Part Three: Reactions Fill in the missing material for each reaction below. Be sure to use...
For the following reactions fill in the box with the missing major organic product. Make sure to include stereochemistry when appropriate. If a reaction affords a mixture of enantiomers draw only one enantiomer. In the space below the reaction draw a detailed arrow pushing mechanism for that reaction.
(10 points) Fill in the boxes with the missing starting material, intermediate products, reagents, and/or products. Then for each reaction draw the reaction mechanism with correct electron flow arrows if appropriate or intermediates and correct formal charges. -OH -NH2 NH (10 points) Use the Gabrielle synthesis to make your starting amine below. Then use this starting amine to synthesize the secondary amine using reductive amination. Draw the mechanisms for both reactions below. Be sure to draw correct intermediates, electron flow...
For each of the following reactions fill in the box to give the missing product(s). If no reaction occurs, write N.R. If the reaction produces a mixture of products, such as stereoisomers or constitutional isomers, give the structure of each product. If a major product arises, label it as so. Be sure to show stereochemistry when needed. 1. NaOH ОН 2. 1-iodopropane THF OH 1. NaH THE 2. 1-bromobutane THF 1. methanol Hg(OAc)2 H2SO4 2. NaBH4 THE H2SO4 YOH 140...
3. (21 points) Provide the major product for each reaction below. Be sure to indicate appropriate stereochemistry when OH HBr 90°C CH,CH OH Br CH,CH, ONa CH,CH, OH NaN, acetone - water (solvent) н,со, 1. TSCI, pyridine 2. LiBr, acetone 9. H.Co
Evening SN2 vs. E2 Homework Predict the major product(s) expected for each of the following reactions. Remember to indica stereochemistry, when appropriate. If no reaction is expected, write NR. a. CH3CN opothe Na t-BuO t-BuOH Rrot b. C. H3C d. H3C Br e. OH EtOH Pro NaN3 OH acetone poic NaOH Stos nlphe h. OTS EtOH pokc
1. (44 points) For the following reactions, fill in the correct structural formulas for the missing starting material, reagents or the products in the empty boxes. If there is no reaction then write NR. REMEMBER TO INCLUDE CORRECT STEREOCHEMISTRY FOR THE PRODUCTS AS NECESSARY. :CH
missing reagents, please explain 9. (20) For each of the following reactions, fill in the missing reagents for the formation of the product shown. Sequential steps. numbered. Reagent List: reagents from the list provided s necessary, should be HyC-Br Nah NaOH H,C- CH ( MCI) HBECH,OH Br-Br O=C=0 HOÀc) (LDA) 041 H2o depromat ΝΛΗ noad to Nattpostele Br Br-Brz H3C H-BK H4C1-NH2 H3C H,C CH, Br H2C+NCHE HEC CH2 LOA B
13. Reactions: Fill in the missing products for each of the boxes in the following reaction sequences. (30) OH Na2Cr2O7 H2SO4 H2O PCC NaBH HOCH, PBr3 Br2, H20 NaH BrMg- 2. H2O* NaOEt 1. OsO4 2. NaHSO3
(10 points) Draw the correct product for the reaction below. For step 2, draw the reaction mechanism. Be sure to include important intermediate compounds, electron flow arrows, and formal charges for full credit. ОН 1. SOCl2, pyridine 2. CH3NH2 (10 points) Fill in the boxes with the missing starting material, intermediate products, reagents, and/or products. Then for each reaction draw the reaction mechanism with Correct electron flow arrows if appropriate or intermediates and correct formal charges. -OH -NH2 NH (10...
Orgo chem help please Fill in the major organic product or products for the following reactions. Make sure to indicate stereochemistry where appropriate. Label each reaction with the mechanism used to get to the product (SN1, SN2, etc) Br H2O Br Br Br Br Br OH Heat Br Draw the complete mechanism for the first reaction (as practice you should draw the mechanism for all of them, based on what we learned in class)