Homework Answers
In this curve c is the point of equllibrium as delta G/delta E is zero.
So points all above it are the answers.
So answer is A B D E
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For the following free energy diagram, select ALL of the points for which the free energy...
Which of the following statements are true in regards to the following reaction coordinate diagram? Free...
Which of the following statements are true in regards to the following reaction coordinate diagram? Free Energy AE AE AE4 ΔΕ Progress of Reaction O There will be a higher concentration of reactants than products at equilibrium. okey > 1 The reactants are more stable than the products. 0 There will be a higher concentration of products than reactants at equilibrium. Keq < 1 O The products are more stable than the reactants.
8. A). Draw a Free energy diagram for each of the following reactions below. In your...
8. A). Draw a Free energy diagram for each of the following reactions below. In your diagram indicate the Free energy of activation (AGⓇ) and the overall free energy change (AGºra) (10 points) B). Determine which side of the equilibrium is favored (products or reactants). (5 points) C). Calculate the relative equilibrium constant for each the reaction. (Hint: use pKas) (5 points) NH2 @NH NaOH HC pk = 27 NH NH2 NaOH H.0 pka 4.6 SI
8. A). Draw a Free energy diagram for each of the following reactions below. In your...
8. A). Draw a Free energy diagram for each of the following reactions below. In your diagram indicate the Free energy of activation (AG°*) and the overall free energy change (AG®rxn) B). Determine which side of the equilibrium is favored (products or reactants). C). Calculate the relative equilibrium constant for each the reaction. (Hint: use pkas) NH2 ONH NaOH H20 + pka 27 NH3 NH2 + HO + NaOH pka = 4.6
8. A). Draw a Free energy diagram for each of the following reactions below. In your...
8. A). Draw a Free energy diagram for each of the following
reactions below. In your diagram indicate the Free energy of
activation (ΔG° ± ) and the overall free energy change (ΔG°rxn)
B). Determine which side of the equilibrium is favored (products
or reactants).
C). Calculate the relative equilibrium constant for each
reaction. (Hint: use pKas)
NH2 O:NH NaOH HO F pka = 27 É ŅHz+ ŅH2 + + NaOH HO F É pKa = 4.6
The diagram above shows the free energy G for several possible states (gray lines) of a...
The diagram above shows the free energy G for several possible
states (gray lines) of a chemical reaction. The black arrows
represent possible transitions between these states, and the
brackets represent the corresponding free energy differences.
Consider the meaning of the different terms in the relation:
?G = ?G°' + RTlnQ
Select the option which most closely corresponds to each
description.
Question 7 (1 point) Standard conditions Actual conditions 0 Equilibrium The diagram above shows the free energy G for...
8. (20 points) Consider the following mechanism, with the accompanying energy diagram, which has been suggested...
8. (20 points) Consider the following mechanism, with the accompanying energy diagram, which has been suggested for the following overall reaction in the presence of a Cl catalyst: 03 +0 202 Step 1: Step 2: 03 + Cl → OCl + O2 OCl + 0 + 02 + Cl +---Ea, Energy - - - - AHrxn --- - Reaction progress- A. Based on the energy diagram, which step is rate limiting? Which step is the fastest? (4 Points) B. Identify...
Energy diagrams (Basic) a. Based on the energy diagram - what can you conclude about this...
Energy diagrams (Basic) a. Based on the energy diagram - what can you conclude about this reaction? (2 points) C+D Free energy A + Progress of reaction b. Which of these processes could this free energy diagram represent? (select all that apply) (2 points) i. Metabolizing sugar for energy ii. Generation of fat stores from consumption of candy. iii. Boiling water iv. Dissolving salt in water v. Photosynthesis c. For one of the processes NOT selected above, explain why that...
4 pts Question 6 The free energy diagram for this reaction hav[ Select ] transition state(s)...
4 pts Question 6 The free energy diagram for this reaction hav[ Select ] transition state(s) and [Select) intermediat 3 Ü 13° Question 6 4 pts The free energy diagram for this reaction has (Select] + transition state(s) and ✓ Select] intermediate(s). + HS -
Consider the reaction coordinate diagram below and select which statement is FALSE, potential energy reaction coordinate...
Consider the reaction coordinate diagram below and select which statement is FALSE, potential energy reaction coordinate (progress of reaction) The reaction is spontaneous. The reaction is reactant favored. The equilibrium constant, K, for this reaction is greater than 1. AG for this reaction is negative.
Free Energy (kcal/mol) Reaction progress- Use the reaction energy diagram above to answer the following questions....
Free Energy (kcal/mol) Reaction progress- Use the reaction energy diagram above to answer the following questions. Calculate the activation energy, AG * , for the step D to C. kcal/mol Calculate the overall energy change, AGⓇ, for the process B to A. kcal/mol Which step is faster, (a) B to A or (b) C to D? - Free Energy (kcal/mol) Reaction progress - Use the reaction energy diagram above to answer the following questions. Calculate the activation energy, AG ,...
Which of the following statements are true in regards to the following reaction coordinate diagram? Free Energy AE AE AE4 ΔΕ Progress of Reaction O There will be a higher concentration of reactants than products at equilibrium. okey > 1 The reactants are more stable than the products. 0 There will be a higher concentration of products than reactants at equilibrium. Keq < 1 O The products are more stable than the reactants.
8. A). Draw a Free energy diagram for each of the following reactions below. In your diagram indicate the Free energy of activation (AGⓇ) and the overall free energy change (AGºra) (10 points) B). Determine which side of the equilibrium is favored (products or reactants). (5 points) C). Calculate the relative equilibrium constant for each the reaction. (Hint: use pKas) (5 points) NH2 @NH NaOH HC pk = 27 NH NH2 NaOH H.0 pka 4.6 SI
8. A). Draw a Free energy diagram for each of the following reactions below. In your diagram indicate the Free energy of activation (AG°*) and the overall free energy change (AG®rxn) B). Determine which side of the equilibrium is favored (products or reactants). C). Calculate the relative equilibrium constant for each the reaction. (Hint: use pkas) NH2 ONH NaOH H20 + pka 27 NH3 NH2 + HO + NaOH pka = 4.6
8. A). Draw a Free energy diagram for each of the following
reactions below. In your diagram indicate the Free energy of
activation (ΔG° ± ) and the overall free energy change (ΔG°rxn)
B). Determine which side of the equilibrium is favored (products
or reactants).
C). Calculate the relative equilibrium constant for each
reaction. (Hint: use pKas)
NH2 O:NH NaOH HO F pka = 27 É ŅHz+ ŅH2 + + NaOH HO F É pKa = 4.6
The diagram above shows the free energy G for several possible
states (gray lines) of a chemical reaction. The black arrows
represent possible transitions between these states, and the
brackets represent the corresponding free energy differences.
Consider the meaning of the different terms in the relation:
?G = ?G°' + RTlnQ
Select the option which most closely corresponds to each
description.
Question 7 (1 point) Standard conditions Actual conditions 0 Equilibrium The diagram above shows the free energy G for...
8. (20 points) Consider the following mechanism, with the accompanying energy diagram, which has been suggested for the following overall reaction in the presence of a Cl catalyst: 03 +0 202 Step 1: Step 2: 03 + Cl → OCl + O2 OCl + 0 + 02 + Cl +---Ea, Energy - - - - AHrxn --- - Reaction progress- A. Based on the energy diagram, which step is rate limiting? Which step is the fastest? (4 Points) B. Identify...
Energy diagrams (Basic) a. Based on the energy diagram - what can you conclude about this reaction? (2 points) C+D Free energy A + Progress of reaction b. Which of these processes could this free energy diagram represent? (select all that apply) (2 points) i. Metabolizing sugar for energy ii. Generation of fat stores from consumption of candy. iii. Boiling water iv. Dissolving salt in water v. Photosynthesis c. For one of the processes NOT selected above, explain why that...
4 pts Question 6 The free energy diagram for this reaction hav[ Select ] transition state(s) and [Select) intermediat 3 Ü 13° Question 6 4 pts The free energy diagram for this reaction has (Select] + transition state(s) and ✓ Select] intermediate(s). + HS -
Consider the reaction coordinate diagram below and select which statement is FALSE, potential energy reaction coordinate (progress of reaction) The reaction is spontaneous. The reaction is reactant favored. The equilibrium constant, K, for this reaction is greater than 1. AG for this reaction is negative.
Free Energy (kcal/mol) Reaction progress- Use the reaction energy diagram above to answer the following questions. Calculate the activation energy, AG * , for the step D to C. kcal/mol Calculate the overall energy change, AGⓇ, for the process B to A. kcal/mol Which step is faster, (a) B to A or (b) C to D? - Free Energy (kcal/mol) Reaction progress - Use the reaction energy diagram above to answer the following questions. Calculate the activation energy, AG ,...
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