moles of HCl = molarity×volume/1000
= 100×0.10/1000 = 0.01 moles
Moles of NH3 = 50×0.14/1000 = 0.007 Moles
Moles of HCl left after consuming NH3 = 0.01-0.007
= 0.003 moles
Total volume = 100+50 = 150 ml
[H+] = moles×1000/volume = 0.003×1000/150 = 0.02
pH = - log[H+] = - log(0.02) = 1.70
Answer is d).
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