The dissociation that occurs is:
H2A = H + + HA-
You have the expression of Ka1:
Ka1 = [H +] * [HA-] / [H2A]
4x10 ^ -6 = X ^ 2 / 0.08
It clears X = 5.7x10 ^ -4 M
The pH is calculated:
pH = - log 5.7x10 ^ -4 = 3.25
You have the second dissociation:
HA- = H + + A-2
You have the expression of Ka2:
Ka2 = [H +] * [A-2] / [HA-]
5.1x10 ^ -9 = 5.7x10 ^ -4 * [A-2] / 5.7x10 ^ -4
It clears [A-2] = 5.1x10 ^ -9 M
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