Question

(a) Crystal types are sometimes classified based on the type of bonding, for example ionic crystals. Name two other types of crystal. (b) A crystal is formed from Natoms. Give a brief description of the origin ofenergy bands in solids [3] (c) Sketch the band structure ofan undoped semiconductor, label the conduction and valence bands, and the relevant energies. Mark the position of the Fermi energy. Make a second sketch and assume the semiconductor has been doped n-type, add in and label the appropriate levels (you dont have to add the Fermi energy on this sketch) [3] (d) At room temperature germanium has an almost completely filled valence band separated by a 0.67 eV gap from an almost completely empty conduction band and so is a poor electrical conductor. Determine the maximum wavelength of electromagnetic radiation that will cause a marked increase in the conductivity. In what part ofthe electromagnetic spectrum does the photon lie? [4] (e) In a pure germanium sample determine the probability, f(E),that a state at the bottom of the conduction band is occupied for the temperatures 300 K and 320 K. What is the fractional change in the probability ofoccupancy between the two temperatures? [4] Forming a junction between two pieces ofthe same semiconductor material doped n-type and p-type, respectively, forms a p-n junction. A simple model predicts that the current through the junction, I, depends in the applied voltage, V, in the form I I,(eelAT -1 Continued over. 4 of 9 PH22001 Classical and Quantum Matter and Radiation July 2015 (f Briefly explain how it may be possible to dope germanium type and p-type, name the majority carriers that result. [3] (g) Determine the current through a p-n junction with a saturation current of 0.500 HA operating at 300 K with an applied voltage of 0.3 V, repeat the calculation for a voltage of -1 V. Briefly comment on the values an on the types of carries contributing to the current in both cases. [2]

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