2) For a mixture of 20 mL diethyl ether and of 5% sodium
hydroxide in 20 mL water two layers form. Based on densities, which
layer is on the bottom? (3) Which layer will 4-nitrobenzoic acid be
in. (4) Which layer will 4-nitrotoluene be in?
ether is less densier than water
so ether layer is top layer and aq. NAOH layer is bottom layer.
since NaOH is a strong base it reacts with 4-nitrobenzoic acid and form sodium salt of 4-nitrobenzoic acid, which is more solble in aq. layer.
so 4-nitrobenzoic acid goes to aq. NaOH layer.
and 4-nitrotoluene goes to ether layer
2) For a mixture of 20 mL diethyl ether and of 5% sodium hydroxide in 20...
3. A crude nonacidic product mixture dissolved in diethyl ether contains acetic acid. Describe an extraction procedure that could be used to remove the acetic acid. b. When the two layers form during an ether/water extraction, what would be an easy, convenient way to tell which layer is which if the densities were not available.
Given: 50mL of solution diethyl ether solution containing 1.00g each of benzoic acid, phenol and aniline,50 mL of sodium bicarbonate solution, 50 ml of sodium hydroxide solution, sodium sulfate and HCl. 1. Which layer in the separatory funnel (top or bottom layer) is the organic layer during an extraction process? 2. Given that sodium bicarbonate and sodium hydroxide solution are 5% by weight, what would be the volume of 1M HCl needed to be added for acidification to crystalize the...
Water : H2O 5% Sodium bicarbonate: NaHCO3 5% Sodium hydroxide: NaOH 5% Hydrochloric acid: HCl Diethyl ether: (C2H5)2O Dichloromethane: CH2Cl2 Which of the solvents from question #1 do(es) not contain water? Which of the solvents from question #1 is (are) basic? Which of the solvents from question #1 is (are) acidic? Which of the solvents from question #1 is (are) neutral?
5. Suppose you are trying to separate butanoic acid and 4-iodotoluene via extraction with diethyl ether and water. (a) Look up the structures and draw them below. Predict which reagent would have a greater preference/affinity for the diethyl ether layer (1 pt) (b) Which solvent will be on the bottom in the separatory funnel (or conical vial) (1 pt)? (c) U to the butanoic acid and which layer would it prefer- aqueous or o pon treatment of butanoic acid with...
Why did you wash the ether solution with sodium bicarbonate? Write chemical equations for the reactions that took place. b. At which purification steps was the unreacted methanol removed in the reaction? Some of it may have been removed in more than one place. c. Three-Step Synthesis of Methyl Anisate (Step 3) 0 CHOH. Н.so, cat.) Wear gloves. Methanol is poisonous. Ether is an anesthetic, so don't breathe it. Sulfuric acid is a strong corrosive acid. Wash any you spill...
What is the purpose of extracting the aqueous layer two more
times with ether in step 5?
What is the purpose of washing the combined organic layers with
NaOH in step 6?
Thank you
Reaction 1: Nitration HNO3 NO2 + H2SO4, H20 NO2 toluene NO2 ortho meta para Procedure for Reaction 1: 1) To a stirred solution of 3 ml (44.7 mmoles) 67 % HNO3 in 3.75 mL of water, H2SO4 (9 mL) was slowly added at 10-15 °C. 2)...
You weight out exactly 1.00 mg of benzoic acid and dissolve it in a mixture of 2.0 mL of diethyl ether and 2.0 mL of water. After mixing and allowing the layers to separate, the ether layer is removed, dried, and concentrated to yield 0.68 mg of benzoic acid. What is the Kp value (ether/water) for this system?
9. Then add slowly while mixing 1 mL of saturated sodium bicarbonate solution (NaHCO3) -IT WILL BUBBLE! Add additional drops of saturated sodium bicarbonate solution with mixing until no additional bubbling occurs Congratulations! You have just made your first ester. Now you want to separate your ester product from the other stuff in the reaction mixture. CTQ3 Sodium bicarbonate is a base. How will it interact with any carboxylic acid molecules still present in your reaction mixture? 10. Add 1mL...
The two immiscible layers in an extraction are water and diethyl ether. Which compound would you expect to be the upper layer?
Extraction of benzoic acid and 9-fluorenone using diethyl ether. (please do not include ethyl 4- aminobenzoate). I have to create a flow chart to diagram the key steps of the experiment and isolation of products. 0.100g of benzoic acid and 9-fluorenone are dissolved in diethyl ether. The extraction solvent is 5% sodium hydroxide (to extract the acidic component from the organic phase). Saturated sodium chloride is added to the organic layer. drying the organic solution: anhydrous sodium sulfate is added...