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A 5.0×10−5M5.0×10−5M solution of a compound in hexane shows an absorbance of 0.440.44 at 252nm252nm in...

A 5.0×10−5M5.0×10−5M solution of a compound in hexane shows an absorbance of 0.440.44 at 252nm252nm in a cell with a 11-cmcm light path. What is the molar absorptivity of the compound in hexane at 252nm252nm?

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Answer #1

Solution:

Absorbance (A) = c l

Where,

= molar absorptivity

c = concentration

l = path length

Thus,

= A / c l

= 0.440 / 11 cm x 5.5 x 10^-5 M

= 7.27 x 10^2 M-1 cm-1

= 7.27 x 10^2 L mol-1 cm-1

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