MC3 20 give the product of the following electrophilic aromatic substitution reaction HNO3 /H2SO4 NO2 ON...
Consider the reactivity of phenol, bromobenzene, toluene, and nitrobenzene toward electrophilic aromatic substitution. 1.) The most reactive compound is (pick one: phenol, bromobenzene, toluene, and nitrobenzene) because the (pick one: electron donating or electron withdrawing) character of the (pick one: alcohol group, methyl group, bromine atom, or nitro group) increases the rate of the reaction. 2.) The least reactive compound is (pick one: phenol, bromobenzene, toluene, and nitrobenzene) because the (pick one: electron donating or electron withdrawing) character of the...
3.) (12 points) For the following electrophilic aromatic substitiution reaction: 02N. CN CN CN HNO3 H2SO4 O2N в a) Which product is the major one? b) Draw a complete mechanism for the formation of the major product, labelling the rate-determining step. c) Referring back to the mechanism you drew in part b, explain your choice of part a
Which of the following sets of substituents are all ortho/para directing in electrophilic aromatic substitution reactions? O CN, NO2, COCH3 O CI, OH, CH3 OBr, OH, COCH3 OCI, CH3. CN
Which of the following molecules is the most reactive towards electrophilic aromatic substitution (EAS)? (all EDG on the benzene) Н. CH3 CN SO3H NO2 OME 1 II IV
4. When 10 g of benzene (Molar mass 78 g/mol) reacts with 9 mL of concentrated HNO3 (16 M) and 9 mL of H2SO4 (18 M), 8.1 g of nitrobenzene (molar mass 123 g/mol) and 1.2 g of an unknown compound with a high boiling point are obtained. a. Identify the limiting reagent. b. Calculate the percent yield of nitrobenzene. c. Give the name and structure of the most probable side product with the high melting point. d. Explain, with...
Which compound is the least reactive in the aromatic
electrophilic substitution reaction?
What product would you expect from the following reaction?
Answer both, please.
1. Which compound is the least reactive in the aromatic electrophilic substitution reaction? NH . B NH С. SOH Logo D. NO2 E 2. What product would you expect from the following reaction? CO.CH ÇO.CH А ÇOCH B OCH, D CO.CH E
3. The electrophilic aromatic substitution (EAS) reaction is a great way to prepare substitute Provide the expected major product for each of the following EAS reactions. (12 pts) SO3H HNO3 H2SO4 CH2CH3 CI AICI en Enhen II Ph-C-NHÓh Br2 CH3 -CH₃ CH3 FeBr3
Aromatic substitution
Give the major product of the following reaction. HNO, OH HSC HC Give the major product of the following reaction: HASA Electrophilic aromatic substitution usually occurs at the 1-position of naphthalene. Give the major product of the following reaction. Give the major product of the following reaction. Draw the starting material if no reaction occurs. Give the major product of the following reaction. Draw the starting material if no reaction occurs. NO 2 Give the major product of...
Consider the electrophilic aromatic substitution reaction shown and draw the structure of the resulting organic product. NH2 NaNO2, HCI, 2 °C O2N
When naphthalene undergoes an irreversible electrophilic aromatic substitution, the major product is the kinetic product, which proceeds through the most stable arenium ion intermediate. With this in mind, draw the curved arrow mechanism for the first step of the electrophilic aromatic substitution of naphthalene with l^+ generated from l_2 and CuCl_2. If you predicted the correct regiochemistry in the first step, then you can draw the curved arrows and a resonance structure in step 2 with an unbroken benzenoid ring....