Consider the following reaction .
a) Provide the IUPAC name of the reactant.
b) Identify the configuration of the reactant . Show the detailed working steps.
c) Draw the 3D structure for the major product expected to be formed.
d) Draw the reaction mechanism.
e) What is the effect on rate of reaction if the concentration of sodium hydroxide (NaOH) is doubled? Explain.
f) What is the effect on the reaction rate if the reactant is replaced with a primary alkyl hallide? Explain.
Homework Answers
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Consider the following reaction .
a) Provide the IUPAC name of the reactant.
b) Identify the...
28) The reaction of tert-butyl bromide, (CH,)CBr, with ethanol affords the substitution product tert-butyl ethyl ether,...
28) The reaction of tert-butyl bromide, (CH,)CBr, with ethanol affords the substitution product tert-butyl ethyl ether, (CH)1COCH CH, in acidic conditions. What would happen to the rate of the reaction if the concentration of ethanol was doubled? A) The rate remains the same. B) The rate decreases by a factor of 2 C) The rate increases by a factor of 2. D) The rate increases by a factor of 4. Circle the following alkyl halide that will undergo the fastest...
Draw the organic product(s) for the following chemical reaction. Underneath each reaction, provide a detailed mechanism(using...
Draw the organic product(s) for the following chemical reaction.
Underneath each reaction, provide a detailed mechanism(using
arrows) of how the product is produced when required.
FeCl3 n o + ch Fello Cl2 No Mechanism Polymerization Initiator *Since this is a polymerization, show the polymer using appropriate brackets. No Mechanism. H2O* Mechanism: "The above molecule polymerizes with itself. Show the polymer that is formed Mechanism: (show the formation of the trimer) 2) Draw the organic reactant(s) for the following chemical reaction....
Identify the product(s) of the following reaction, rationalizing their formation by drawing a detailed mechanism. Be...
Identify the product(s) of the following reaction, rationalizing their formation by drawing a detailed mechanism. Be sure to include the structures of any intermediates or transition states that are formed during the reactions. Remember to include lone pairs, partial or formal charges, and the absolute configuration (R or S) of any chiral centers. HO Ca Br ΗΣΗ + NaOH (10 marks) CCNL DMSO CH2CH3 (12 marks) C) CH3 C.Br CCH, CH CH OH + NaCN | Học (11 marks) HO...
need 35 and 38 (a) OH (b) 8.35 (SYN) For each of these compounds, draw an...
need 35 and 38
(a) OH (b) 8.35 (SYN) For each of these compounds, draw an alkyl halide that can be used to produce it in an S 1 reaction. Then, determine whether the alkyl halide would need to be treated with water or methanol and draw the corresponding mechanism. OCH 8.4 The Kinetics of SN2, Sn1, E2, and E1 Reactions 8.38 When benzyl bromide is treated separately with ki and CH,OH, the substitution products are different but the KI...
Name: 5. Identify the correct statement for the given reactions given. - Reaction A Reaction B...
Name: 5. Identify the correct statement for the given reactions given. - Reaction A Reaction B Room Temp. CH, a. Reaction A is an allylic halogenation reaction, and reaction B is an electrophilic addition reaction. b. Reaction A is an electrophilic addition reaction, and reaction B is an allylic substitution reaction. c. Reactions A and B are allylic substitution reactions. d. Reaction A is a displacement reaction, and reaction B is an allylic halogenation reaction. 6. The reaction of methyl...
1.Provide the major organic product of the reaction below. 2.Provide the major organic product of the...
1.Provide the major organic product of the reaction below.
2.Provide the major organic product of the reaction shown
below.
3.Provide the major organic product of the reaction shown
below.
4.Predict the necessary starting material for the reaction
below. Give the IUPAC name.
5.
Part A
Draw the carbonyl compound needed for this synthesis.
6.Predict the product formed when
CH3-CH2-C≡C:–Na+
undergoes a reaction with the compound shown below followed by an
aqueous workup..
Interactive 3D display mode
7. When 2,2-dibromo-1-phenylpropane is...
1. For the following Alkyl halide indicate which position will react under SN1 reaction conditions and...
1. For the following Alkyl halide indicate which position will react under SN1 reaction conditions and under SN2 reaction conditions. Explain your answer. mer 2. Draw the complete mechanism and the products for of the following SN1 reaction paying close attention to stereochemistry. H3C CI CH OH CH2CH3 општироотип солио 3. Provide the product/s for the following reactions. Indicate if the reactions proceed via an SN1, or SN2 mechanism. Indicate proper stereochemistry if it is applicable. Show the mechanisms NaCN...
hich of the following statements about the reactions of alkyme A) The characteristic reactions of alkyl...
hich of the following statements about the reactions of alkyme A) The characteristic reactions of alkyl halides are addition and elimination B) The characteristic reactions of alkyl halides are addition and substitution C) The characteristic reactions of alkyl halides are elimination and substitution D) The characteristic reactions of alkyl halides are oxidation and reduction. 2. The reaction of 1-bromobutane with sodium hydroxide affords the substitution product 1-butanol. What would happen to the rate of the reaction if the concentration of...
4. The chloroalkane Q can be hydrolysed by reaction with aqueous sodium hydroxide to give tertiary...
4. The chloroalkane Q can be hydrolysed by reaction with aqueous sodium hydroxide to give tertiary alcohol R. NaOH Hot Q R (a) Give the systematic IUPAC name for tertiary alcohol R. [1 mark] (b) What is the name of the mechanism that this reaction proceeds by? [1 mark] (c) Explain what is meant by the term order of reaction, and, based on your answer to (b), assign orders of reaction to chloroalkane Q and sodium hydroxide in this hydrolysis...
1. (2 points) Provide the IUPAC name for the following structure. он 2. (2 points) Draw...
1. (2 points) Provide the IUPAC name for the following structure. он 2. (2 points) Draw the structure from the provided name: 5-chloro-2,2-dimethylcyclohexane-1,3-dione. 3. (6 points) The following reaction produces five different substitution and elimination products, (a) Draw these products and (b) rank the stability of the elimination products by using the labels (E1-E3) according to the products as you have entered them. substitution product S1 substitution product S2 HzC04 CF, H-OH elimination product E1 elimination product E2 elimination product...
28) The reaction of tert-butyl bromide, (CH,)CBr, with ethanol affords the substitution product tert-butyl ethyl ether, (CH)1COCH CH, in acidic conditions. What would happen to the rate of the reaction if the concentration of ethanol was doubled? A) The rate remains the same. B) The rate decreases by a factor of 2 C) The rate increases by a factor of 2. D) The rate increases by a factor of 4. Circle the following alkyl halide that will undergo the fastest...
Draw the organic product(s) for the following chemical reaction.
Underneath each reaction, provide a detailed mechanism(using
arrows) of how the product is produced when required.
FeCl3 n o + ch Fello Cl2 No Mechanism Polymerization Initiator *Since this is a polymerization, show the polymer using appropriate brackets. No Mechanism. H2O* Mechanism: "The above molecule polymerizes with itself. Show the polymer that is formed Mechanism: (show the formation of the trimer) 2) Draw the organic reactant(s) for the following chemical reaction....
Identify the product(s) of the following reaction, rationalizing their formation by drawing a detailed mechanism. Be sure to include the structures of any intermediates or transition states that are formed during the reactions. Remember to include lone pairs, partial or formal charges, and the absolute configuration (R or S) of any chiral centers. HO Ca Br ΗΣΗ + NaOH (10 marks) CCNL DMSO CH2CH3 (12 marks) C) CH3 C.Br CCH, CH CH OH + NaCN | Học (11 marks) HO...
need 35 and 38
(a) OH (b) 8.35 (SYN) For each of these compounds, draw an alkyl halide that can be used to produce it in an S 1 reaction. Then, determine whether the alkyl halide would need to be treated with water or methanol and draw the corresponding mechanism. OCH 8.4 The Kinetics of SN2, Sn1, E2, and E1 Reactions 8.38 When benzyl bromide is treated separately with ki and CH,OH, the substitution products are different but the KI...
Name: 5. Identify the correct statement for the given reactions given. - Reaction A Reaction B Room Temp. CH, a. Reaction A is an allylic halogenation reaction, and reaction B is an electrophilic addition reaction. b. Reaction A is an electrophilic addition reaction, and reaction B is an allylic substitution reaction. c. Reactions A and B are allylic substitution reactions. d. Reaction A is a displacement reaction, and reaction B is an allylic halogenation reaction. 6. The reaction of methyl...
1.Provide the major organic product of the reaction below.
2.Provide the major organic product of the reaction shown
below.
3.Provide the major organic product of the reaction shown
below.
4.Predict the necessary starting material for the reaction
below. Give the IUPAC name.
5.
Part A
Draw the carbonyl compound needed for this synthesis.
6.Predict the product formed when
CH3-CH2-C≡C:–Na+
undergoes a reaction with the compound shown below followed by an
aqueous workup..
Interactive 3D display mode
7. When 2,2-dibromo-1-phenylpropane is...
1. For the following Alkyl halide indicate which position will react under SN1 reaction conditions and under SN2 reaction conditions. Explain your answer. mer 2. Draw the complete mechanism and the products for of the following SN1 reaction paying close attention to stereochemistry. H3C CI CH OH CH2CH3 општироотип солио 3. Provide the product/s for the following reactions. Indicate if the reactions proceed via an SN1, or SN2 mechanism. Indicate proper stereochemistry if it is applicable. Show the mechanisms NaCN...
hich of the following statements about the reactions of alkyme A) The characteristic reactions of alkyl halides are addition and elimination B) The characteristic reactions of alkyl halides are addition and substitution C) The characteristic reactions of alkyl halides are elimination and substitution D) The characteristic reactions of alkyl halides are oxidation and reduction. 2. The reaction of 1-bromobutane with sodium hydroxide affords the substitution product 1-butanol. What would happen to the rate of the reaction if the concentration of...
4. The chloroalkane Q can be hydrolysed by reaction with aqueous sodium hydroxide to give tertiary alcohol R. NaOH Hot Q R (a) Give the systematic IUPAC name for tertiary alcohol R. [1 mark] (b) What is the name of the mechanism that this reaction proceeds by? [1 mark] (c) Explain what is meant by the term order of reaction, and, based on your answer to (b), assign orders of reaction to chloroalkane Q and sodium hydroxide in this hydrolysis...
1. (2 points) Provide the IUPAC name for the following structure. он 2. (2 points) Draw the structure from the provided name: 5-chloro-2,2-dimethylcyclohexane-1,3-dione. 3. (6 points) The following reaction produces five different substitution and elimination products, (a) Draw these products and (b) rank the stability of the elimination products by using the labels (E1-E3) according to the products as you have entered them. substitution product S1 substitution product S2 HzC04 CF, H-OH elimination product E1 elimination product E2 elimination product...
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