Homework Answers
a. N-H bonding character is the correct option because these three orbitals comprise N-H bond. as NH3 has 8 valence electrons, consisting of a lone pair on its nitrogen and 3 N-H sigma bonds. The s orbitals for the 3 hydrogens are used to set up the sigma and anti bonding combinations of N sp3 orbitals and H 1s orbitals. The H3 1s orbitals form an a1 and e combination.
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Look at the MO diagram for NH3 shown below. Which property does each of the e...
please answer question 9 using the attached figure %. Refer to Figure 5.17 in the textbook....
please answer question 9 using the attached figure
%. Refer to Figure 5.17 in the textbook. Read the discussion on bonding in BH, in section 2.0. (a) Why does the 2p, atomic orbital become a non-bonding M.O. in BH, but is involved in bonding in NH? (consider what is required for an orbital on one atom to bond with an orbital on another atom or an LGO; consider the differences between the MO diagram for BH: in Fig 5.17 and...
Sketch the qualitative molecular orbital energy diagram for water. Inclu symmetry labels for each...
Sketch the qualitative molecular orbital energy diagram for water. Inclu symmetry labels for each molecular orbital. Indicate whether each molecular bonding, nonbonding, or anti-bonding and don't forget the σ and π labels. Remember to construct appropriate group orbitals from the outer H-atoms. Describe the bonding of this molecule from the MO diagram you constructed, including the location s) of the lone pair(s). The 2s and 2p energies for oxygen are -26 and -13 eV, respectively, and the ls energy of...
Could you show how to do (d) step by step, please? AO = Atomic orbital MO = Molecular orbital (L)GO= (Ligand) Group orb...
Could you show how to do (d) step by step, please?
AO = Atomic orbital
MO = Molecular orbital
(L)GO= (Ligand) Group orbital
2. TaHs has a square pyramidal geometry and a Cev symmetry. (a) Assign x, y, z coordinates on the atoms: - Z axis on central Ta atom is the principal rotation axis (z axes on other atoms are colinear) - X, y axes on central Ta atom match Ta-H bonds (x, y axes on other atoms are...
4. On the basis of molecular orbitals and molecular orbital diagrams, predict which molecule in each...
4. On the basis of molecular orbitals and molecular orbital diagrams, predict which molecule in each series will have the longest bond. Be sure to provide a brief explanation a. B2, B2 b. 02*, 0,- c. HHe", Hz 5. Consider the hydroxide ion, OH and do the following: a. Prepare a molecular orbital diagram and fill with electrons given the following atomic orbital potential energies: O(2s) = -32.3 eV, O(2p) = -15.8 eV, H(s) -13.6 eV. Be sure to label...
question 1 2 3 4 5 6 Which are correct? In molecular orbital (MO) energy level...
question 1 2 3 4 5 6
Which are correct? In molecular orbital (MO) energy level diagram for cyanide ion? The MO shows: (a) bond order = 2 (b) bonder order =3 ) cyanide ion is paramagnetic ) cyanide ion is! diamagnetic (e) HOMO is nu HOMO is og (6%) (2) Write down the diatomic molecules 2p orbitals for (a), (b), (6%) (3) What is the bond order of (a) OF(b) to which atom ( O or F ) the...
1) **The electron configurations of five different elements are shown below. Which of these elements is...
1) **The electron configurations of five different elements are shown below. Which of these elements is expected to have the largest second ionization energy (IE2)?** (a) 1s 2s 2p 3s1 (b) 152 2s22p6352 (c) 152 282 2p 3s 3p1 (d) 152 252 2p6 352 3p4 (e) 1s 2s 2p 3s 3p5 2) **A single Lewis Structure of the formate ion (HCO2) is shown below. Which statement best describes the bonding character of this ion?** H-C-0: 10: (a) One double bond...
Question 10: Objective Question: Circle the letter corresponding to the BEST answer for each multiple choice...
Question 10: Objective Question: Circle the letter corresponding to the BEST answer for each multiple choice question. Partial credit may be awarded for incorrect answers where some correct work is shown. (3X9=27 points) A. Which of the following atom/ion is described by the electronic configuration 1s 2s 2p? a) Na b) c) Mg d) O B. Which type of bonding is present in the compound CH,COONa? a) lonic bonding b) Covalent bonding c) Hydrogen bonding d) lonic and covalent bonding...
Draw molecular orbital energy level diagram for CH3 by following the steps given below. Valance orbital...
Draw molecular orbital energy level diagram for CH3 by following the steps given below. Valance orbital ionization potentials: H(1s) - 13.6 eV, C(2s) -19.5 eV, C(2p) -10.7 ev. (6C, 11) E x +y?,z? 1 1 1 203 3C on 1 1 1 1 1 1 1 T - 1 0 2 1 1 -1 | 1 -1 1 -1 -1 TOT- 2 25; 1 1 - 1 1 -1 1 -1 1 30, 1 1 1 -1 0 1 -1...
3. (cont).(c) (10 pts) Now consider the MO diagram below, which could be used to describe...
3. (cont).(c) (10 pts) Now consider the MO diagram below, which could be used to describe the bonding. Explain whether NO+ or NO- would have a stronger bond. 2po* 2p* 2prº P. 20.P. 2p. 2p 2pr 2pm 2pc 25 25 Which one is stronger? Why? 4. Stronger bond = (d) (10 pts) What bond order would you predict for neutral NO? BO = Consider the following terms used to describe molecular structure: linear, bent, trigonal planar, trigonal pyramidal, tetrahedral, and...
9. Consider the shorthand structure below (which also does not show lone pair electrons on N,...
9. Consider the shorthand structure below (which also does not show lone pair electrons on N, O, or S). H S OH 0 CE (a) (5 pts each) Fill in the correct number next to the atomic symbol, for the molecular formula of this compound. H= C=__ N= S = (b) (5 pts each) For each of the atoms indicated by a, b, c, indicate the hybrid atomic orbitals you would expect it to be using to bond. a =...
please answer question 9 using the attached figure
%. Refer to Figure 5.17 in the textbook. Read the discussion on bonding in BH, in section 2.0. (a) Why does the 2p, atomic orbital become a non-bonding M.O. in BH, but is involved in bonding in NH? (consider what is required for an orbital on one atom to bond with an orbital on another atom or an LGO; consider the differences between the MO diagram for BH: in Fig 5.17 and...
Sketch the qualitative molecular orbital energy diagram for water. Inclu symmetry labels for each molecular orbital. Indicate whether each molecular bonding, nonbonding, or anti-bonding and don't forget the σ and π labels. Remember to construct appropriate group orbitals from the outer H-atoms. Describe the bonding of this molecule from the MO diagram you constructed, including the location s) of the lone pair(s). The 2s and 2p energies for oxygen are -26 and -13 eV, respectively, and the ls energy of...
Could you show how to do (d) step by step, please?
AO = Atomic orbital
MO = Molecular orbital
(L)GO= (Ligand) Group orbital
2. TaHs has a square pyramidal geometry and a Cev symmetry. (a) Assign x, y, z coordinates on the atoms: - Z axis on central Ta atom is the principal rotation axis (z axes on other atoms are colinear) - X, y axes on central Ta atom match Ta-H bonds (x, y axes on other atoms are...
4. On the basis of molecular orbitals and molecular orbital diagrams, predict which molecule in each series will have the longest bond. Be sure to provide a brief explanation a. B2, B2 b. 02*, 0,- c. HHe", Hz 5. Consider the hydroxide ion, OH and do the following: a. Prepare a molecular orbital diagram and fill with electrons given the following atomic orbital potential energies: O(2s) = -32.3 eV, O(2p) = -15.8 eV, H(s) -13.6 eV. Be sure to label...
question 1 2 3 4 5 6
Which are correct? In molecular orbital (MO) energy level diagram for cyanide ion? The MO shows: (a) bond order = 2 (b) bonder order =3 ) cyanide ion is paramagnetic ) cyanide ion is! diamagnetic (e) HOMO is nu HOMO is og (6%) (2) Write down the diatomic molecules 2p orbitals for (a), (b), (6%) (3) What is the bond order of (a) OF(b) to which atom ( O or F ) the...
1) **The electron configurations of five different elements are shown below. Which of these elements is expected to have the largest second ionization energy (IE2)?** (a) 1s 2s 2p 3s1 (b) 152 2s22p6352 (c) 152 282 2p 3s 3p1 (d) 152 252 2p6 352 3p4 (e) 1s 2s 2p 3s 3p5 2) **A single Lewis Structure of the formate ion (HCO2) is shown below. Which statement best describes the bonding character of this ion?** H-C-0: 10: (a) One double bond...
Question 10: Objective Question: Circle the letter corresponding to the BEST answer for each multiple choice question. Partial credit may be awarded for incorrect answers where some correct work is shown. (3X9=27 points) A. Which of the following atom/ion is described by the electronic configuration 1s 2s 2p? a) Na b) c) Mg d) O B. Which type of bonding is present in the compound CH,COONa? a) lonic bonding b) Covalent bonding c) Hydrogen bonding d) lonic and covalent bonding...
Draw molecular orbital energy level diagram for CH3 by following the steps given below. Valance orbital ionization potentials: H(1s) - 13.6 eV, C(2s) -19.5 eV, C(2p) -10.7 ev. (6C, 11) E x +y?,z? 1 1 1 203 3C on 1 1 1 1 1 1 1 T - 1 0 2 1 1 -1 | 1 -1 1 -1 -1 TOT- 2 25; 1 1 - 1 1 -1 1 -1 1 30, 1 1 1 -1 0 1 -1...
3. (cont).(c) (10 pts) Now consider the MO diagram below, which could be used to describe the bonding. Explain whether NO+ or NO- would have a stronger bond. 2po* 2p* 2prº P. 20.P. 2p. 2p 2pr 2pm 2pc 25 25 Which one is stronger? Why? 4. Stronger bond = (d) (10 pts) What bond order would you predict for neutral NO? BO = Consider the following terms used to describe molecular structure: linear, bent, trigonal planar, trigonal pyramidal, tetrahedral, and...
9. Consider the shorthand structure below (which also does not show lone pair electrons on N, O, or S). H S OH 0 CE (a) (5 pts each) Fill in the correct number next to the atomic symbol, for the molecular formula of this compound. H= C=__ N= S = (b) (5 pts each) For each of the atoms indicated by a, b, c, indicate the hybrid atomic orbitals you would expect it to be using to bond. a =...
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