V. Concentration Cell Copper - Copper Cy(s), CuCl2 (0.01) || Cu(s), CuCl2 (1.0 M) 1. Draw...
V. Concentration Cell
Copper - Copper
Cy(s), CuCl2 (0.01) || Cu(s), CuCl2 (1.0 M)
1. Draw the schematic of the electrochemical cell that includes all the components (metals, solutions, salt bridges, voltmeters, etc.). Annotate on the schematic which side is the anode, which side is the cathode, the sign of each half cell, the composition of the metals and solutions, and the direction of the flow of the electrons through the cell.
2. Write the half reactions that occur at the anode and cathode in this electrochemical cell. Annotate which half reaction occurs at the anode and the cathode.
3. Write the overall balance reaction of this electrochemical cell.
4. Calculate E°cell of this electrochemical cell. (include units)
E°cell __________________________
5. Calculate the reaction quotient (Q) of this reaction.
Q ______________________
6. Calculate the expected Ecell for this reaction.
Ecell ______________________
Homework Answers
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V. Concentration Cell
Copper - Copper
Cy(s), CuCl2 (0.01) ||
Cu(s), CuCl2 (1.0 M)
1. Draw...
My percent error is high so before I keep going I wanted to make sure I...
My percent error is high so before I keep going I wanted to
make sure I am doing this right. Can someone check this over and
make sure everything is right?
Ered (V) Half-reaction F(g)+2e2F" (aq) Cl,(g)+2e2C (aq) Ag (aq)+leAg(s) Fe (aq)+le Fe (aq) Cu (aq)+2e-> Cu(s) 2H (aq)+2eH, (g) Ni (aq)+2eNi(s) Cd (aq)+2eCd(s) Fe (aq)+2e Fe(s) Zn2 (aq)+2e-> Zn(s) 2.87 1.36 0.80 0.77 0.34 0.00 0.28 -0.40 -0.44 -0.76 Mg (aq)+2e- Mg(s) -2.37 Table 1. Standard Reduction Potential for...
data collected Cu(NO3)2 | Zn(NO3)2 = 0.999 V Pb | 1.0 M Pb(NO3)2 || 1.0 M...
data collected
Cu(NO3)2 | Zn(NO3)2 = 0.999 V
Pb | 1.0 M Pb(NO3)2 || 1.0 M Zn(NO3)2 | Zn = 0.396 V
PART B: REDUCTION POTENTIALS 1. Report the measured cell potential for each galvanic cell and state which electrode corresponds to the cathode and which to the anode. 2. Given E = -0.76 V for the Zn/Zn half-cell, and your measured Ecell, calculate the reduction potential at the Cu and Pb electrodes and write the redox half- 6 reactions...
You are given metal stripes of Zn, Cu, Cd, Fe, Ni, Mg and their respective salt...
You are given metal stripes of Zn, Cu, Cd, Fe, Ni, Mg and their respective salt solutions Zn(NO3)2, Cu(NO3)2, Cd(NO3)2 , Fe(NO3)2 , Ni(NO3)2 , and Mg(NO3)2. Build 6 different electrochemical cells using the given materials and calculate the standard cell potential using Table 19.1, and write the cell notations for each of your electrochemical cell on the given space in the worksheet. One of the electrochemical cells must have the largest standard cell potential E°cell using the given materials....
A voltaic electrochemical cell is constructed in which the anode is a Pb2+Pb half cell and...
A voltaic electrochemical cell is constructed in which the anode is a Pb2+Pb half cell and the cathode is a Cu2+, Cu+ half cell. The half-cell compartments are connected by a salt bridge. Write the anode reaction. ___+______---->_____ +______ Write the cathode reaction. ______+________---->______ +_____ Write the net cell reaction. _______+_______------>______ +_______ In the external circuit, electrons migrate_____(from or to) the Pb2+Pb electrode ______ (from or to) the Cu2+, Cu+ electrode. In the salt bridge, anions migrate______ (from or to)...
An electrochemical cell is expressed as Cu(s) | Cu^2+ (0.20 M) || I^- (0.10 M) |...
An electrochemical cell is expressed as Cu(s) | Cu^2+ (0.20 M) || I^- (0.10 M) | I_3^- (0.20 M) | Pt. I_3^- + 2e^- rightarrow 3I^-, E^0 = 0.535 V Cu^2+ + 2e^- rightarrow Cu(s) E^0 = 0.339 V Please answer the following questions: a. Write half-cell reactions at anode and at cathode. b. Write whole-cell reaction. c. Calculate the potential/voltage of the cell. d. Calculate equilibrium constant for this whole-cell reaction.
salt bridge Zn(s) electrode Culs) electrode 1.0M Zn (a 1.0 M Cu (aq A voltaic cell...
salt bridge Zn(s) electrode Culs) electrode 1.0M Zn (a 1.0 M Cu (aq A voltaic cell similar to that shown in the figure above is constructed. The electronic device shown at the top of the figure is a volt meter. One electrode compartment consists of a zinc strip placed in a 1.0 M ZnCl2 solution, and the other has a copper strip placed in a 1.0 M CuSOA solution. The overall cell reaction is: Zn(s)Cu2+(aq)= zn2+ (aq ) Cu (s)...
3. A student connects a Cd?"(0.20 M)|Cd(s) half-cell to a Cu?"(1 M) Cu(s) electrode. When the...
3. A student connects a Cd?"(0.20 M)|Cd(s) half-cell to a Cu?"(1 M) Cu(s) electrode. When the red lead is attached to the Cu electrode, the cell potential read by the voltmeter, E is +0.77 V. a. What is the reduction half-reaction at the cathode (red lead)? b. What is the oxidation half-reaction at the anode (black lead)? c. What is the overall cell reaction? d. Write the expression for the thermodynamic reaction quotient, Q, and calculate its value for this...
salt bridge ME Cr(s) electrode Cu(s) electrode 1.0 M Cr3+ (aq) 1.0 M Cu2+ (aq) A...
salt bridge ME Cr(s) electrode Cu(s) electrode 1.0 M Cr3+ (aq) 1.0 M Cu2+ (aq) A electrolytic cell similar to that shown in the figure above is constructed. The electronic device shown at the top of the figure is a power supply. One electrode compartment consists of a chromium strip placed in a 1.0 M CrCl3 solution, and the other has a copper strip placed in a 1.0 M CuSO4 solution. The overall cell reaction is: 2 Cr3+ (aq) +...
A copper/magnesium electrochemical cell was constructed. EXPERIMENT S Volumetric Analysi Acid-Bse Titration Part Il: Answer each...
A copper/magnesium electrochemical cell was constructed.
EXPERIMENT S Volumetric Analysi Acid-Bse Titration Part Il: Answer each of the following questions about the copper/magnesium electrochemical cell you built in this experiment. Answer for the single cell, do not worry about the series configuration. 65 Copper Which electrode is the cathode? Magnesium Copper Which electrode is the anode? 2 Magnesium 3. Write the equation for the half-reaction that occurs at the copper electrode, and indicate whether it is an oxidation or a...
Prelab Activity: Electrochemical Cells To determine the solubility product of copper(II) carbonate, CuCO3 , a concentration...
Prelab Activity:
Electrochemical Cells
To determine the solubility product of copper(II) carbonate,
CuCO3 , a concentration cell as described on pages 71-72
of the lab handout is constructed. The temperature of the Galvanic
cell is measured to be 22.5°C, and the cell potential 282 mV (0.282
V). Using this data and Equation 8 in the lab manual, calculate the
Ksp for CuCO3 and report your answer with
three significant digits.
For the Galvanic cell you will construct in PART B,...
My percent error is high so before I keep going I wanted to
make sure I am doing this right. Can someone check this over and
make sure everything is right?
Ered (V) Half-reaction F(g)+2e2F" (aq) Cl,(g)+2e2C (aq) Ag (aq)+leAg(s) Fe (aq)+le Fe (aq) Cu (aq)+2e-> Cu(s) 2H (aq)+2eH, (g) Ni (aq)+2eNi(s) Cd (aq)+2eCd(s) Fe (aq)+2e Fe(s) Zn2 (aq)+2e-> Zn(s) 2.87 1.36 0.80 0.77 0.34 0.00 0.28 -0.40 -0.44 -0.76 Mg (aq)+2e- Mg(s) -2.37 Table 1. Standard Reduction Potential for...
data collected
Cu(NO3)2 | Zn(NO3)2 = 0.999 V
Pb | 1.0 M Pb(NO3)2 || 1.0 M Zn(NO3)2 | Zn = 0.396 V
PART B: REDUCTION POTENTIALS 1. Report the measured cell potential for each galvanic cell and state which electrode corresponds to the cathode and which to the anode. 2. Given E = -0.76 V for the Zn/Zn half-cell, and your measured Ecell, calculate the reduction potential at the Cu and Pb electrodes and write the redox half- 6 reactions...
An electrochemical cell is expressed as Cu(s) | Cu^2+ (0.20 M) || I^- (0.10 M) | I_3^- (0.20 M) | Pt. I_3^- + 2e^- rightarrow 3I^-, E^0 = 0.535 V Cu^2+ + 2e^- rightarrow Cu(s) E^0 = 0.339 V Please answer the following questions: a. Write half-cell reactions at anode and at cathode. b. Write whole-cell reaction. c. Calculate the potential/voltage of the cell. d. Calculate equilibrium constant for this whole-cell reaction.
salt bridge Zn(s) electrode Culs) electrode 1.0M Zn (a 1.0 M Cu (aq A voltaic cell similar to that shown in the figure above is constructed. The electronic device shown at the top of the figure is a volt meter. One electrode compartment consists of a zinc strip placed in a 1.0 M ZnCl2 solution, and the other has a copper strip placed in a 1.0 M CuSOA solution. The overall cell reaction is: Zn(s)Cu2+(aq)= zn2+ (aq ) Cu (s)...
3. A student connects a Cd?"(0.20 M)|Cd(s) half-cell to a Cu?"(1 M) Cu(s) electrode. When the red lead is attached to the Cu electrode, the cell potential read by the voltmeter, E is +0.77 V. a. What is the reduction half-reaction at the cathode (red lead)? b. What is the oxidation half-reaction at the anode (black lead)? c. What is the overall cell reaction? d. Write the expression for the thermodynamic reaction quotient, Q, and calculate its value for this...
salt bridge ME Cr(s) electrode Cu(s) electrode 1.0 M Cr3+ (aq) 1.0 M Cu2+ (aq) A electrolytic cell similar to that shown in the figure above is constructed. The electronic device shown at the top of the figure is a power supply. One electrode compartment consists of a chromium strip placed in a 1.0 M CrCl3 solution, and the other has a copper strip placed in a 1.0 M CuSO4 solution. The overall cell reaction is: 2 Cr3+ (aq) +...
A copper/magnesium electrochemical cell was constructed.
EXPERIMENT S Volumetric Analysi Acid-Bse Titration Part Il: Answer each of the following questions about the copper/magnesium electrochemical cell you built in this experiment. Answer for the single cell, do not worry about the series configuration. 65 Copper Which electrode is the cathode? Magnesium Copper Which electrode is the anode? 2 Magnesium 3. Write the equation for the half-reaction that occurs at the copper electrode, and indicate whether it is an oxidation or a...
Prelab Activity:
Electrochemical Cells
To determine the solubility product of copper(II) carbonate,
CuCO3 , a concentration cell as described on pages 71-72
of the lab handout is constructed. The temperature of the Galvanic
cell is measured to be 22.5°C, and the cell potential 282 mV (0.282
V). Using this data and Equation 8 in the lab manual, calculate the
Ksp for CuCO3 and report your answer with
three significant digits.
For the Galvanic cell you will construct in PART B,...
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