Homework Answers
Retio of integration = 9:2:3
retio 9 given by 3 -CH3 (total 9 H) thay are attached to C atom which have no hydrogen atom therefore give singlet.
retio 2 given by -CH2- (total 2 H ) attached to -CH3 which have 3 H so give quartet
retio 3 given by -CH3(total 3 H) attaced to -CH2- which have 2 H so give triplet
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The H NMR spectrum for the ester shown below displays a singlet, a quartet, and a...
Question 2 The 13 C-NMR spectrum of an unknown compound (formula CgH180) is shown below. Its...
Question 2 The 13 C-NMR spectrum of an unknown compound (formula CgH180) is shown below. Its "H-NMR spectrum only shows one singlet at 1.2 ppm. Draw the structure of this unknown compound. 240 220 '200'180' 160140120100' 80' 604020 PPM H3CU CH3 CH3 CH3 Create OscerSketch Answer 2 Incorrect: Answer has an incorrect structure. What would be the expected splitting pattern of the signal associated with the indicated hydrogen atoms? Question 3 A. singlet B. doublet C. triplet D. quartet E....
The H-NMR spectrum of an unknown compound (formula CaHgO2) is shown below. Draw the structure of...
The H-NMR spectrum of an unknown compound (formula CaHgO2) is shown below. Draw the structure of the unknown compound. Question 5 4 1 6 5 8 10 11 Ppm The 13C-NMR spectrum of an unknown compound (formula CgH180) is shown below. Its 1H-NMR spectrum only shows one singlet at 1.2 ppm. Draw the structure of this unknown compound. uestion 2 220 200 160 140 120 PPM 100 80 240 180 60 40 20 Create OscerSketch Answer 2 What would be...
4. Consider the following two diastercomers: Both compounds generate 'H NMR spectra with the following signals:...
4. Consider the following two diastercomers: Both compounds generate 'H NMR spectra with the following signals: A multiplet between 7.20-7.63 ppm with an integration of 5H Two separate doublets between 5.70-6.50 ppm, each with an integration of 1H A singlet around 1.30 ppm with an integration of 9H Despite the similarities, how could you differentiate between the H NMR spectra of these isomers? 5. Assign each set of protons to their appropriate signals in the 'H NMR spectrum shown below....
Question 45 1. a) NMR spectrum of CH3-CH2-O-CH3 contain one singlet, one quartet, and one triplet:...
Question 45 1. a) NMR spectrum of CH3-CH2-O-CH3 contain one singlet, one quartet, and one triplet: True/False True False Question 46 1.b) CHCI-CHBr2: two doublets (d) will appear in the NMR spectra: True/False True False Question 47 1.c) CH3-CH2-CO-CH2-CN: IR spectra will show a peak at 1740 and 2200cm-1: True/False True False Question 48 1 pts 1.d) NMR of the above molecule will show two triplets and one singlets: True/False True False Question 49 1 pts 1. e) Or, one...
19. A compound with a molecular formula C Hascio, has the following 'H NMR spectrum. The...
19. A compound with a molecular formula C Hascio, has the following 'H NMR spectrum. The IR spectrum shows strong absorption at 1800 cm. Which of the following structures is consistent with this spectrum? quartet triplet triplet quartet triplet 20. Which of the following compounds is consistent with the C NMR spectrum shown below? 3 signals PPM CHO / a) OH b) OH d) OH
18) How many signals would you expect to see in the 1H NMR spectrum of the...
18) How many signals would you expect to see in the 1H NMR spectrum of the following compound? 18) NI CH3CH2CH2CCH3 A) 6 B) 4 C)2 D) 5 E) 3 3 19) What splitting pattern is observed in the 1H NMR spectrum for the indicated hydrogens? OCH CH3 19) - D) quartet E) septet A) singlet B) doublet C) triplet 20) Which of the following alcohols dehydrates most rapidly? 1 -OH IV. CH3- 20) CH3- II. CH3 OH Cox HO...
Fill in the blank s=singlet d= doublet q= quartet and so on also which molecule match...
Fill in the blank s=singlet d= doublet q= quartet and so on also
which molecule match the HNMR and CNMR spectra
Observed 1H NMR and 13C NMR spectra: NMR Data Table for Predicting Expected Signals ЗН # of 'H Alcohol Ester Esterification Product with Acetic Acid # of 13C Ester NMR signals NMR signals 1H Ester NMR Integration & splitting (from left to right) HO Ethanol 4 3 3H(s), 2H(q), 3H(t) Ethyl acetate НО 1-Butanol Butyl acetate 2H 3H 4H...
What types of splitting patterns would you expect in the proton NMR spectrum of the molecule...
What types of splitting patterns would you expect in the proton NMR spectrum of the molecule shown below? Mark all that apply. singlet А doublet B triplet с quartet D sextet E ОА OB Ос Dם О Е D Question 9 4 pts Which compound corresponds to the 'H NMR spectrum below? (Integral values are indicated above/beside signals.) ОА Ос OE
7. Which compound below be H-1 NMR 0.9 ppm (quartet fits the following spectral data? (6...
7. Which compound below be H-1 NMR 0.9 ppm (quartet fits the following spectral data? (6 points) 1.2 ppm (sextet 2 hydrogens), 2.1 ppm (triplet, hydrogens), 4.3 ppm (singlet 3 hydrogens) C-13 NMR 5 signals 25 ppr ppm (CH2); 61 ppm: (CH3) 198 Ppm (C). IR strong peak 1735 cm Ignals 25 ppm (CH): 35 ppm (CH2), 46 ppm (CH2); 61 ppm: em Mass Spee parent M+ = 102 Mass Spec paren ou 0 H2 CH3 HjC Holo H3C- CC...
A compound has the 'H NMR spectrum shown below. Identify the compound. 11 10 9 00...
A compound has the 'H NMR spectrum shown below. Identify the compound. 11 10 9 00 7 6 UI 4 3 2 1 O None of these compounds fit the spectrum that is shown here. CN O Me H A compound has the 'H NMR spectrum shown below. Identify the compound. 3H triplet 2H triplet 2H 11 10 9 00 7 0) 5 4 3 N 1 0 None of these compounds fit the spectrum that is shown here. A...
Question 2 The 13 C-NMR spectrum of an unknown compound (formula CgH180) is shown below. Its "H-NMR spectrum only shows one singlet at 1.2 ppm. Draw the structure of this unknown compound. 240 220 '200'180' 160140120100' 80' 604020 PPM H3CU CH3 CH3 CH3 Create OscerSketch Answer 2 Incorrect: Answer has an incorrect structure. What would be the expected splitting pattern of the signal associated with the indicated hydrogen atoms? Question 3 A. singlet B. doublet C. triplet D. quartet E....
The H-NMR spectrum of an unknown compound (formula CaHgO2) is shown below. Draw the structure of the unknown compound. Question 5 4 1 6 5 8 10 11 Ppm The 13C-NMR spectrum of an unknown compound (formula CgH180) is shown below. Its 1H-NMR spectrum only shows one singlet at 1.2 ppm. Draw the structure of this unknown compound. uestion 2 220 200 160 140 120 PPM 100 80 240 180 60 40 20 Create OscerSketch Answer 2 What would be...
4. Consider the following two diastercomers: Both compounds generate 'H NMR spectra with the following signals: A multiplet between 7.20-7.63 ppm with an integration of 5H Two separate doublets between 5.70-6.50 ppm, each with an integration of 1H A singlet around 1.30 ppm with an integration of 9H Despite the similarities, how could you differentiate between the H NMR spectra of these isomers? 5. Assign each set of protons to their appropriate signals in the 'H NMR spectrum shown below....
Question 45 1. a) NMR spectrum of CH3-CH2-O-CH3 contain one singlet, one quartet, and one triplet: True/False True False Question 46 1.b) CHCI-CHBr2: two doublets (d) will appear in the NMR spectra: True/False True False Question 47 1.c) CH3-CH2-CO-CH2-CN: IR spectra will show a peak at 1740 and 2200cm-1: True/False True False Question 48 1 pts 1.d) NMR of the above molecule will show two triplets and one singlets: True/False True False Question 49 1 pts 1. e) Or, one...
19. A compound with a molecular formula C Hascio, has the following 'H NMR spectrum. The IR spectrum shows strong absorption at 1800 cm. Which of the following structures is consistent with this spectrum? quartet triplet triplet quartet triplet 20. Which of the following compounds is consistent with the C NMR spectrum shown below? 3 signals PPM CHO / a) OH b) OH d) OH
18) How many signals would you expect to see in the 1H NMR spectrum of the following compound? 18) NI CH3CH2CH2CCH3 A) 6 B) 4 C)2 D) 5 E) 3 3 19) What splitting pattern is observed in the 1H NMR spectrum for the indicated hydrogens? OCH CH3 19) - D) quartet E) septet A) singlet B) doublet C) triplet 20) Which of the following alcohols dehydrates most rapidly? 1 -OH IV. CH3- 20) CH3- II. CH3 OH Cox HO...
Fill in the blank s=singlet d= doublet q= quartet and so on also
which molecule match the HNMR and CNMR spectra
Observed 1H NMR and 13C NMR spectra: NMR Data Table for Predicting Expected Signals ЗН # of 'H Alcohol Ester Esterification Product with Acetic Acid # of 13C Ester NMR signals NMR signals 1H Ester NMR Integration & splitting (from left to right) HO Ethanol 4 3 3H(s), 2H(q), 3H(t) Ethyl acetate НО 1-Butanol Butyl acetate 2H 3H 4H...
What types of splitting patterns would you expect in the proton NMR spectrum of the molecule shown below? Mark all that apply. singlet А doublet B triplet с quartet D sextet E ОА OB Ос Dם О Е D Question 9 4 pts Which compound corresponds to the 'H NMR spectrum below? (Integral values are indicated above/beside signals.) ОА Ос OE
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