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1- In the presence of excess OH-, the Zn2+(aq) ion forms a hydroxide complex ion, Zn(OH)42-....

1- In the presence of excess OH-, the Zn2+(aq) ion forms a hydroxide complex ion, Zn(OH)42-. Calculate the concentration of free Zn2+ ion when 1.32×10-2mol ZnSO4(s) is added to 1.00 L of solution in which [OH- ] is held constant (buffered at pH 12.40). For Zn(OH)42-, Kf = 4.6×1017.

[Zn2+] = ------ M

2-
What is the approximate concentration of free Hg2+ ion at equilibrium when 1.86×10-2 mol mercury(II) nitrate is added to 1.00 L of solution that is 1.310 M in Cl-. For [HgCl4]2-, Kf = 1.2×1015.

  • [Hg2+] = ------- M
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