Homework Answers
11) in this C1 are all sigma bonds due to all sigma bond it shows sp3 hybridization in C2 carbon two pi bonds due to two pi bonds it is sp hybridization
12) based on s percent
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11. Specify the hybridization on the carbons shown in the following structure. o" 1: sp 2:...
6. (6 marks) Consider the hybridization in the following structure (not all lone pairs explicitly shown)....
6. (6 marks) Consider the hybridization in the following structure (not all lone pairs explicitly shown). | Y 0 & CH N JOH H₂C Z Specify what orbitals overlap to form the designated bonds? (Circle the appropriate orbital in the list provided beside each atom.) sigma bond between carbon "Y" and nitrogen orbital on carbon "y" SPdf spsp?sp orbital on nitrogen: S P d f sp sp? sp? ii. pi bond between oxygen "X" and carbon "Y orbital on oxygen...
can someone please help me 6. (6 marks) Consider the hybridization in the following structure (not...
can someone please help me
6. (6 marks) Consider the hybridization in the following structure (not all lone pairs explicitly shown). o CH₂ Y- > C-N НС ОН Specify what orbitals overlap to form the designated bonds? (Circle the appropriate orbital in the list provided beside each atom.) i sigma bond between carbon "Y" and nitrogen orbital on carbon "Y": 5 p d f sp sp? sp? orbital on nitrogen: S p d f sp sp? sp3 ii. pi bond...
Extra Credit The properties of the hybrid orbitals (energy, most probable radius, electronegativity, ete.) will be...
Extra Credit The properties of the hybrid orbitals (energy, most probable radius, electronegativity, ete.) will be determined by: (1), the properties of the atomie orbitals that the hybrid orbitals contain (2) the contribution that each orbital type makes to the hybrid mixture. Questions: In each case justify your response 1) In which of the following hybrid orbitals will electrons be the highest in energy? 2) In which will the electrons be lowest in energy? sp, spl. sp, sp'd spid (assume...
Passage 11 (Questions 1-9) Dienes, a special group of alkenes, can be classified as conjugated or...
Passage 11 (Questions 1-9) Dienes, a special group of alkenes, can be classified as conjugated or isolated. Conjugated dienes are alkenes with alternating double and single bonds. Isolated dienes have double bonds separated by more than one single bond. One explanation for this observation is the hybridization theory. According to the hybridization theory, the stability of conjugated dienes comes from the hybridization of the orbitals forming the carbon-carbon single bonds. For example, in 1,4-pentadiene, the C-C single bonds result from...
2. The structure of the commonly used organic solvent dimethylformamide (DMF) is shown below. The numbers...
2. The structure of the commonly used organic solvent dimethylformamide (DMF) is shown below. The numbers by each carbon atom are shown to distinguish each C atom in the molecule. Using Valence Bond Theory, answer the questions in parts a) and b). (4 pts) o: н LH H) N )H -Co HIH Dimethylformamide a) Specify the hybrid orbitals for each atom in the molecule indicated below C 2): N: C(1): b) Identify the bond type(s) and the overlapping orbitals of...
Complete the Lewis structure of the compound shown below and indicate which of the following statements are true. 46 Η...
Complete the Lewis structure of the compound shown below and indicate which of the following statements are true. 46 Η Η H C =C-C-N H=21日 An sp2 hybrid orbital on C-1 overlaps with an sp hybrid orbital on C-2 to form the sigma bond between C-1 and C-2. There are ten o bonds in this molecule. There are five i bonds in this molecule. The C-2 and C-3 atoms cannot rotate about the internuclear axis between the two atoms since...
Match each of the following ions and molecules with its correct molecular Complete the Lewis structure...
Match each of the following ions and molecules with its correct molecular Complete the Lewis structure of the chlorite ion, ClO2-, which is used as a bleaching agent. Complete only two resonance structure in which the formal charges are closest to zero. What is the valence molecular orbital configuration (according to MO theory) of homonuclear diatomic species where the atoms have an atomic number greater than seven? How many electrons are there in the pi antibonding orbitals of the following...
QUESTION 11 Match the alom indicated with the correct hybridization for the molecule CHCOOH (scetic acid)...
QUESTION 11 Match the alom indicated with the correct hybridization for the molecule CHCOOH (scetic acid) of the CH csup>3<sup> - Cof the COOH - In the CEO bond - in the CO H portion Acis in CO bond and thus is sp Bo has electron domains but is sp C carbon has & electron domains and so is sp 0.has only 3 electron domains and so is sp? QUESTION 12 in the compound CH CH The hybridization of both...
Answer the following on a separate sheet of paper. 1. Using the data collected for PF,...
Answer the following on a separate sheet of paper. 1. Using the data collected for PF, SF, and CIF, what structural comments can be made about molecules with more than four groups (charge clouds) around the central atom? 2. Select which structure is preferred and discuss why? SC 3. To assess the stability of the axial versus equatorial positions for a trigonal bipyramidal structure, a computer program was used to determine the energy to assess SF, with the lone pair...
Question 1 and 2 of the worksheet? Shang 22 In this figure, P2 is lower energy...
Question 1 and 2 of the worksheet?
Shang 22 In this figure, P2 is lower energy than P1. By the Hammond postulate, TS2 is also lower energy as well as structurally more like the reactants. Thus the activation energy. EA[2) is also lower Trends in Nucleophile Strength For this discussion, we have to assume the rate factors above apply in reverse that a faster reaction rate is associated with a more exothermic reaction. For nucleophiles, the neutral nucleophiles (amines, alcohols,...
6. (6 marks) Consider the hybridization in the following structure (not all lone pairs explicitly shown). | Y 0 & CH N JOH H₂C Z Specify what orbitals overlap to form the designated bonds? (Circle the appropriate orbital in the list provided beside each atom.) sigma bond between carbon "Y" and nitrogen orbital on carbon "y" SPdf spsp?sp orbital on nitrogen: S P d f sp sp? sp? ii. pi bond between oxygen "X" and carbon "Y orbital on oxygen...
can someone please help me
6. (6 marks) Consider the hybridization in the following structure (not all lone pairs explicitly shown). o CH₂ Y- > C-N НС ОН Specify what orbitals overlap to form the designated bonds? (Circle the appropriate orbital in the list provided beside each atom.) i sigma bond between carbon "Y" and nitrogen orbital on carbon "Y": 5 p d f sp sp? sp? orbital on nitrogen: S p d f sp sp? sp3 ii. pi bond...
Extra Credit The properties of the hybrid orbitals (energy, most probable radius, electronegativity, ete.) will be determined by: (1), the properties of the atomie orbitals that the hybrid orbitals contain (2) the contribution that each orbital type makes to the hybrid mixture. Questions: In each case justify your response 1) In which of the following hybrid orbitals will electrons be the highest in energy? 2) In which will the electrons be lowest in energy? sp, spl. sp, sp'd spid (assume...
Passage 11 (Questions 1-9) Dienes, a special group of alkenes, can be classified as conjugated or isolated. Conjugated dienes are alkenes with alternating double and single bonds. Isolated dienes have double bonds separated by more than one single bond. One explanation for this observation is the hybridization theory. According to the hybridization theory, the stability of conjugated dienes comes from the hybridization of the orbitals forming the carbon-carbon single bonds. For example, in 1,4-pentadiene, the C-C single bonds result from...
2. The structure of the commonly used organic solvent dimethylformamide (DMF) is shown below. The numbers by each carbon atom are shown to distinguish each C atom in the molecule. Using Valence Bond Theory, answer the questions in parts a) and b). (4 pts) o: н LH H) N )H -Co HIH Dimethylformamide a) Specify the hybrid orbitals for each atom in the molecule indicated below C 2): N: C(1): b) Identify the bond type(s) and the overlapping orbitals of...
Complete the Lewis structure of the compound shown below and indicate which of the following statements are true. 46 Η Η H C =C-C-N H=21日 An sp2 hybrid orbital on C-1 overlaps with an sp hybrid orbital on C-2 to form the sigma bond between C-1 and C-2. There are ten o bonds in this molecule. There are five i bonds in this molecule. The C-2 and C-3 atoms cannot rotate about the internuclear axis between the two atoms since...
Match each of the following ions and molecules with its correct molecular Complete the Lewis structure of the chlorite ion, ClO2-, which is used as a bleaching agent. Complete only two resonance structure in which the formal charges are closest to zero. What is the valence molecular orbital configuration (according to MO theory) of homonuclear diatomic species where the atoms have an atomic number greater than seven? How many electrons are there in the pi antibonding orbitals of the following...
QUESTION 11 Match the alom indicated with the correct hybridization for the molecule CHCOOH (scetic acid) of the CH csup>3<sup> - Cof the COOH - In the CEO bond - in the CO H portion Acis in CO bond and thus is sp Bo has electron domains but is sp C carbon has & electron domains and so is sp 0.has only 3 electron domains and so is sp? QUESTION 12 in the compound CH CH The hybridization of both...
Answer the following on a separate sheet of paper. 1. Using the data collected for PF, SF, and CIF, what structural comments can be made about molecules with more than four groups (charge clouds) around the central atom? 2. Select which structure is preferred and discuss why? SC 3. To assess the stability of the axial versus equatorial positions for a trigonal bipyramidal structure, a computer program was used to determine the energy to assess SF, with the lone pair...
Question 1 and 2 of the worksheet?
Shang 22 In this figure, P2 is lower energy than P1. By the Hammond postulate, TS2 is also lower energy as well as structurally more like the reactants. Thus the activation energy. EA[2) is also lower Trends in Nucleophile Strength For this discussion, we have to assume the rate factors above apply in reverse that a faster reaction rate is associated with a more exothermic reaction. For nucleophiles, the neutral nucleophiles (amines, alcohols,...
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