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7. (3 pts each) Write the correct reactant, reagents, or major product of the following reactions...
ADraw the reactant required to produce each major product. Be sure to indicate the correct stereochemistry where appropriate. Нс CI Cl2, CH2CI, hv NH3 NH2 OCH3 KCO3 (a base) then CHaBr 1. Na (metal) 2. butyl bromide Осн Н.с. 1. Br2, hv, CHCl 2. methanolysis 1. mesyl chloride, pyridine NH2 HO 2. NH3 Он 1.TICI, py 2. H2O (hydrolysis) 1.TsCl, K2CO3 2. Nal (acetone) Page 5 of 8
VI. Reactions (21 pts) Provide the major product in the following reaction. If no reaction occurs, write "NR as the product. Show your work for each step!! Pay attention to Regiochemistry and Stereochemistry! TSCI EtyN 1. CHg-Br (xs) 2. Ag20, H20, A H-CI Et20 Sold lo no? NaBH CN a. NaNg, EtOH b. H20,4 OH 1. SOCI, pyridine 2. NaN, DMF 3. LIAIH, Et20
Predict the MAJOR product for the following reactions. (3 pts each) Br2, hv Br2, hv Br2, hv Bry, hv Provide the missing reagents for the following reactions. (Hint:There may be more than 1 step) (4pts each) OH HO
5. Complete the following reactions by filling in the missing Reactants, Reagents, or MAJOR Product. If TWO products are equally formed show BOTH. 1. DIBAL 2. H307 Colon - ohne кон ОН OH NH2 LIAIH4 1. LDA / Dry THE - to 1.LA/D THE 1.1.2 Equiv. LDA/THF 2. Br Br2 acetic acid Pyridine Heat Nat Et EtOH single product
please help!! praw the reactant required to produce each major product. Be sure to indicate the Walle! indicate the correst dereichemistry where appropria нс с Cl, CH CI, hv NH OCHS Kąco, (a base) then CH,BI 1. Na (metal) 2. butyl bromide OCH, 1. Brg, hv, CHCI HC- 2. methanolysis NH2 1. mesyl chloride, pyridine 2. NH3 1. TICI, py 2. H20 (hydrolysis) 1.TSCI, K2CO3 2. Nal (acetone) Page 5 of 8
racemiC 3. In each of the following problems, draw a starting material that could be used as a suitable precursor in the conversion to the given product. a. b. H3C CN 1. CH3CO3H 1. TsCI, pyridine 2. H'/H20 он 2. NaCN, DMSO racemic d. CH3 H CH2 1. Br2, hv 1. HBr, CH3CO2H 2. KOCH3 2. KOtBu, DMSO
VI. Reactions (21 pts) Provide the major product in the following reaction. It as the product Show your work for each stepll Pay attentio Stereochemistry! Product in the following reaction. If no reaction occurs, write" NR stepll pay attention to Regiochemistry and TSCI ElyN 1. CHy-Br (xs) 2 A0,0,H,O, A H-CI E-G NaBH,CN a. NaNs, EtOH b. H20, он 1. SOCI, pyridine 2. NaN, DMF 3. LIAIH, EL 0
Complete the following reactions. Provide the missing reactant(s) OR major organic product(s). Show correct regio- and stereochemistry for products you draw, where applicable Сн,, Zn(Cu) 1. OSONMO, pyridine 2. NaHSO, H,0 H2O* g. V 1. BH-THF 2. 1,0,, NaOH, HO - Y 1. MCPBA 2.4,00 DCM H,802, H2O heat 1., 2. Zn, AcOH
Predict the MAJOR product for the following reactions. (3 pts each) Br2, hv Br2, hv Br2, hv Br2, hv
Predict the MAJOR product for the following reactions. (3 pts each) Br2, hv Br2, hv Br2, hv Br2, hy