17. Draw the product(s) of each of the following reactions, accounting for rearrangement and stereoisomers when...
17. Draw the structure of the major organic product(s) for each of the following reactions. Indicate stereochemistry when appropriate. C(CH3)3 NASH Br (S)-2-bromononane - acetonitrile KOH CH,OH NaCN HE Br Acetonitrile C2H5 H, Br NaOH Acetone excess HBr ROOR HC1 + Br Na o DMSO
4. Predict the possible organic product(s) from the following reactions. Where relevant, show all stereoisomers. Pay particular attention to any information given in the product boxes. explair wnswers daw aroustolz OH Can you + HCI substitution AND elimination products + Н,о но., HCI only products with formula C1ghH1C +H2O H2SO4 OH only products with formula CeH120 HBr + 6 mono-addition products including stereoisomers 1 1
17. Draw the structure of the major organic product(s) for each of the following reactions. Indicate stereochemistry when appropriate. excess HBr ROOR HC1 + Na o BⓇOS DMSO
Draw the major organic product(s) of the following reactions
including stereochemistry when it is appropriate.
including stereochemistry when it is appropriate. the major organic product(s) of the following reactions CH3 H20/ H2SO4/Hgso4 H3C-C-CEC-CH3 OH
17. Draw the structure of the major organic product(s) for each of the following reactions. Indicate stereochemistry when appropriate. OCHY NISH store (S)-2-bromononane KOH CHOE NaCN Acetonitrile NaOH Acetone ROOR + Na o
Draw the product(s), including stereoisomers, of the reaction below. Do not duplicate any answers. All reactions have a product. m-CPBA Tsci pyridine OH HI ОН 1. SOCIE. pyridine 2. Ко"Ви OH 1. SOCl2, pyridine 2. KO'Bu O HI
1. Predict the major organic products of the following reactions. Draw all stereoisomers that are formed. НО, OH 1 eq ,H2SO4 (assume H2O workup of reaction to neutralize product) 1. LDA 2. (assume H,O workup of reaction to neutralize product) 3. Hg(OAC)2 4. NaBH, EtOH 1eq HBr EtOH ambiente 1. Brz. CCL 2. NaOET, ETOH OH
For each of the following reactions fill in the box to give the
missing product(s). If no reaction occurs, write N.R. If the
reaction produces a mixture of products, such as stereoisomers or
constitutional isomers, give the structure of each product. If a
major product arises, label it as so. Be sure to show
stereochemistry when needed.
1. NaOH ОН 2. 1-iodopropane THF OH 1. NaH THE 2. 1-bromobutane THF 1. methanol Hg(OAc)2 H2SO4 2. NaBH4 THE H2SO4 YOH 140...
1. Draw the product(s) of the following reactions. Include stereochemistry when relevant. If stereoisomers are formed then draw out and label the relationship between your structures. Ph-N3 40°C HN-NH2 SACOMe 150 °C d. CO2CH3 210 °C нсОСН3 In hv ZI 160 °C OBn 85 °C OBn OBno= o 1 equiv. CI K2CO3 heat PhCH N= H 1. LDA (1 equiv.) P 2. Ph Ph 3. aqueous work-up heat EtOH NaOEt 2. Draw the mechanism for the following transformations. I Н...
Draw the major organic product for each of the following
reactions. The first and third product are correct, but the second
one is not.
I am getting a hint for the second one that: "a rearrangement
will occur before water additions."
Thanks.
Draw the major organic product for each of the following reactions. 1. BH3, THF 1. Hg (OAC)2, H20 2. NaOH, H20, H202 H2SO4 2. NaBH4 H20