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Marr says “Consider, for example, some gas in a bottle. A description of thermodynamic effects—temperature, pressure,...

Marr says “Consider, for example, some gas in a bottle. A description of thermodynamic effects—temperature, pressure, density, and the relationships among these factors—is not formulated by using a large set of equations, one for each of the particles involved. Such effects are described at their own level, that of an enormous collection of particles; the effort is to show that in principle the microscopic and macroscopic descriptions are consistent with one another.” What is the main point he is trying to make? Why do you think he uses this example?

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Answer #1

In thermodynamics, properties are classified in terms of intrinsic and extrinsic.

In the above question also, Marr is trying to explain that temperature, pressure and density are intrinsic in nature as they are independent of other objects (the property corresponds to itself).

He uses this example because intrinsic properties are only dependent on chemical composition, inherent property.

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