4. Suppose that when the cell potential for the unknown solution in # 3 was measured,...
a.) A voltaic cell is constructed in which the cathode is a standard hydrogen electrode and the anode is a hydrogen electrode (P(H2) = 1 atm) immersed in a solution of unknown [H+]. If the cell potential is 0.204 V, what is the pH of the unknown solution at 298 K? b.) An electrochemical cell is constructed in which a Cr3+(1.00 M)|Cr(s) half-cell is connected to an H3O+(aq)|H2(1 atm) half-cell with unknown H3O+ concentration. The measured cell voltage is 0.366...
Use measured cell potential to calculate concentration. When [ Hg2+ ]=1.35 M, the observed cell potential at 298K for an electrochemical cell with the reaction shown below is 2.582 V. What is the Al** concentration in this cell? 3 Hg2+ (aq) + 2 Al (s) — 3 Hg (1) + 2 A1+ (aq) [A13+]= M
A galvanic cell consists of a chromium anode immersed in a CrSO4 solution and a cobalt cathode immersed in a CoSO, solution. A salt bridge connects the two half-cells (a) Write a balanced equation for the cell reaction. + (b) A current of 1.33 A is observed to flow for a period of 1.61 hours. How much charge passes through the circuit during this time? How many moles of electrons is this charge equivalent to? C mol (c) Calculate the...
Use the References to access important values if needed for this question. A student does an experiment to determine the molar solubility of lead chloride. He constructs a voltaic cell at 298 K consisting of a 0.709 M lead nitrate solution and a lead electrode in the cathode compartment, and a saturated lead chloride solution and a lead electrode in the anode compartment. If the cell potential is measured to be 4.96×10-2 V, what is the value of Ksp for...
4.In a electrochemical cell consisting of a silver electrode in a solution of AgNO3 and a gold electrode in a solution of Au(NO3)3 at standard conditions, the correct cell potential is 0.70 V b. 2.30 V 0.90 V d. -0.90 V 5. Predict which of the following reactions would exhibit an increase in entropy based on the nature of the reactants and products. 2H2(g) + O2(g) → 2H2O(g) 2NO2(g) → N2O4(g) H+(aq) + F-(aq) → HF(aq) BaF2(s) → Ba2+(aq) +...
In a galvanic cell, one half-cell consists of a lead strip dipped into a 1.00 M solution of Pb(NO). In the second half-cell, solid germanium is in contact with a 1.00 M solution of Ge(NO), Ge is observed to plate out as the galvanic cell operates, and the initial cell voltage is measured to be 0.250 V at 25°C. (a) Write balanced equations for the half-reactions at the anode and the cathode. Show electrons as e'. Use the smallest integer...
The half cell voltage for a Fe^3+/Fe^2+ electrode is measured to be +0.810V. Based on this information, and the E°red values provided, which species has a higher concentration? Fe^3+(aq) +e- --> Fe^2+(aq) E°red= 0.771V Fe^3+(aq) +3e- --> Fe(s) E°red= -0.037V Fe^3+(aq) +2e- --> Fe(s) E°red= -0.447V
Use the References to access important values if needed for this question An electrochemical cell consists of a Pt/H(aq,1.00 M) H (8) cathode connected to a Pt/H(aq)|Hz(8) anode in which the H concentration is that of a buffer consisting of a weak acid, HA(0.117 M), mixed with its conjugate base, A (0.193 M). The measured cell voltage is Ecell -0.169 V at 25 °C, with Pt. -1.00 atm at both electrodes. Calculate the pH in the buffer solution and the...
5. What was the purpose of the NaNO3 solution in this experiment? 6. Could a solution of NaCl be used instead of NaNO3? 7. What was the purpose of FeSO4 solution in this experiment? 8. Could a solution of FeCl, be used instead of FeSO4? 9. Could a solution of NaSO4 be used instead of FeSO4? 10. Calculate the standard cell potential for the spontaneous redox reaction between a Pb(s)/Pb(NO3)2(aq) half-cell and a Ag(s)/AgNO3(aq) half-cell. Which metal would be oxidized?...
i answered 0.58 but I got it wrong. can you help/solve? Question: A chemist measures the potential of an electrochemical cell vs. the saturated calomel electrode to be +0.5V. Then, the chemist switches the reference electrode to the silver-silver chloride electrode. What should the voltage read? Use the following diagram to assist your thought process: Previously we discussed a calomel reference electrode. A second type of reference electrode is also very common in lab - this one is called the...