For cis-4-t-butylcyclohexanol and tras-4-t-butylcyclohexanol, why do the two isomeric products have different relative chromatographic movements?
Yes. two isomeric products, cis and trans -4-t-butylcyclohexanol will have different chromatographic moveents. Depends upon the interaction of hydroxyl group interaction with the chromatographic plate, it will move. In trans product, OH group is freely appear so it will interact with chromatographic plate more so it has high polarity. In cis,isomer there is a steric hindrance so, we can expect it will move faster.
For cis-4-t-butylcyclohexanol and tras-4-t-butylcyclohexanol, why do the two isomeric products have different relative chromatographic movements?
6. When the alkene shown below is treated with NBS, two isomeric products (ignoring R/S stereoisomers) are formed. A. (4 points) Draw the structures of these two products. (Hint: do part "B" first) NBS hv/CCl4 (4 points) Draw the structure of the allylic radical that is formed at the beginning of the propagation step, and then draw its resonance structure. B. C. (4 points) Draw the structure of the MAIOR product and give reasons for your choice.
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