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9. (20 points) Examine the structure shown below. Draw BOTH chair conformations of this compound. SHOW...
1. For each of these molecules, draw both chair conformations. Include all the hydrogens on the...
1. For each of these molecules, draw both chair conformations. Include all the hydrogens on the ring. Circle the more stable chair conformation of each molecule. CH3 .?? H3C CH3 H3C CH3 2. Which of these two molecules is more stable, A or B? Circle your answer, and support your decision by drawing all relevant chairs.
A chair conformation of compound A is shown: Answer both of the questions and explain A...
A
chair conformation of compound A is shown:
Answer both of the questions and explain
A chair conformation of Compound A is shown: CH3 ring flip H3C CH3 Conformation A a) (apts) Draw a conformation of compound A as a result of ring flip. Circle the more stable conformation if possible. b) (5pts) Draw a Newman projection of conformation A.
3. a) Draw both chair conformations for the molecule shown below. (2pts) b) Circle the most...
3. a) Draw both chair conformations for the molecule shown
below. (2pts) b) Circle the most stable conformation above. Give a
brief explanation on why your choice is more stable. (2pts)
b) Circle the most stable conformation above. Give a brief
explanation on why your choice is more stable. (2pts)
3. a) Draw both chair conformations for the molecule shown below. (2pts) HO OH b) Circle the most stable conformation above. Give a brief explanation on why your choice is...
4. Draw the lowest energy chair conformations for both of the following compounds. Which is more...
4. Draw the lowest energy chair conformations for both of the following compounds. Which is more stable? Briefly explain. (8pts) 18 II llora nobsefoin smw.odo a) I c) Both have the same stability b) п 5. Draw the lowest energy chair conformations for both of the following compounds. Which is more stable? Briefly explain (8pts) beuo zed n bos enonsmothop beagndoa ow odb TotoKD ( .a1alil o enoemogoo boaee.ove dos 10 d II a) I b) II c) Both have...
1. Draw (1S,3S)-3-aminocyclohexanecarbonitrile structure below: 2. Draw the two chair conformations of the above disubstituted cyclohexane...
1. Draw (1S,3S)-3-aminocyclohexanecarbonitrile structure below: 2. Draw the two chair conformations of the above disubstituted cyclohexane compound, before and after ring-flip. 3. Draw the Newman projections of both chair conformations about the C1−C6 and C3−C4 bonds. 4. Which conformation is the least stable one? Briefly explain your answer with words AND by showing it on the appropriate Newman projection.
please explain in detail . thank you in advance . 3. (a) Draw both chair conformations...
please explain in detail . thank you in advance .
3. (a) Draw both chair conformations for (1R,2R4S)-4-t-butyl-1-chloro-2-ethylcyclohexane. Label the B-carbons (as Br, B2, etc.) in each chair structure; include all hydrogens on the B-carbons. (2.5 pts) nC (1R,2R 4S)-4-t-butyl-1-chloro- 2-ethylcyclohexane (b) Draw a square around the chair conformation most likely to undergo an E2 reaction and explain your choice. (1 pt) (c) Draw the major organic product (including stereochemistry) of the E2 reaction between (1R,2R 4S)-4-t-butyl-1-chloro-2-ethylcyclohexane and sodium ethoxide...
please help II. (8 pts.) Draw both possible chair conformations of the following compound as sawhorse...
please help
II. (8 pts.) Draw both possible chair conformations of the following compound as sawhorse projections. Show all substituents on the substituted positions of the ring. Each structure will be graded as right or wrong (no partial credit), so do your very best. OH III. (12 pts.) Give the expected major product for each reaction. Show any stereochemistry clearly. HCI, room temp (1 equiv.) 1) H2 Lindlar catalyst 2) BH3
4 4. (a) Draw the structure of the two chair forms of methylcyclohexane. Draw in all...
4 4. (a) Draw the structure of the two chair forms of methylcyclohexane. Draw in all bonds (even the C-H bonds). Be sure the axial and equatorial bonds are shown correctly. On the appropriate structure, indicate the 1,3-diaxial interactions involving the methyl group. (b) Which is more stable, trans-1,3-dimethylcyclohexane or cis-1,3-dimethylcyclohexane? Why? 5. Draw the Newman projections for the anti conformation and two types of eclipsed conformations of 1,2-diiodoethane. Of the two eclipsed conformations, which is of higher energy, and...
7. (13 points) For the compound 1-tert-butyl-4-methylcyclohexane: a. Draw the two possible chair conformations for the...
7. (13 points) For the compound 1-tert-butyl-4-methylcyclohexane: a. Draw the two possible chair conformations for the cis isomer, Which conformation, if either, is more stable? Circle one b. Draw the two possible chair conformations for the cis isomer, Which conformation, if either, is more stable? Circle one trans: C. Between the two more stable isomers circled above, which is more stable? Why?
6. (14 points) Consider the following molecule. DH CI H2C CH3 (a) (7 points) Draw three...
6. (14 points) Consider the following molecule. DH CI H2C CH3 (a) (7 points) Draw three staggered conformations of this molecule using Newman projections from the indicated perspective (one structure per box). Then, circle the lowest energy conformation. (b) (7 points) Draw three eclipsed conformations of this molecule using Newman projections from the indicated perspective (one structure per box). Then, circle the highest energy conformation. 7. (4 points) Draw a Newman projection for the following compound: C1 CH3 NOZ CI...
1. For each of these molecules, draw both chair conformations. Include all the hydrogens on the ring. Circle the more stable chair conformation of each molecule. CH3 .?? H3C CH3 H3C CH3 2. Which of these two molecules is more stable, A or B? Circle your answer, and support your decision by drawing all relevant chairs.
A
chair conformation of compound A is shown:
Answer both of the questions and explain
A chair conformation of Compound A is shown: CH3 ring flip H3C CH3 Conformation A a) (apts) Draw a conformation of compound A as a result of ring flip. Circle the more stable conformation if possible. b) (5pts) Draw a Newman projection of conformation A.
3. a) Draw both chair conformations for the molecule shown
below. (2pts) b) Circle the most stable conformation above. Give a
brief explanation on why your choice is more stable. (2pts)
b) Circle the most stable conformation above. Give a brief
explanation on why your choice is more stable. (2pts)
3. a) Draw both chair conformations for the molecule shown below. (2pts) HO OH b) Circle the most stable conformation above. Give a brief explanation on why your choice is...
4. Draw the lowest energy chair conformations for both of the following compounds. Which is more stable? Briefly explain. (8pts) 18 II llora nobsefoin smw.odo a) I c) Both have the same stability b) п 5. Draw the lowest energy chair conformations for both of the following compounds. Which is more stable? Briefly explain (8pts) beuo zed n bos enonsmothop beagndoa ow odb TotoKD ( .a1alil o enoemogoo boaee.ove dos 10 d II a) I b) II c) Both have...
please explain in detail . thank you in advance .
3. (a) Draw both chair conformations for (1R,2R4S)-4-t-butyl-1-chloro-2-ethylcyclohexane. Label the B-carbons (as Br, B2, etc.) in each chair structure; include all hydrogens on the B-carbons. (2.5 pts) nC (1R,2R 4S)-4-t-butyl-1-chloro- 2-ethylcyclohexane (b) Draw a square around the chair conformation most likely to undergo an E2 reaction and explain your choice. (1 pt) (c) Draw the major organic product (including stereochemistry) of the E2 reaction between (1R,2R 4S)-4-t-butyl-1-chloro-2-ethylcyclohexane and sodium ethoxide...
please help
II. (8 pts.) Draw both possible chair conformations of the following compound as sawhorse projections. Show all substituents on the substituted positions of the ring. Each structure will be graded as right or wrong (no partial credit), so do your very best. OH III. (12 pts.) Give the expected major product for each reaction. Show any stereochemistry clearly. HCI, room temp (1 equiv.) 1) H2 Lindlar catalyst 2) BH3
4 4. (a) Draw the structure of the two chair forms of methylcyclohexane. Draw in all bonds (even the C-H bonds). Be sure the axial and equatorial bonds are shown correctly. On the appropriate structure, indicate the 1,3-diaxial interactions involving the methyl group. (b) Which is more stable, trans-1,3-dimethylcyclohexane or cis-1,3-dimethylcyclohexane? Why? 5. Draw the Newman projections for the anti conformation and two types of eclipsed conformations of 1,2-diiodoethane. Of the two eclipsed conformations, which is of higher energy, and...
7. (13 points) For the compound 1-tert-butyl-4-methylcyclohexane: a. Draw the two possible chair conformations for the cis isomer, Which conformation, if either, is more stable? Circle one b. Draw the two possible chair conformations for the cis isomer, Which conformation, if either, is more stable? Circle one trans: C. Between the two more stable isomers circled above, which is more stable? Why?
6. (14 points) Consider the following molecule. DH CI H2C CH3 (a) (7 points) Draw three staggered conformations of this molecule using Newman projections from the indicated perspective (one structure per box). Then, circle the lowest energy conformation. (b) (7 points) Draw three eclipsed conformations of this molecule using Newman projections from the indicated perspective (one structure per box). Then, circle the highest energy conformation. 7. (4 points) Draw a Newman projection for the following compound: C1 CH3 NOZ CI...
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