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questions 6 and 7
QUESTION 6 Low spin octahedral complexes are always diamagnetic True False QUESTION...
Which dorbital configuration has the highest crystal field stabilization energy (CFSE) in a low spin octahedral...
Which dorbital configuration has the highest crystal field stabilization energy (CFSE) in a low spin octahedral crystal field? d4 d3 d6 ОООО g8 d? Predic whether the following complex is diamagnetic or paramagentic. 72+ paramagnetic need more information to answer this question diamagnetic The magnetic property of a transition metal complex can be predicted using crystal field theory. If we assume that the magnetic moment arises entirely from unpaired electron spins then the "spin only magnetic moment (us) is given...
can anyone please confirm my answers for 5&6? And can you explain how to fill in...
can
anyone please confirm my answers for 5&6? And can you explain
how to fill in the electrons for 7? Please and Thank you.
5. The values of A, for some coordination complexes are given below. (a) [Fe(ox)) --- 14,100 cm-1 (ox-oxalato ligand-----weak ligand] (b) [Fe(CN).-----35,000 cm ©) [Fe(CN)6]* -----33,800 cm (1) Explain reason(s) why A. of complex (a) and (b) are different (ii) Explain reason(s) why 4, of complex (b) and (c) are different 6. Answer the following questions...
questions 4 and 5 Minbox (249) -rheem.rammal x Take Test: Crystal Field Theo X o ora...
questions 4 and 5
Minbox (249) -rheem.rammal x Take Test: Crystal Field Theo X o ora edu/webapps/assessment/take/launch.jsp?course_assessment id=_234074_1&course_id=_2163 WebAdvisor Main.. http://prospective... Welcome, R G Google M Inbox - rammal... Question Completion Status: QUESTION 4 The d orbitals for a free metal ion (non-complexed) are lower in energy than the orbitals in an octahedral field. True False QUESTION 5 Match each ion with the correct number of UNPAIRED ELECTRONS as predicted in an octahedral field. 003 low spin pa3+ low spin...
Crystal Field Question. I understand that octahedral shapes have larger splitting energies then in tetrahedral complexes....
Crystal Field Question.
I understand that octahedral shapes have larger splitting energies
then in tetrahedral complexes. And it would take more energy to
split more electrons. So would the order be from Highest to Lowest:
B>A>C where A, B, C are the compounds listed in their
respective orders.
Between Ni(H20)s2+ ; Ni(en)32+; and lowest and why? Cu(CN)42- which has highest splitting and which has
Question 1: Consider the complex ion [Mn(OH2)6] with 5 unpaired electrons. Which response includes all the...
Question 1: Consider the complex ion [Mn(OH2)6] with 5 unpaired electrons. Which response includes all the following statements that are true, and no false statements? I. It is diamagnetic. II. It is a low spin complex III. The metal ion is a d ion IV. The ligands are weak field ligands V. It is octahedral (a) I, II (b) II, IV, V (c) I, IV (d) II, V (е) Ш, IV
a. Predict the structure of [Cr(OH2)6]2+ - I wrote that the complex will undergo Jahn-Teller distortion,...
a. Predict the structure of [Cr(OH2)6]2+ - I wrote that the complex will undergo Jahn-Teller distortion, making the octahedral complex become tetragonal (don't know if that's correct) b. Account for the variation in the lattice enthalpy of Mn (2780 kJ/mol), Fe (2926 kJ/mol), Co (2976 kJ/mol), Ni (3060 kJ/mol), and Zn (2985 kJ/mol) flouride given that the metal center in all of the flourides is surrounded by an octahedral array of F-ions. c. Explain the effect on the d-orbital energies...
3. [Ti(H20)6]3+ is an octahedral complex. (9 pts) a. Name this complex. b. How many d...
3. [Ti(H20)6]3+ is an octahedral complex. (9 pts) a. Name this complex. b. How many d electrons does it have? C. Sketch the d-orbital diagram for the complex. Label the energy levels (tzg and eg) and each of the d-orbitals. d. A. is 3.99 x 10-19) (per photon). What is the value of A, in kJ/mol? e. Calculate the wavelength of light (nm) needed to excite an electron from the tz, to the eg orbital. f. What color of the...
Hello. Based on the textbook below I solved a true or false problem. textbook: 1. Light...
Hello. Based on the textbook below I solved a true or false problem. textbook: 1. Light absorption: Sunlight absorbs in the battery 2. Charge generation: Free electrons and holes are generated inside the cell by the absorbed light. 3 Charge Separation: Free electrons and holes are separated by an electric field created at the p-n junction. 4. Charge collection: free electrons move toward n-type semiconductor and holes move toward p-type semiconductor Problem: In solar cells made of organic semiconductors, electron-hole...
1) Choose true (T) or false (F) to the following statements: a) Light is a...
1) Choose true (T) or false (F) to the following statements: a) Light is a shower of protons b) Light is a type of energy embodied in electric and magnetic fields c) The speed of light in vacuum is 3.00 x 108 m/s d) The speed of light in vacuum is 3.00 x 108 km/s 2) Choose the correct statement a) We can characterize a wave only by its amplitude b) Electric and magnetic...
In the complex ion [ML6]n+, Mn+ has five d electrons and L is a strong field...
In the complex ion [ML6]n+, Mn+ has five d electrons and L is a strong field ligand. According to crystal field theory, the magnetic properties of the complex ion correspond to how many unpaired electrons? A. 0 B. 1 C. 2 D. 3 E. 5 Which one of these complex ions would absorb light with the shortest wavelength? A. [Co(H2O)6]2+ B. [Co(NH3)6]2+ C. [CoF6]4– D. [Co(CN)6]4– E. [Co(en)6]2+ The ion [Co(NH3)6]2+ is octahedral and high spin. This complex is (4pts)...
Which dorbital configuration has the highest crystal field stabilization energy (CFSE) in a low spin octahedral crystal field? d4 d3 d6 ОООО g8 d? Predic whether the following complex is diamagnetic or paramagentic. 72+ paramagnetic need more information to answer this question diamagnetic The magnetic property of a transition metal complex can be predicted using crystal field theory. If we assume that the magnetic moment arises entirely from unpaired electron spins then the "spin only magnetic moment (us) is given...
can
anyone please confirm my answers for 5&6? And can you explain
how to fill in the electrons for 7? Please and Thank you.
5. The values of A, for some coordination complexes are given below. (a) [Fe(ox)) --- 14,100 cm-1 (ox-oxalato ligand-----weak ligand] (b) [Fe(CN).-----35,000 cm ©) [Fe(CN)6]* -----33,800 cm (1) Explain reason(s) why A. of complex (a) and (b) are different (ii) Explain reason(s) why 4, of complex (b) and (c) are different 6. Answer the following questions...
questions 4 and 5
Minbox (249) -rheem.rammal x Take Test: Crystal Field Theo X o ora edu/webapps/assessment/take/launch.jsp?course_assessment id=_234074_1&course_id=_2163 WebAdvisor Main.. http://prospective... Welcome, R G Google M Inbox - rammal... Question Completion Status: QUESTION 4 The d orbitals for a free metal ion (non-complexed) are lower in energy than the orbitals in an octahedral field. True False QUESTION 5 Match each ion with the correct number of UNPAIRED ELECTRONS as predicted in an octahedral field. 003 low spin pa3+ low spin...
Crystal Field Question.
I understand that octahedral shapes have larger splitting energies
then in tetrahedral complexes. And it would take more energy to
split more electrons. So would the order be from Highest to Lowest:
B>A>C where A, B, C are the compounds listed in their
respective orders.
Between Ni(H20)s2+ ; Ni(en)32+; and lowest and why? Cu(CN)42- which has highest splitting and which has
Question 1: Consider the complex ion [Mn(OH2)6] with 5 unpaired electrons. Which response includes all the following statements that are true, and no false statements? I. It is diamagnetic. II. It is a low spin complex III. The metal ion is a d ion IV. The ligands are weak field ligands V. It is octahedral (a) I, II (b) II, IV, V (c) I, IV (d) II, V (е) Ш, IV
3. [Ti(H20)6]3+ is an octahedral complex. (9 pts) a. Name this complex. b. How many d electrons does it have? C. Sketch the d-orbital diagram for the complex. Label the energy levels (tzg and eg) and each of the d-orbitals. d. A. is 3.99 x 10-19) (per photon). What is the value of A, in kJ/mol? e. Calculate the wavelength of light (nm) needed to excite an electron from the tz, to the eg orbital. f. What color of the...
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