. 0/CH,CI, (o) 2. Zn/H,O 1. O, (p) 2. H.о/он
2. Predict the major organic product(s) of the reactions below. Assume 1 equivalent of reagent unless...
2. Predict the major organic product(s) of the
reactions below. Assume 1 equivalent of reagent unless otherwise
stated, it's a solvent, or an oxidizing/reducing agent. Do consider
stereochemistry and regioselectivity.
2. Predict the major organic product(s) of the reactions below. Assume 1 equivalent of reagent unless otherwise stated, it's a solvent, or an oxidizing/reducing agent. Do consider stereochemistry and regioselectivity. (3 points each; 15 points total) A. Me 1. HNO3 2. O3 3. DMS 1. mCPBA, DCM (1 equiv) 2....
What is the best route for converting the alcohol to the ether as shown below using...
What is the best route for converting the alcohol to the ether as shown below using a substitution reaction or a sequence of substitution reactions while preserving the steroochemistry at the chiral center? OH OCH a. NaOCHy b.i. PC13; ii. NaOCH ci.HCI; N.CH OH 4. CH3OH Oei. HCI; il NOCH f. LICH3 What reagents is the best choice for achieving the following chemical transformation? 0 ?? no CH; CC1z O a. PC13 b. Cl2, NaOH c. NaCl, H20 Ed. Cl2...
home / study / science / chemistry / chemistry questions and answers / hello! just double checking the answers my organic chemistry study guide. please go ahead and ... Question: Hello! Just double ch...
home / study / science / chemistry / chemistry questions and
answers / hello! just double checking the answers my organic
chemistry study guide. please go ahead and ...
Question: Hello! Just double checking the answers my
organic chemistry study guide. Please go ahead and ans...
Hello! Just double checking the answers my organic chemistry
study guide. Please go ahead and answer ALL the
questions you see below, if you can't answer all then
PLEASE let someone else do them!...
What are the best reagents to complete this synthesis? O 1. BH3 – THF; 2. H2O2, NaOH; 3. PCC O 1. BHz – THF; 2. H2O2, NaOH; 3. H, CrO4 01. 03; 2. DMS 01. Hg(OAC)2, H2O; 2. NaBH4; 3. PCC Predict the product of the following reaction scheme: 2LIATH H2O OH OH Predict the product for the following reaction | | Identify the reaction sequence of reactions that can achieve the following transformation a- O (1) Br2, CCl4: (2)...
Hello! Just double checking the answers my organic chemistry
study guide. Please go ahead and answer ALL the
questions you see below, if you can't answer all then
PLEASE let someone else do them! High rating only
given to ALL questions complete
21. Provide reagents (including solvent and/or special conditions, such as light) to complete the following reaction scheme. CH3-CCH-CH2 CH3 H3C CO+Ho -CH CH OH Page 8 of 9 HC H3C gOCH2CH3 18. Draw the structure of the alkene...
2. Draw the major product(s) from the reaction of the starting material below with the following reagents: (12 marks) (a) (b) (1) BH3, THF (2) H2O2, NaOH, H2O Cl in excess EtOH (0) I-CI (d) (1) O3. CH CI: (2) Zn, acetic acid (e) (1) (1) OsO4, THF (2) H2S (1) Hg(OOCCH3)2, H2O (2) NaBH4, NaOH, H2O
Predict the major product(s) of the following reactions. Show stereochemistry where appropriate. 3 CO3H i) OsO4 H ii) NaHSO3, H2O CHC13, KOH any cha, kot i) BH3, THF CECH 11) H2O2, NaOH Li NH (liquid) cm X Ft, H/HO (vii) Two Markovnikov products Draw the structure of alkene for each of the following reactions. OH i) BH, THF 11) H202, NaOH 1) Hg(OAc)2, H20 ii) NaBH4 1) 03 ii) Zn/H Styrene undergoes propagation to give polystyrene. Showing electron-flow using half-headed...
I. OH HIO4 OH OH 1. NaBH4 2 Ho 1. LiAH THF 2. aq. HCl он SOC1 IV. Cl How many of the following reactions are correct? Only numerical answers are accepted. For example, if the answer is four, do not write "Four"; instead, write "4" only. Answer
I. OH HIO4 OH OH 1. NaBH4 2 Ho 1. LiAH THF 2. aq. HCl он SOC1 IV. Cl How many of the following reactions are correct? Only numerical answers are accepted....
Select the reagents you would use to accomplish the syntheses shown below in no more than the number of steps specified. List the letters of the reagents in the order that they are used; example: fa. Reagents Available a. HBr b. PBr3 C. (CH3CH2CH2CH2)2Culi f. CH31 g. Hg(OAC)2, H2O, THF; then NaBH4 h. Cl2, light d. (CH3)2Culi I. KOH j. NBS (N-bromosuccinimide) e. BH3, THF; then H202, OH - он CH3 Use 2 steps: V - M Use 3 steps:
Predict the product(s) using the same alkene reactant for the following reactions: 2. н, (a) Pt/C D, (b) Pt/C Cl, (c) CH,Cl, Br, (d) Н.о Cl, (e) CH,OH HI (0 DBr (g) НВr (h) нолу ноно (0) 1. Hg". THF-H,O 2. NaBH/NaOH 1. В, Н, ТHF (k) 2. H,O/NaOH кMпо, H,о (I) cold 1. OsO, (m) 2. NaHSO, 1. KMnO/OH/heat (n) 2. Н.О" 1. 0/CH,CI, (o) 2. Zn/H,O 1. O, (p) 2. H.о/он
2. Predict the major organic product(s) of the
reactions below. Assume 1 equivalent of reagent unless otherwise
stated, it's a solvent, or an oxidizing/reducing agent. Do consider
stereochemistry and regioselectivity.
2. Predict the major organic product(s) of the reactions below. Assume 1 equivalent of reagent unless otherwise stated, it's a solvent, or an oxidizing/reducing agent. Do consider stereochemistry and regioselectivity. (3 points each; 15 points total) A. Me 1. HNO3 2. O3 3. DMS 1. mCPBA, DCM (1 equiv) 2....
What is the best route for converting the alcohol to the ether as shown below using a substitution reaction or a sequence of substitution reactions while preserving the steroochemistry at the chiral center? OH OCH a. NaOCHy b.i. PC13; ii. NaOCH ci.HCI; N.CH OH 4. CH3OH Oei. HCI; il NOCH f. LICH3 What reagents is the best choice for achieving the following chemical transformation? 0 ?? no CH; CC1z O a. PC13 b. Cl2, NaOH c. NaCl, H20 Ed. Cl2...
home / study / science / chemistry / chemistry questions and
answers / hello! just double checking the answers my organic
chemistry study guide. please go ahead and ...
Question: Hello! Just double checking the answers my
organic chemistry study guide. Please go ahead and ans...
Hello! Just double checking the answers my organic chemistry
study guide. Please go ahead and answer ALL the
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PLEASE let someone else do them!...
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