2. What equations are used to calculate: [4 marks] (a) The slope of a one-component phase...
2. What equations are used to calculate: [4 marks]
(a) The slope of a one-component phase transition curve
(b) The Gibbs energy change for a liquid undergoing a
compression
(c) The composition of a vapour in equilibrium with a solution of
composition, xA
(d) The fugacity of any gas
Homework Answers
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2. What equations are used to calculate: [4 marks]
(a) The slope of a one-component phase...
gibbs energy phase diagram question
Which ONE of the following statements is INCORRECT? (A) The triple point of a phase diagram shows the temperature and pressure at which three phases of a substance are in equilibrium. (B) When considering a reaction, the total Gibbs energy change for a system does not depend on any Gibbs energy of mixing. (C) At the freezing temperature of a liquid, DG = 0. (D) The equilibrium composition of a reaction mixture represents the system where the Gibbs energy is at a minimum. (E) The...
1. Mark with T (True) or F (False) (2 points each) • A Joule Thompson experiment...
1. Mark with T (True) or F (False) (2 points each) • A Joule Thompson experiment corresponds to a process with constant enthalpy • The state functions (U.H.G.A) act as thermodynamic potentials when represented as functions of their natural variables. • The Gibbs free energy is equal to the maximum PV work done by the system on the envi ronment • The standard enthalpy of formation for any pure element in its reference state is temperature dependent • The phase...
Please answer true or false and explain why for each of them. Thank you 1. Mark...
Please answer true or false and explain why for each of them.
Thank you
1. Mark with T (True) or F (False) (2 points each) • Joule Thompson experiment corresponds to process with constant enthalpy. . The state functions (U.H,G,A) act as thermodynamic potentials when represented as functions of their natural variables. • The Gibbs free energy is equal to the maximum PV work done by the system on the envi- ronment. . The standard enthalpy of formation for any...
A gas cylinder containing carbon dioxide, CO2, 85% by volume, and nitrogen, N2, 15% by volume...
A gas cylinder containing carbon dioxide, CO2, 85% by volume, and nitrogen, N2, 15% by volume has a volume of 2.2 m and is kept at a temperature of 20°C. You may assume the gas mixture is ideal. 0 Calculate the pressure in kPa in the cylinder when it contains 50 kg of gas. [2 marks] After a certain amount of gas has been used, the pressure decreases by 150 kPa. Calculate the mass of gas used. [2 marks] (b)...
GENERAL FEATURES OF A PHASE DIAGRAM; HYBRID ORBITALS AND FORMAL CHARGE MODEL 1 solid structure liquid...
GENERAL FEATURES OF A PHASE DIAGRAM; HYBRID ORBITALS AND FORMAL CHARGE MODEL 1 solid structure liquid rc Pressure in atm solid structure Il Temperature in K — KEY QUESTIONS 1. What quantities are plotted on the x-and y-axes of a phase diagram? 2. 2. How many different phases are shown by the phase diagram in the model? b. What are the labels used to identify them? 3. What do the solid lines in a phase diagram represent 4. 2. How...
Thermodynamics example information to help solve each question CALCULATIONS Question 1. Write the complete exp...
Thermodynamics
example information to help solve each question
CALCULATIONS Question 1. Write the complete expression for the free energy change of the L = V equilibrium reaction for pure water (equation 2) at 100 bars and 300-C using the following data: Gy = -210330 joules/mole GL = -210330 joules/mole Recall that the right side (water vapor) of the reaction is the product side and left side (water liquid) of the reaction is the reactant side, Recall that we always calculate...
2. a) The forward rate constant for an elementary solution-phase reaction is 100 sl, and the...
2. a) The forward rate constant for an elementary solution-phase reaction is 100 sl, and the reverse rate constant is 0.1 M's!. What is the standard Gibbs free energy change, AG", for this reaction? The temperature is 300 K. b) For the same reaction, the free energy of activation, AG , for the forward reaction is 50 kJ/mole. What is the activation free energy, AG,, for the reverse reaction? c) If the solvent is changed to one that interacts with...
Which of the following statements does not apply to the definition of an ideal gas? Group...
Which of the following statements does not apply to the definition of an ideal gas? Group of answer choices a. Intermolecular interactions are negligible. b. The Gibbs free energy only depends upon the temperature. c. The enthalpy only depends upon the temperature. d. The internal energy only depends upon the temperature. e. None. The previous answers are all correct. Consider a solid substance. Which of the following expressions is wrong? Group of answer choices a. Internal energy increases when the...
only 6...7...and 8 The Gibbs function of a thermodynamic system is defined by G H- TS. If the system is consisting of two phases 1 and 2 of a single substance and maintained at a constant temperat...
only 6...7...and 8
The Gibbs function of a thermodynamic system is defined by G H- TS. If the system is consisting of two phases 1 and 2 of a single substance and maintained at a constant temperature and pressure, the equilibriunm condition for the coexistence of these two phases is that the specific Gibbs functions are equal Consider now a first-order phase change between the phase 1 and the phase 2. At the phase boundary, the equilibrium condition for the...
2.A certain compound undergoes a solid + liquid phase transition at -25.5°C. The entropy change AS,...
2.A certain compound undergoes a solid + liquid phase transition at -25.5°C. The entropy change AS, associated with the phase transition at this temperature is 53.8 J mor' K". What is the amount of heat energy. 9, that is absorbed to give this value for AS? (8 points) 8. Use the data in the appendix to calculate the standard entropy change, ASo, for the combustion of 1 mole of methane, CHe() (note: all reactants and products are in the gaseous...
1. Mark with T (True) or F (False) (2 points each) • A Joule Thompson experiment corresponds to a process with constant enthalpy • The state functions (U.H.G.A) act as thermodynamic potentials when represented as functions of their natural variables. • The Gibbs free energy is equal to the maximum PV work done by the system on the envi ronment • The standard enthalpy of formation for any pure element in its reference state is temperature dependent • The phase...
Please answer true or false and explain why for each of them.
Thank you
1. Mark with T (True) or F (False) (2 points each) • Joule Thompson experiment corresponds to process with constant enthalpy. . The state functions (U.H,G,A) act as thermodynamic potentials when represented as functions of their natural variables. • The Gibbs free energy is equal to the maximum PV work done by the system on the envi- ronment. . The standard enthalpy of formation for any...
A gas cylinder containing carbon dioxide, CO2, 85% by volume, and nitrogen, N2, 15% by volume has a volume of 2.2 m and is kept at a temperature of 20°C. You may assume the gas mixture is ideal. 0 Calculate the pressure in kPa in the cylinder when it contains 50 kg of gas. [2 marks] After a certain amount of gas has been used, the pressure decreases by 150 kPa. Calculate the mass of gas used. [2 marks] (b)...
GENERAL FEATURES OF A PHASE DIAGRAM; HYBRID ORBITALS AND FORMAL CHARGE MODEL 1 solid structure liquid rc Pressure in atm solid structure Il Temperature in K — KEY QUESTIONS 1. What quantities are plotted on the x-and y-axes of a phase diagram? 2. 2. How many different phases are shown by the phase diagram in the model? b. What are the labels used to identify them? 3. What do the solid lines in a phase diagram represent 4. 2. How...
Thermodynamics
example information to help solve each question
CALCULATIONS Question 1. Write the complete expression for the free energy change of the L = V equilibrium reaction for pure water (equation 2) at 100 bars and 300-C using the following data: Gy = -210330 joules/mole GL = -210330 joules/mole Recall that the right side (water vapor) of the reaction is the product side and left side (water liquid) of the reaction is the reactant side, Recall that we always calculate...
2. a) The forward rate constant for an elementary solution-phase reaction is 100 sl, and the reverse rate constant is 0.1 M's!. What is the standard Gibbs free energy change, AG", for this reaction? The temperature is 300 K. b) For the same reaction, the free energy of activation, AG , for the forward reaction is 50 kJ/mole. What is the activation free energy, AG,, for the reverse reaction? c) If the solvent is changed to one that interacts with...
only 6...7...and 8
The Gibbs function of a thermodynamic system is defined by G H- TS. If the system is consisting of two phases 1 and 2 of a single substance and maintained at a constant temperature and pressure, the equilibriunm condition for the coexistence of these two phases is that the specific Gibbs functions are equal Consider now a first-order phase change between the phase 1 and the phase 2. At the phase boundary, the equilibrium condition for the...
2.A certain compound undergoes a solid + liquid phase transition at -25.5°C. The entropy change AS, associated with the phase transition at this temperature is 53.8 J mor' K". What is the amount of heat energy. 9, that is absorbed to give this value for AS? (8 points) 8. Use the data in the appendix to calculate the standard entropy change, ASo, for the combustion of 1 mole of methane, CHe() (note: all reactants and products are in the gaseous...
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